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Polymer-Supported Bis-1,2,4-triazolium ionic tag framework for an efficient Pd(0) catalytic system in biomass derived γ-valerolactone
, Article ACS Sustainable Chemistry and Engineering ; Volume 7, Issue 7 , 2019 , Pages 6939-6946 ; 21680485 (ISSN) ; Mahmoudi, H ; Bivona, L. A ; Piermatti, O ; Bagherzadeh, M ; Fusaro, L ; Aprile, C ; Marrocchi, A ; Vaccaro, L ; Sharif University of Technology
American Chemical Society
2019
Abstract
A resin-bound 1,2,4-triazolium ionic tag has been used as support for the preparation of solid palladium nanoparticles (Pd(0)-POLI-TAG-Pd). Owing to the pincer-type architecture of the triazolium ligand, the stabilization of a high amount of palladium nanoparticles (16 wt %) has been possible. The catalytic system has been fully characterized and used in low amounts (i.e., 0.1 mol % palladium loading) in representative Heck-Mizoroki cross-coupling processes. A negligible release of the metal was demonstrated, and a high activity was obtained over more runs. Besides, the protocol has been optimized for the use of safe biomass-derived γ-valerolactone reaction medium
Hydro-purification of crude terephthalic acid using palladium catalyst supported on multi-wall carbon nanotubes
, Article Journal of Industrial and Engineering Chemistry ; 2015 ; ISSN: 1226086X ; Khorasheh, F ; Rashidi, A. M ; Safekordi, A. A ; Sharif University of Technology
Abstract
Palladium catalysts supported on functionalized multi-wall carbon nanotubes were synthesized for hydro-purification of crude terephthalic acid containing 2100ppm 4-carboxybenzaldehyde (4-CBA) as impurity. PdCl2 and Pd(OAc)2 were used as precursors. Palladium loadings were 0.05 to 0.6wt.% with catalysts reduced at 200 to 400°C. Catalysts prepared from both precursors with least 0.3wt.% palladium resulted in 99%+ removal of 4-CBA. The most desired selectivity was obtained for the catalyst with PdCl2 as precursor, reduction temperature of 300°C, and palladium loading of 0.3wt.%. This catalyst had slightly better performance than the commercial catalyst (0.5wt.% of palladium on activated carbon)...
Hydro-purification of crude terephthalic acid using palladium catalyst supported on multi-wall carbon nanotubes
, Article Journal of Industrial and Engineering Chemistry ; Volume 28 , August , 2015 , Pages 202-210 ; 1226086X (ISSN) ; Khorasheh, F ; Rashidi, A. M ; Safekordi, A. A ; Sharif University of Technology
Korean Society of Industrial Engineering Chemistry
2015
Abstract
Palladium catalysts supported on functionalized multi-wall carbon nanotubes were synthesized for hydro-purification of crude terephthalic acid containing 2100ppm 4-carboxybenzaldehyde (4-CBA) as impurity. PdCl2 and Pd(OAc)2 were used as precursors. Palladium loadings were 0.05 to 0.6wt.% with catalysts reduced at 200 to 400°C. Catalysts prepared from both precursors with least 0.3wt.% palladium resulted in 99%+ removal of 4-CBA. The most desired selectivity was obtained for the catalyst with PdCl2 as precursor, reduction temperature of 300°C, and palladium loading of 0.3wt.%. This catalyst had slightly better performance than the commercial catalyst (0.5wt.%...