Sharif Digital Repository

CO 2 removal from synthesis gas to reduce emission in the atmosphere was studied using physical absorption with the Selexol solvent. Variances of 2-5 separator units and various pressure drop patterns were utilized. Simulation results showed that the case with 4 separators and uniform pressure drop distribution leads to the optimum design, in terms of capital and operational expenditures. Since the cost model for compressors, heat exchangers and coolers is a direct function of energy consumed, the capital expenditure was optimized simultaneously with operational expenditure, and the CAPEX/OPEX analysis reflects this matter as well. This is an abstract of a paper presented at the 19th... 

An analysis of carbon dioxide (CO2) removal process from synthesis gas has been carried out in this work. CO2 removals by physical and chemical solvents are the most often used. The most important factors that affect cost and performance of a CO2 recovery unit are the number of flash drum separation units, and the pressure drop pattern among them. Different variations of this process were simulated using Hysys software, and the capital and operational expenditures for these plants were estimated. The focus was to reach an optimum process to minimize the total unit cost of separated CO2. The results indicate that for a fixed number of separation units, the case with uniform pressure drop... 

Hexagonal array of Cu@CuO core-shell nanoparticles (NPs) on the a-C:H thin film was prepared by codeposition of RF-sputtering and RF-PECVD. The trace of hexagonal NPs supperlattice was recognized by AFM image and XRD result. On the basis of localized surface plasmon resonance (LSPR) of core-shell NPs, the prepared array detected a low flow rate of CO gas at room temperature. XPS results indicate that the surface of Cu@CuO core-shell NPs have no chemical reaction with CO molecule. The physical absorption of CO molecule on the surface of Cu@CuO core-shell NPs increases the LSPR absorbance and causes a red shift in LSPR wavelength. These experimental results are in agreement with Mie theory... 

The effects of addition of an ionic liquid to pure water as a physical absorbent and monoethanolamine (MEA) solutions as a chemical absorbent on carbon dioxide (CO2) absorption through hollow fiber membrane contactors were investigated using a 2D axisymmetric model. A numerical simulation was developed based on finite element method using computational fluid dynamics techniques. Liquid phase flowed in the tube side and gas mixture containing CO2 passed in the shell side of the membrane contactor in co-current and countercurrent modes. The simulation results are consistent with experimental data, and the root-mean-square error was calculated as 9 and 13% for pure water and 25 wt % for ionic...