Sharif Digital Repository

2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) as one of the high energy cage nitramines has been used in various propellants and explosive formulations. The performance of energetic materials depends on its particle size and shape. Therefore, in this research, microemulsion method has been applied for the preparation of CL-20 nanoparticles via oil in water (O/W) microemulsions. The optimized formulation contains water 45%, n-butyl acetate 20.5%, sodium dodecyl sulfate (SDS, as anionic surfactant) 6.5% and 2-propanol (as co-surfactant) 26.5%. CL-20 nanoparticles that were obtained by microemulsion method are spherical with an average diameter of 25 nm, based on TEM image.... 

In this study the effect of HPGR operational parameters on the dimensional properties of pellet feed was examined and optimized using factorial methodology. The operational parameters considered include feed moisture, specific pressure and roll speed. For this study, size and shape of particles with Blaine number in the range 1800–2200 cm2 g−1 was thoroughly investigated. It was deduced that increasing the specific pressure and decreasing the roll speed would result in reduction of D80 but would increase the Blaine number. The circularity, aspect ratio and roughness descriptors of the particles were measured by SEM micrographs and image analysis software. It was observed that particles... 

In this study the effect of HPGR operational parameters on the dimensional properties of pellet feed was examined and optimized using factorial methodology. The operational parameters considered include feed moisture, specific pressure and roll speed. For this study, size and shape of particles with Blaine number in the range 1800–2200 cm2g−1 was thoroughly investigated. It was deduced that increasing the specific pressure and decreasing the roll speed would result in reduction of D80 but would increase the Blaine number. The circularity, aspect ratio and roughness descriptors of the particles were measured by SEM micrographs and image analysis software. It was observed that particles tended... 

Particle size and shape of iron ore concentrate are effective parameters in the production of quality green pellets. In this research, the effect of particle morphology on green pellet quality was studied. It was concluded that pellet quality improved with increasing specific surface area. Drop number and green compression strength of pellets ground by HPGR were found to be superior over those ground in the ball mill. The chief reasons were related to particle shape and the fraction of fine particles. Smaller particle size results in a higher order of bonding between particles and therefore the formation of a stronger system. Also, the rougher and less circular shape of particles resulted in... 

A simplified model based on cohesive energy is proposed to estimate the formation energy of Schottky vacancies (VFE) in free-standing metal nanoparticles with BCC and FCC crystal structures. To study the effect of particle size and shape, the surface energy, elastic contraction and average coordination number of particles at the surface and core was considered. It is shown that the energy of vacancy formation in FCC nanoparticles increases with decreasing the size while the effect of particle shape (sphere, cubic and icosahedral) is marginal. In spite of this behavior, BCC nanoparticles exhibit a critical particle size at around 25 Å, at which a minimum VFE is attained. Additionally, the...