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    Pore Scale Modeling and Upscaling of Non-Aqueous Phase Liquid Dissolution, Flow and Distribution in Heterogeneous Porous Media

    , M.Sc. Thesis Sharif University of Technology Khasi, Saeed (Author) ; Ghazanfari, Mohammad Hossein (Supervisor)
    Abstract
    In this work, flow transport, distribution, and dissolution of non-aqueous phase liquids (NAPLs) in heterogeneous porous media were modeled by focusing on the dissolution process in pore-level and field scale. First, by adopting advection-diffusion and mass transfer equations, dissolution process and NAPL distribution were investigated in a heterogeneous porous media using pore network modeling. The 2-D developed model was based on observations of micromodel tests. The pore scale simulator which adopted by this work was improved in some aspects in comparison to previous models in the literatures. First, in the phase displacement, by considering more realistic geometries for pore structure... 

    Numerical Simulation of Non-Aqueous and Dissolved Petroleum Hydrocarbon Transport in Groundwater

    , M.Sc. Thesis Sharif University of Technology MahmoodiNobar, Farzad (Author) ; Ataie Ashtiani, Behzad (Supervisor)
    Abstract
    Within the past few years, soil and groundwater resources contamination by petroleum-based products has become of great concern in the environmental engineering literature as a serious environmental problem throughout the world. Amongst petroleum hydrocarbons, groundwater contamination by Non-Aqueous Phase Liquids (NAPLs) is one of the most important environmental problems. In order to effectively remediate contaminated sites, knowledge of the distribution of the NAPLs is essential. The success of the remedial design will be dependent on the ability to predict the subsurface distribution of the NAPLs. Release of these compounds from spills and leaky underground storage tanks into subsurface... 

    Pore Scale Experimental Study of Non-Aqueous Phase Liquid Dissolution, Flow and Distribution in Heterogeneous Porous Media

    , M.Sc. Thesis Sharif University of Technology Ramezanzadeh, Mehdi (Author) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Fatemi, Mobeen (Co-Supervisor)
    Abstract
    In this work, a pore-scale analysis of nonaqueous phase liquid (NAPL) flow, transport, dissolution, and mobilization in heterogeneous and homogeneous porous media was presented. First, dissolution processes and distribution of NAPL phase were investigated using micromodel experiments. The tests were conducted at different injection rates in NAPL-saturated porous media using distilled water, surfactant, and nanoparticles-assisted surfactant. Changes in residual NAPL volume and interfacial area were measured using image analysis method to calculate the mass transfer coefficient, k, and the lumped mass transfer rate coefficient, K. Based on the experimental results, empirical Sherwood... 

    Physical Modeling of Bioremediation of Gasoline Spill in the Vadose Zone

    , M.Sc. Thesis Sharif University of Technology Rahimi, Behnam (Author) ; Sadeghi, Hamed (Supervisor) ; Moghimi, Hamid (Co-Supervisor)
    Abstract
    Oil pollutants are among the important sources of pollution in countries with oil and gas industries such as Iran. Soil pollution by these pollutants is one of the environmental issues and hazards. All kinds of organic and inorganic pollutants in the soil may penetrate the underground water or enter the atmosphere in the form of gas, which respectively enters the food chain through absorption by plants or enter the body of living organisms through breathing. They include humans, which are a threat to the health and life of living beings. For example, many of these pollutions cause diseases such as cancer, suppression of the body's immune system, or even obesity; therefore, it is necessary to... 

    Dissolution and remobilization of NAPL in surfactant-enhanced aquifer remediation from microscopic scale simulations

    , Article Chemosphere ; Volume 289 , 2022 ; 00456535 (ISSN) Ramezanzadeh, M ; Aminnaji, M ; Rezanezhad, F ; Ghazanfari, M. H ; Babaei, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    In this paper, the dissolution and mobilization of non-aqueous phase liquid (NAPL) blobs in the Surfactant-Enhanced Aquifer Remediation (SEAR) process were upscaled using dynamic pore network modeling (PNM) of three-dimensional and unstructured networks. We considered corner flow and micro-flow mechanisms including snap-off and piston-like movement for two-phase flow. Moreover, NAPL entrapment and remobilization were evaluated using force analysis to develop the capillary desaturation curve (CDC) and predict the onset of remobilization. The corner diffusion mechanism was also applied in the modeling of interphase mass transfer to represent NAPL dissolution as the dominant mass transfer... 

    Remediation of trapped DNAPL enhanced by SDS surfactant and silica nanoparticles in heterogeneous porous media: experimental data and empirical models

    , Article Environmental Science and Pollution Research ; Volume 27, Issue 3 , 2020 , Pages 2658-2669 Ramezanzadeh, M ; Khasi, S ; Fatemi, M ; Ghazanfari, M. H ; Sharif University of Technology
    Springer  2020
    Abstract
    The remediation of nonaqueous phase liquids (NAPLs) enhanced by surfactant and nanoparticles (NP) has been investigated in numerous studies. However, the role of NP-assisted surfactants in the dissolution process is still not well discussed. Besides, there is a lack of empirical dissolution models considering the effects of initial residual saturation Strap, NAPL distribution, and surfactant concentration in NAPL-aqueous phase systems. In this work, micromodel experiments are conducted to quantify mass transfer coefficients for different injected aqueous phases including deionized water, SDS surfactant solutions, and NP-assisted solutions with different levels of concentrations and flow... 

    Experimentally based pore network modeling of NAPL dissolution process in heterogeneous porous media

    , Article Journal of Contaminant Hydrology ; Volume 228 , November , 2020 Khasi, S ; Ramezanzadeh, M ; Ghazanfari, M. H ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    Practical designs of non-aqueous phase liquids (NAPLs) remediation strategies require reliable modeling of interphase mass transfer to predict the retraction of NAPL during processes such as dissolution. In this work, the dissolution process of NAPL during two-phase flow in heterogeneous porous media is studied using pore-network modeling and micromodel experiments. A new physical-experimental approach is proposed to enhance the prediction of the dissolution process during modeling of interphase mass transfer. In this regard, the normalized average resident solute concentration is evaluated for describing the dissolution process at pore-level. To incorporate the effect of medium... 

    DNAPL flow and complex electrical resistivity evolution in saturated porous media: A coupled numerical simulation

    , Article Journal of Contaminant Hydrology ; Volume 248 , 2022 ; 01697722 (ISSN) Koohbor, B ; Deparis, J ; Leroy, P ; Ataie Ashtiani, B ; Davarzani, H ; Colombano, S ; Sharif University of Technology
    Elsevier B.V  2022
    Abstract
    Induced Polarization (IP) is a non-intrusive geophysical method to monitor Dense Non-Aqueous Phase Liquid (DNAPL) contamination and remediation processes underground. In this study, an advanced numerical code simulating DNAPL flow and complex electrical resistivity is presented. The model was validated against existing IP results and image measurements that were carried out previously in a series of 2D tank experiment. Multiphase flow modeling in porous media is coupled with electrical current modeling to simulate the process of DNAPL migration and the associated IP response. This brings a broader view of the contamination in space and time compared to surface and borehole measurements,...