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    The impact of silica nanoparticles on the performance of polymer solution in presence of salts in polymer flooding for heavy oil recovery

    , Article Fuel ; Vol. 123 , May , 2014 , pp. 123-132 ; ISSN: 00162361 Maghzi, A ; Kharrat, R ; Mohebbi, A ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    Due to role of polymer in increasing sweep efficiency during oil recovery, much attention has been paid to the using polymer solutions in enhanced oil recovery methods. In spite of the existence of the great researches in this area, the role of nanoparticles in modification of the polymer performance in the presence of salts has not been examined before. Furthermore, there is no information about how the dispersed silica nanoparticles affect the heavy oil recovery during the polymer flooding in the presence of divalent cations. In this study, a series of polymer flooding experiments are performed in a quarter five-spot glass micromodel saturated with heavy oil. Solutions of polyacrylamide... 

    Investigation of the applicability of nano silica particles as a thickening additive for polymer solutions applied in EOR processes

    , Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; Vol. 36, Issue. 12 , 2014 , Pages 1315-1324 ; ISSN: 15567036 Zeyghami, M ; Kharrat, R ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    In past decades, many attempts have been made to use water-soluble polymers as a mobility control agent to improve sweep efficiency of enhanced oil recovery processes. However, sensitivity of the thickening behavior of these polymers to some harsh conditions, such as high salinity, has cast serious doubt on their applicability in reservoir conditions. By expansion of nanotechnology, scientists discovered that nanoparticles can be utilized as thickening and rheology control agents in many polymer solutions. In this study, hydrophilic fumed silica is added to hydrolyzed polyacrylamide and sulfonated polyacrylamide solutions. The effect of the addition of nano silica on the thickening and... 

    , M.Sc. Thesis Sharif University of Technology Javidi Sofiani, Mahyar (Author) ; Ramezani Saadat, Ahmad (Supervisor)
    Abstract
    Polymer flooding can yield considerable increase in percentage recovery. However, there are limitations with the existing polymer flooding technology, such as thermal, mechanical, bacterial degradation, surface absorption and undesirable plugging. A novel nanocore shell structure of polyacrylamide and polystyrene designed and prepared to intellectually control mobility ratio in oil reservoirs and overcome weakness and limitations of classical polymer flooding. Polyacrylamide particles have been obtained using spray drying of dilute solution of polyacrylamide. Then, polystyrene shell has been produced on polyacryamide particles by in-situ polymerization of styrene monomer in hydrophobic... 

    Experimental Investigation of Formation Damage Caused by Polymer Mud

    , M.Sc. Thesis Sharif University of Technology Mahdipoor, Morteza (Author) ; Shad, Saeed (Supervisor)
    Abstract
    In oil industry, increment of drilling mud viscosity is of great importance. Water based polymers are widely use as drilling fluid to achieve this goal. Formation damages can be occurred by invading polymer solution into the formation in different ways such as scale and precipitation. These damages appear in different shapes such as reduction in relative permeability and productivity index reduction. In this study we have proposed, designed and fabricated a novel device, called sand pack, to measure the damage of the reservoir which enable us to calculate relative permeability and recovery factor by means of pressure difference and flow rate. Using this lab-scaled device we have measured... 

    Study on Viscoelastic Fluid Flow in Channels with Dead End and Valuation in Micro Model

    , Ph.D. Dissertation Sharif University of Technology Kamyabi, Ata Allah (Author) ; Ramazani Saadatabadi, Ahmad (Supervisor)
    Abstract
    It is about half century passed from the invention and application of the polymer flooding. Although there are successful reports from the using polymer flooding, but there are problems that in some cases this process fails. For more insight on the problems and in order to improve
    the efficiency of this process the conceptual understanding of the process is required. More conceptual understanding from this process, requires investigation in pore scale. In the presenting investigation, the flow of Newtonian and non-Newtonian fluids in the single phase and two phase form and in pore scale are simulated using finite volume method. Because, the finite volume method is used in very... 

    Study of Hole Pressure Effect on the Oil Recovery from Dead Ends in Polymer Flooding in Petroleum Reservoirs

    , M.Sc. Thesis Sharif University of Technology Zirrahi, Mohsen (Author) ; Ramezani Saadat Aabadi, Ahmad (Supervisor)
    Abstract
    Most of residual oil is difficult to displace and recover during water flooding process. One of the most important chemical flooding processes is polymer flooding that can improve microscopic and macroscopic sweep efficiency. Since, a large percent of reservoirs rocks is consisted of the dead ends in which oil remains immobile during water flooding, study of sweep efficiency from dead ends is important to improve oil recovery efficiency. In this study, effects of polymer flooding on oil recovery from dead end in glass micromodel have been studied experimentally and obtained results are compared with those of simulation of polymeric fluids in this micromodel. A correlation has been presented... 

    Effect of small scale flow barriers heterogeneities and connate water on displacement efficiency of polymer floods to heavy oil reservoirs

    , Article Canadian Journal of Chemical Engineering ; Vol. 91, issue. 10 , October , 2013 , p. 1729-1740 ; ISSN: 00084034 Mohammadi, S ; Ghazanfari, M. H ; Masihi, M ; Vossoughi, S ; Sharif University Of Technology
    Abstract
    This work concerns a fundamental understanding of how heterogeneities induced by flow barriers and connate water affect the displacement efficiency of polymer floods, which has rarely been studied in the available literature. Here, a series of water/polymer injection experiments to heavy oil performed on five-spot glass micromodels containing randomly distributed shale structures is presented. It has been found that macroscopic efficiency of polymer flooding majorly depends on flow barriers distribution/configuration; shale content and geometrical characteristics; presence of connate water and wettability of medium. Microscopic pictures revealed that the main parts of connate water were... 

    Analysis of Capillary-Viscous-Gravity Forces in Biopolymer Flooding with a Sensitivity Analysis on Polymer and Porous Medium Parameters

    , Article Journal of Dispersion Science and Technology ; Vol. 35, issue. 12 , Aug , 2014 , p. 1764-1773 Hamidpour, E ; Mirzaei-Paiaman, A ; Ramazani, S. A. A ; Hatami, A ; Sharif University of Technology
    Abstract
    Gravity, viscous, and capillary are three main forces affecting flow characteristics in porous media. No analytical solution can be found to model the flow by considering all these forces. In this work, by considering all these forces, the polymer-flooding process is modeled by using a numerical simulation approach. For characterizing the polymer, the modified Blake-Kozeny model is chosen, which benefits consideration of the permeability reduction due to polymer adsorption on the rock surface  

    Experimental Investigation of Polymer Flooding for more Heavy Oil Recovery; Comparing to the Thermal EOR Method

    , M.Sc. Thesis Sharif University of Technology Ashoorian, Sefatallah (Author) ; Ayatollahi, Sahab (Supervisor) ; Masihi, Mohsen (Supervisor)
    Abstract
    Heavy oil reservoirs are becoming more important as the oil price increase and more light oil reservoirs are being depleted. Thermal oil recovery, especially steam flooding is considered as the most efficient EOR technique for heavy oil reservoirs that stays on the top of the recent EOR field experiences. However this method is not applicable in some reservoir conditions like deep reservoirs or reservoirs with thin pay zones.
    Due to sever viscous fingering during water flooding heavy oil reservoirs, a large amount of oil would remain untouched in the reservoir. Polymer flooding could be a potential method for enhanced oil recovery by improving sweep efficiency. However there haven’t been... 

    Preparation of Polyacrylamide Nanoparticle with Nanoscale Coating to Control Solubility of Polymer during Polymer Flooding Process

    , M.Sc. Thesis Sharif University of Technology Tamsilian,Yousef (Author) ; Ramezani Saadat, Ahmad (Supervisor)
    Abstract
    Hydrophilic polymers are widely used in enhanced oil recovery (EOR) processes to increase water viscosity during polymer flooding. However, these polymers increase the viscosity of injected water in undesirable strands, before reaching considerable positions that make some problems in polymer flooding process such as thermal, mechanical, bacterial degradation, surface absorption and undesirable plugging. In this study, a novel core-shell structure of polyacrylamide as an active polymer and nanoscale coating polystyrene as a shell polymer was designed and prepared to intelligently control mobility ratio in oil reservoirs and overcome weakness and limitations of classical polymer flooding.... 

    Experimental Investigation of Polymer Type and Concentration on the Oil Recovery in Polymer Flooding Process

    , M.Sc. Thesis Sharif University of Technology Bamzad, Vahid (Author) ; Ramazani Saadatanadi, Ahmad (Supervisor) ; Masihi, Mohsen (Supervisor)
    Abstract
    Most of Iranian oil reservoirs, usually fractured carbonate, are in the end of primary or secondary recovery. Enhanced oil recovery methods are required for obtaining more performance from these resources. It seems to obtain more oil from reservoirs by flooding polymer after water flooding due to persistence of polymer effect, so the cost remain low. In this project, at the first the theory of water flooding and polymer flooding is described and after that we have done the following steps: •Injection of water into the plugs and calculate secondary recovery •Injection of polymer samples with 700 ppm concentration into the plugs •Injection of polymer samples with 1500 ppm concentration into... 

    Investigation of Rheological Behavior of Polymer on EOR in Carbonate Reservoir

    , Ph.D. Dissertation Sharif University of Technology Nourani, Meysam (Author) ; Ramazani Saadat Abadi, Ahmad (Supervisor) ; Emadi, Mohammad Ali (Supervisor)
    Abstract
    The major objectives of this study are to analytically and experimentally investigate the rheological behavior of polymers in the fractured carbonate medium based on the polymer solution properties and operational conditions. The intrinsic and apparent viscosity of high molecular weight-partially hydrolyzed poly (acrylamide) which is mainly used in enhanced oil recovery (EOR) processes hasbeen investigated in reservoir conditions. Since, the EOR efficiency of hydrolyzed poly (acrylamide) is very sensitive to the temperature and salinity of petroleumreservoirs; investigations have been carried out at different possible reservoirtemperatures using high saline polymer solutions. The parameters... 

    The Investigation of Thermal and Rheological Properties of Hydrophobically Modified Polymer of Acrylamide

    , M.Sc. Thesis Sharif University of Technology Shahin Varnousfaderani, Ali (Author) ; Ramazani Saadatabadi, Ahmad (Supervisor)
    Abstract
    Among chemically enhanced oil recovery (CEOR) methods, polymer flooding has the highest commercial potential. However, the most widely used conventional polymers such as partially hydrolyzed polyacrylamide (HPAM) are not applicable for high-temperature and high-salinity reservoirs. To overcome above-mentioned problems, in this work, a series of water-soluble hydrophobically modified polymers (HMPs) nanostructures comprising 2-vinyl naphthalene (hydrophobic monomer) has been produced by freestyle method (without Surfactant), micellar (with Surfactant). The size of the particles was investigated using scanning electron microscopy (FE-SEM) and optical scattering (DLS). Results from FT-IR... 

    Experimental investigation of flooding hydrolyzed-sulfonated polymers for EOR process in a carbonate reservoir

    , Article Petroleum Science and Technology ; Vol. 32, issue. 9 , Mar , 2014 , p. 1114-1122 ; ISSN: 10916466 Bamzad, S ; Nourani, M ; Ramazani, A ; Masihi, M ; Sharif University of Technology
    Abstract
    The main purposes of this study were to scrutinize experimentally effects of polymer and rock types on the oil recovery using water and polymer flooding processes. Four dynamic flooding experiments were carried out at simulated reservoir condition of temperature and pressure. According to the obtained results, the ultimate oil recovery by water flooding in highly fractured reservoirs was less than reservoirs with the microfractures. The results of polymer flooding showed that in addition the polymer molecular weight, the sulfonation of polymers also affects the oil recovery  

    Experimental investigation of microscopic/macroscopic efficiency of polymer flooding in fractured heavy oil five-spot systems

    , Article Journal of Energy Resources Technology, Transactions of the ASME ; Volume 135, Issue 3 , 2013 ; 01950738 (ISSN) Sedaghat, M. H ; Ghazanfari, M. H ; Parvazdavani, M ; Morshedi, S ; Sharif University of Technology
    2013
    Abstract
    This paper concerns on experimental investigation of biopolymer/polymer flooding in fractured five-spot systems. In this study, a series of polymer injection processes were performed on five-spot glass type micromodels saturated with heavy crude oil. Seven fractured glass type micromodels were used to illustrate the effects of polymer type/concentration on oil recovery efficiency in presence of fractures with different geometrical properties (i.e., fractures orientation, length and number of fractures). Four synthetic polymers as well as a biopolymer at different levels of concentration were tested. Also a micromodel constituted from dead-end pores with various geometrical properties was... 

    Effect of brine salinity and hydrolyzed polyacrylamide concentration on the Oil/Brine and Brine/Rock Interactions: Implications on enhanced oil recovery by hybrid low salinity polymer flooding in sandstones

    , Article Fuel ; Volume 324 , 2022 ; 00162361 (ISSN) Amiri, M ; Fatemi, M ; Biniaz Delijani, E ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    The main idea behind the application of Low salinity polymer flooding (LSPF) enhanced oil recovery (EOR) method is that diluted brine improves the oil recovery by wettability alteration from oil-wet (OW) towards water-wet (WW) condition, while polymer enhances the mobility of the displacing phase. However the possible effect of polymer on the fluid/fluid and fluid/rock interactions are not investigated systematically in the literature. The main objective of the present reserach is to examine the possible effect of hybrid application of low-salinity and polymer on the brine/rock and brine/oil interfaces properties. Formation water (FW) and sea water (SW) and its two different dilutions, i.e.... 

    Characterizing the Role of Shale Geometry and Connate Water Saturation on Performance of Polymer Flooding in Heavy Oil Reservoirs: Experimental Observations and Numerical Simulations

    , Article Transport in Porous Media ; Volume 91, Issue 3 , 2012 , Pages 973-998 ; 01693913 (ISSN) Mohammadi, S ; Masihi, M ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    Many heavy oil reservoirs contain discontinuous shales which act as barriers or baffles to flow. However, there is a lack of fundamental understanding about how the shale geometrical characteristics affect the reservoir performance, especially during polymer flooding of heavy oils. In this study, a series of polymer injection processes have been performed on five-spot glass micromodels with different shale geometrical characteristics that are initially saturated with the heavy oil. The available geological characteristics from one of the Iranian oilfields were considered for the construction of the flow patterns by using a controlled-laser technology. Oil recoveries as a function of pore... 

    In Situ Preparation of Acrylamide-Styrene- Maleic Anhydride Nano Hydrogels and Investigation of their Properties

    , M.Sc. Thesis Sharif University of Technology Lalehgani, Zahra (Author) ; Ramazani Saadatabadi, Ahmad (Supervisor)
    Abstract
    Among the methods for increasing chemical oil extraction,the polymeric flood method has the most commercialization capability.However,most commonly used polymers such as Hydrolyzed Polyacrylamide (HPAM) are not able to withstand high levels of salinity and high temperatures.To overcome these problems,in this project,new types of polymer nanostructures were synthesized with hydrophobic groups consisting of styrene (hydrophilic monomer) and malic anhydride (hydrophilic monomer) acrylamide (hydrophilic monomer). These polymers were synthesized by reversible mini-emulsion by adjusting the synthesis conditions for the purpose of producing the terpolymer with suitable conditions for tolerating... 

    Preparation of Hydrophobically Modified Copolymer Nanostructures as Viscosity Increasing Agents for Enhanced Oil Recovery

    , Ph.D. Dissertation Sharif University of Technology Shaban, Masoom (Author) ; Ramazani Saadatabadi, Ahmad (Supervisor) ; Ahadian, Mohammad Mahdi (Supervisor)
    Abstract
    Among chemical enhanced oil recovery (CEOR) methods, polymer flooding has the highest commercial potential. However, the most widely used conventional polymers such as partially hydrolyzed polyacrylamide (HPAM) are not applicable for high temperature and high-salinity reservoirs. To overcome above mentioned problems, in this work, a series of water- soluble hydrophobically modified polymers (HMPs) nanostructures comprising styrene (hydrophobic monomer) and acrylamide (hydrophilic monomer) have been produced. The copolymers have been synthesized using inverse miniemulsion synthesis method by adjusting synthesis conditions to optimize solution characteristic of copolymers for applying under... 

    Simultaneous/sequential alkaline-surfactant-polymer flooding in fractured/non-fractured carbonate reservoirs

    , Article Canadian Journal of Chemical Engineering ; Vol. 92, issue. 5 , May , 2014 , p. 918-927 ; ISSN: 00084034 Sedaghat, M. H ; Ghazanfari, M. H ; Masihi, M ; Sharif University of Technology
    Abstract
    Alkaline-Surfactant-Polymer flooding is one of the most novel chemical enhanced oil recovery methods in the petroleum industry. This method has attracted interest due to its remarkable advantages. In this work, a series of ASP floods are conducted on fractured/non-fractured carbonate rocks. The performance of the tests was investigated by various ASP floods consisting of five types of polymers, two surfactants and one common alkaline. ASP was flooded simultaneously and sequentially in four defined scenarios after water flooding. The results showed that although using hydrolysed polymers increases the recovery factor in the fractured medium, sulfonated polymers increase oil recovery even more...