Sharif Digital Repository

In this study, cationic polyurethane resin was synthesized by use of the reflux technique under N2 atmosphere. At first TDI was reacted with GMS to form prepolymer with terminal –NCO, also DBTDL was used as catalyst. This prepolymer was then reacted for chain-lengthening with N-methyl diethanolamine compound containing tertiary nitrogen atoms. The chain-lengthened product was then converted into an ammonium compound or cationic compound, by reacting with HCl as reactive hydrogen containing compound. The structure of product was studied by FT-IR spectroscopy. Then the cationic product was used as adduct resin with commercial tow-components polyurethane with proportion of 25%wt, 50%wt and... 

Membrane Technology is rapidly growing all over the world because of many applications. In all of this applications , use of adhesive ( between membranes and wall ) is necessary. selection of appropriate adhesive for membrane is very important in order to membrane has best performance and lifetime .Adhesives used in membrane technology must have good adhesion and suitable hardness . One of the newest adhesives used in membrane technology is two-component polyurethane adhesive. PU adhesives make strong and durable bond and have good flexibility which is an advantage for membrane technology.MDI isocyanate is used in most of commercial PU adhesives’ formulation. But in this study , modified MDI... 

Selection of appropriate coating system is the most important subject in corrosion control of buried pipelines. Corrosion control of buried pipelines is achieved by using a combination of barrier coatings and cathodic protection (CP). Applying barrier coating can decrease the protection current of CP. However, at the coating holidays the pipeline act as cathode generating hydroxyl ion and hydrogen electrochemically. Therefore the selected coating should be compatible with the alkaline condition.This research focuses on evaluating of an epoxy-tar and a urethane-tar based coating. Coatings performance has been tested by accelerated corrosion test methods (i.e. Salt spray according to ASTM... 

In recent years, the use of polyurethane foams has been of interest for many researchers and craftsmen. Polyurethane foams, due to their excellent properties, can be used in important applications such as advanced military industries, insulation and those requiring strength and maneuverability. The aim of this research project is to produce polyurethane / sodium silicate or nano-silica nanocomposites. Prior to the fabrication and synthesis process of polyurethane containing sodium or nano-silica, deposited silica nanoparticles were synthesized using high-rubbed sodium silicate and sulfuric acid, followed by various tests including XRD, FE-SEM and BET to verify It was done. Sodium silicate... 

Blending can be used as one of the ways of producing materials with appropriate properties, which have many relative advantages in comparison with other methods like polymerization. Among the existing blends in the market and scientific areas, blends of polyurethane thermoplastic and polypropylene have been also studied because of its commercial importance and scientific interest. This blending can improve the mechanical properties, friction resistance, improvement of impact strength at low temperatures and improvement of plasticity properties. In this research, blends with different ratios of TPU/PP is produced by melt mixing, and for improving properties of blends, two kinds of nano fumed ... 

Porous medium is a material consisting of a solid matrix with an interconnected void. A polymer is a large molecule composed of many repeated subunits, known as monomers; Polyurethane is a type of polymer which has many uses. The aim of this research project is to investigate the effective factors in polyurethane polymer injection and the behavior of this material during the foaming in cavities with different soil porosities (0.15 < φ < 0.4). Parameters such as thermal boundary conditions and the soil material that could be effective in solidification of polyurethane are analyzed, numerically using FLUENT software. A simplified model for foaming is presented in this study which can be used... 

In this study, the influence of multi wall carbon nanotube on the thermal properties and microstructure of open cell flexible polyurethane (PU) foam was investigated. To do this untreated CNT (named here n-CNT) along with three different highly functionalized CNTs having carboxyl, hydroxyl and amide functional groups, abbreviated here by CNT-COOH, CNT-OH and CNT-NH-COR, respectively, were employed. A series of PU foam with and without CNTs (both treated and untreated ones) were prepared by cast molding. Prior molding, the CNTs (0.1 wt% loading) were first dispersed into the polyol (Mw = 3000 g/mol and OH No. 56) and then the mixture was subsequently added to the isocynate (TDI). The SEM... 

In this study, antistatic waterborne polyurethane coating containing zirconia nanoparticles is made and applied on 304 stainless steel substrates at weight percentage of 0.66, 1.3, 3, 4.5 and 6% zirconia nanoparticles. For synthesis of hydrophilic isocyanate prepolymer, isocyanate prepolymer is modified by hydrophilic polyethylene glycol with molecular weight 600, 1000 and 4000. For ensuring of modification condition and stability of hydrophilic isocyanate prepolymer in aqua solution, FTIR and stability tests are employed, respectively. In order to create antistatic properties of these coatings, semi - conductive zirconia nanoparticles are used. To improve the distribution of zirconia...