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    Effect of water salinity on oil/brine interfacial behaviour during low salinity waterflooding: A mechanistic study

    , Article Petroleum ; Volume 5, Issue 4 , 2019 , Pages 367-374 ; 24056561 (ISSN) Rostami, P ; Fattahi Mehraban, M ; Sharifi, M ; Dejam, M ; Ayatollahi, S ; Sharif University of Technology
    KeAi Communications Co  2019
    Abstract
    In recent years, controlling the salinity and composition of the injected water has become an emerging enhanced oil recovery (EOR) technique, often described as low salinity (LS) waterflooding. This work is done with the intention to contribute to the ongoing discussions about LS waterflooding mechanism(s). For this purpose, a series of different experiments were conducted. At first, the effect of salinity on the interfacial tension (IFT) and the contact angle was evaluated with a crude oil sample. Then to achieve more accurate results in observing oil/water interface, similar IFT experiments were also carried out on a synthetic oil containing asphaltenes. Thereafter, microscopic... 

    The non-linear effect of oil polarity on the efficiency of low salinity waterflooding: A pore-level investigation

    , Article Journal of Molecular Liquids ; January , 2021 ; 01677322 (ISSN) Golmohammadi, M ; Mohammadi, S ; Mahani, H ; Ayatollahi, S ; Sharif University of Technology
    Elsevier B. V  2021
    Abstract
    Oil polarity is an important property impacting the efficiency of low salinity waterflooding (LSWF). It directly affects fluid/fluid and rock/fluid interactions, controlling the interfacial properties and forces. However, the current findings in the literature on the effect of concentration of polar components on oil recovery by LSWF are contradictory. Therefore, the main objective of this paper is to investigate how the type of non-polar fractions and the concentration of acidic polar oil constituents change the trapped oil saturation at the pore-scale during LSWF. In this regard, we conducted a series of microfluidics LSWF experiments in both secondary and tertiary modes, using clay-free... 

    Novel experimental evidence on the impact of surface carboxylic acid site density on the role of individual ions in the electrical behavior of crude oil/water

    , Article Journal of Molecular Liquids ; Volume 362 , 2022 ; 01677322 (ISSN) Farhadi, H ; Mahmoodpour, S ; Ayatollahi, S ; Fatemi, M ; Sharif University of Technology
    Elsevier B.V  2022
    Abstract
    Perceiving the electrical behavior of the rock/brine and the crude oil/brine interfaces gives insight into the performance of engineered waterflooding. Compared to the rock surface, few studies have attempted to comprehend the complex behavior of the crude-oil surface electrical behavior. To reveal the impact of each ion on the surface charge of crude oil, the zeta potential of crude oil/single-salt brines (including NaCl, CaCl2, MgCl2, Na2SO4, and NaHCO3) was measured in a wide range of salinity. Then, the counterpart interfacial tension (IFT) was measured to determine the capability of each brine in bringing carboxylic acid groups from crude-oil bulk (COOH) to crude oil/brine interface... 

    The non-linear effect of oil polarity on the efficiency of low salinity waterflooding: A pore-level investigation

    , Article Journal of Molecular Liquids ; Volume 346 , 2022 ; 01677322 (ISSN) Golmohammadi, M ; Mohammadi, S ; Mahani, H ; Ayatollahi, S ; Sharif University of Technology
    Elsevier B.V  2022
    Abstract
    Oil polarity is an important property impacting the efficiency of low salinity waterflooding (LSWF). It directly affects fluid/fluid and rock/fluid interactions, controlling the interfacial properties and forces. However, the current findings in the literature on the effect of concentration of polar components on oil recovery by LSWF are contradictory. Therefore, the main objective of this paper is to investigate how the type of non-polar fractions and the concentration of acidic polar oil constituents change the trapped oil saturation at the pore-scale during LSWF. In this regard, we conducted a series of microfluidics LSWF experiments in both secondary and tertiary modes, using clay-free...