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    Thermodynamic and environmental consideration of advanced gas turbine cycles with reheat and recuperator

    , Article International Journal of Environmental Science and Technology ; Volume 4, Issue 2 , 2007 , Pages 253-262 ; 17351472 (ISSN) Sheikhbeigi, B ; Ghofrani, M. B ; Sharif University of Technology
    CEERS  2007
    Abstract
    The role of gas turbine power plants in electrical energy production has been considerably increased in the last two to three decades. Various methods have been proposed to improve the performance of gas turbine cycles. In this research, two methods, a reheat cycle and a cycle with a reheat and a recuperator, were investigated and compared with a simple cycle. The main objective of this paper is to study the performance of an simple cycle and reheat cycle under actual conditions. In this regard, all processes are treated as actual, and in particular a relatively simple and reliable approach is used to predict the amount of cooling air. The results obtained on the basis of a model developed... 

    Experimental Study of Flameless Combustion

    , M.Sc. Thesis Sharif University of Technology Azimizadeh, Ehsaneddin (Author) ; Farshchi, Mohammad (Supervisor)
    Abstract
    Flameless Combustion was experimentally studied. In this combustion mode, inlet air is preheated and products are recirculated inside the chamber. Therefore, the reaction zone is spread from a limited front to a wider area with that of a lower peak temperature and very lower Nitrogen Oxides (NOx) production. Controllable parameters are preheating temperature, equivalence ratio, and fuel and air mass flow rates. Applying similar conditions, the flameless combustion was compared to the diffusion flame. Measurable parameters are exhaust temperature and composition, including NOx. Reaction zone homogeneity is observed by photographing inside the combustion chamber through its visual access... 

    Exposure Level of Vehicle Cabins to Particulate Matter and Gaseous Contaminations: Experimental Investigation and Theoretical Modeling of Influential Factors

    , M.Sc. Thesis Sharif University of Technology Saemian, Peyman (Author) ; Arhami, Mohammad (Supervisor)
    Abstract
    Mobile Sources are the main source of air pollutant emission in Tehran, the capital city of Iran. Everyday thousands of vehicles commute in roads and highways. Unfortunately, People are exposed to high level of particulate matter and gaseous contaminants in automobile cabins. Even though this environment is exposed to high pollutant concentration emitted by on-road vehicle, In comparison with other built environment, in-cabin commuter exposure and its key parameters has never been quantified. In general, this work entails measurement of in-cabin air quality, predicting mathematical models for calculating Air-Exchange-Rate (AER) in vehicles and on-road vehicle emission measurement. Our... 

    Numerical Evaluation of Engine Performance and Emission Characteristics of Rapeseed Oil and its Blends in Diesel Engines

    , M.Sc. Thesis Sharif University of Technology Saeedan, Mohammad (Author) ; Saeedi, Mohammad Hassan (Supervisor)
    Abstract
    Today, the importance of transportation and motor vehicles is crystal clear for everyone. On the other hand, energy crisis and the emissions of these vehicles are two fundamental problems of internal combustion motors. On account of this, the diesel vehicles have absorbed researchers’ attentions due to their higher efficiency and low fuel consumption.Due to high diesel vehicle efficiency, it is tried to substitute gasoline vehicles with these vehicles. In addition, the unrecyclable nature of fossil fuels has led to more attention to renewable energies such as biofuels. A lot of kinds of herbal oils have identical characteristics with diesel fuel.In this research, the combustion of Rapeseed... 

    Numerical Simulation of Reacting Flow in Large Scale Heavy Fuel Oil Fired Furnaces to Control Temperature Field and NOx Emission

    , M.Sc. Thesis Sharif University of Technology Fatin, Ali (Author) ; Darbandi, Masoud (Supervisor)
    Abstract
    Heavy fuel oil (HFO) is usually consumed in large scale furnaces, e.g., those of power plants. Experience shows that its combustion produces large amount of NOx emission. In present study, a large scale heavy fuel oil fired furnace is numerically simulated to investigate different possible solutions for NOx reduction. In this regard, a computational framework is firstly designed benefiting from the researches reported previously in literature. The results of this framework are then compared with available measurements to evaluate the accuracy of current designed computational framework. Second, the influences of a number of different controlling parameters are studied carefully to improve... 

    Optimization of Design Parameters for NOx Reduction in Combustion Process of an Effective Power Plants Burner

    , M.Sc. Thesis Sharif University of Technology Abdollahpour, Mohammad Saleh (Author) ; Mazaheri, Karim (Supervisor)
    Abstract
    In recent decade, pollution reduction is one of challenges in front of engineers. Nowadays accurate prediction of temperature and harmful Pollutants is vital, this leads to various models for turbulent combustion to predict combustion-generated pollutants. One of the most widely used models for simulating turbulent combustion is Flamelet because of separating the chemical reactions and the turbulent flow field. The unsteady state assumption of Flamelet model is capable of reasonably predict complicated phenomenon such as slow chemical reaction and radiation. The purpose of this study is to calculate combustion-generated emissions by Flamelet model and reduce these emissions by engineering... 

    Experimental and Numerical Study of Gas Turbine Model Combustor

    , M.Sc. Thesis Sharif University of Technology Rezapour-Rastaghi, Hamed (Author) ; Mardani, Amir (Supervisor)
    Abstract
    High Swirl Combustors can provide stable flames in wide range of operating conditions. Double swirl combustors, as one of the newest designs in this field, have particular effects on improving the efficiency of combustion chambers in terms of flame stability, mixing process quality and reducing combustion pollutants. In this study, a double swirl gas turbine combustor, SGTMC, which is redesigned version of a German combustor (GTMC), has been investigated. According to experimental section of this study, lean stability limits, UHCs, CO and NOx has been measured and analyzed. Results show that this burner can provide a stable flame even in very low equivalence ratios. Also in some specific... 

    Numerical Study of Oxygen Enrichment on NO Pollution Spread in an Ignition Chamber

    , M.Sc. Thesis Sharif University of Technology Orshesh, Zohreh (Author) ; Kazemzadeh Hannani, Siamak (Supervisor)
    Abstract
    In the present study, a 3D combustion chamber was simulated using FLUENT6.32. The objectives were to obtain detailed information on the combustion characteristics and NO formation in the furnace, and also to examine the effect of Oxygen enrichment on the combustion process. The combustion chamber has internal dimensions of 60 cm wide, 90 cm high and 190 cm long. The fuel pipe diameter is 1.25 cm and the air pipe diameter is 3.5 cm. The 3-D Reynolds Averaged Navier Stokes (RANS) equations together with standard k-ε turbulence model are solved by Fluent 6.3. Air/fuel flow rate ratio is varied as 1.3, 3.2 and 5.1 and the oxygen enriched flow rates are 28, 54, 68 lit/min. NO emission was... 

    Studies on Modeling of Bioreactors for Removal of Pollutants in Flue Gas

    , M.Sc. Thesis Sharif University of Technology Mousavi Shoushtari, Shimasadat (Author) ; Vosoughi, Manoochehr (Supervisor) ; Yaghmaei, Soheila (Supervisor)
    Abstract
    In present study, two bioreactors for biological and chemical removal of nitrogen oxides are modeled. Nitrogen oxides are of the most important pollutants in flue gas stream. These components are hazardous materials and could lead to acid rain, ground-level ozone, smog and the depletion of ozone layer. There are several methods for removing these pollutants which are categorized to two main groups: non-biological and biological methods. Biological removal has the advantage of removing the pollutants by an acceptable efficiency. In present study, two packed-bed bioreactors are modeled by the means of considering two kinds of biological removal mechanism in defined operating conditions. The... 

    Lean partially premixed combustion investigation of methane direct-injection under different characteristic parameters

    , Article ASME 2013 Internal Combustion Engine Division Fall Technical Conference, ICEF 2013, Dearborn, MI, 13 October 2013 through 16 October 2013 ; Volume 1 , 2013 ; 9780791856093 (ISBN) Askari, O ; Metghalchi, H ; Hannani, S. K ; Hemmati, H ; Ebrahimi, R ; Sharif University of Technology
    American Society of Mechanical Engineers (ASME)  2013
    Abstract
    The effects of hydrogen addition, diluent addition, injection pressure, chamber pressure, chamber temperature and turbulence intensity on methane-air partially premixed turbulent combustion have been studied experimentally using a constant volume combustion chamber (CVCC). The fuel-air mixture was ignited by centrally located electrodes at given spark delay times of 1, 5, 40, 75 and 110 milliseconds. Experiments were performed for a wide range of hydrogen volumetric fractions (0% to 40%), exhaust gas recirculation (EGR) volumetric fractions (0% to 25% as a diluent), injection pressures (30-90 bar), chamber pressures (1-3 bar), chamber temperatures (298-432 K) and overall equivalence ratios... 

    Personalized disease-specific protein corona influences the therapeutic impact of graphene oxide

    , Article Nanoscale ; Volume 7, Issue 19 , Apr , 2015 , Pages 8978-8994 ; 20403364 (ISSN) Hajipour, M. J ; Raheb, J ; Akhavan, O ; Arjmand, S ; Mashinchian, O ; Rahman, M ; Abdolahad, M ; Serpooshan, V ; Laurent, S ; Mahmoudi, M ; Sharif University of Technology
    Royal Society of Chemistry  2015
    Abstract
    The hard corona, the protein shell that is strongly attached to the surface of nano-objects in biological fluids, is recognized as the first layer that interacts with biological objects (e.g., cells and tissues). The decoration of the hard corona (i.e., the type, amount, and conformation of the attached proteins) can define the biological fate of the nanomaterial. Recent developments have revealed that corona decoration strongly depends on the type of disease in human patients from which the plasma is obtained as a protein source for corona formation (referred to as the 'personalized protein corona'). In this study, we demonstrate that graphene oxide (GO) sheets can trigger different... 

    An experimental and theoretical study of the effects of excess air ratio and waste gate opening pressure threshold on NOx emission and performance in a turbocharged CNG SI engine

    , Article International Journal of Engineering, Transactions B: Applications ; Volume 28, Issue 2 , March , 2015 , Pages 251-260 ; 1728-144X (ISSN) Kharazmi, S ; Benisi, A. H ; Mozafari ; Sharif University of Technology
    Materials and Energy Research Center  2015
    Abstract
    In this research, effects of excess air ratio and waste gate opening pressure threshold on NOx emission and performance in a turbocharged CNG SI engine are studied experimentally at 13-mode ECE-R49 test cycle. The engine power, boost ratio and charge air temperature are investigated experimentally at the cycle for different waste gate pressure thresholds. A code is developed in MATLAB environment for predicting engine performance and NOx and the results are validated with the research experiments. The effects of excess air ratio on the engine indicated power and specific fuel consumption as well as NOx emission are numerically investigated at WOT by the code. NOx emission of WOT is max at... 

    Exhaustive denitrification via chlorine oxide radical reactions for urea based on a novel photoelectrochemical cell

    , Article Water research ; Volume 170 , 2020 , Pages 115357- Shen, Z ; Zhang, Y ; Zhou, C ; Bai, J ; Chen, S ; Li, J ; Wang, J ; Guan, X ; Rahim, M ; Zhou, B ; Sharif University of Technology
    NLM (Medline)  2020
    Abstract
    Urea is a major source of nitrogen pollution in domestic sewage and its denitrification is difficult since it is very likely to be converted into ammonia or nitrate instead of expected N2. Herein, we propose an exhaustive denitrification method for urea via the oxidation of amine/ammonia-N with chlorine oxide radical, which induced from a bi-functional RuO2//WO3 anode, and the highly selective reduction of nitrate-N on cathode in photoelectrochemical cell (PEC). Under illumination, the WO3 photoanode side promotes the quantities hydroxyl and reactive chlorine radical, and these radicals are immediately combined to stronger chlorine oxide radical by RuO2 side, which obviously enhances the... 

    Simulation and designing of methanol production plant based on the synthesis gas

    , Article CHISA 2006 - 17th International Congress of Chemical and Process Engineering, Prague, 27 August 2006 through 31 August 2006 ; 2006 ; 8086059456 (ISBN); 9788086059457 (ISBN) Babazadeh, F ; Haddadi, A. M ; Kazemini, M ; Sharif University of Technology
    2006
    Abstract
    Regarding the energy and environment crisis in the current century and future that threatens human communities, necessity of study and use of supplement fuels is felt more than before. Consumption of natural gas has been increasing rapidly making it one of the most important energy resources in the world. During the last decade the consumption of natural gas increased by almost 25%. By 2020 natural gas is predicted to increase its world energy share to as much as 50% from the present of 22%. The scale of its reserves and its environmental advantage favor its use, (the lower carbon emissions compared to oil and coal along with other reduced emissions of nitrogen oxides and particulates) for... 

    Oxovanadium(IV) complexes as homogeneous catalyst-aerobic epoxidation of olefins

    , Article Applied Catalysis A: General ; Volume 278, Issue 2 , 2005 , Pages 263-267 ; 0926860X (ISSN) Mohebbi, S ; Boghaei, D. M ; Sarvestani, A. H ; Salimi, A ; Sharif University of Technology
    2005
    Abstract
    The novel N2O2 unsymmetrical tetradentate Schiff bases complexes are used as catalysts for the selective aerobic oxidation of cyclohexene. In general, conversion percentages decrease with increasing ΔEp and decreasing Eredox 0′. Catalytic activity increases with decrease of the number of electron-donating groups and the catalytic selectivity varies according to the types of substituents in the ligands. The catalytic system described here is an inexpensive method for selective oxidation of olefins, with advantages of high activity, selectivity, re-usability and short reaction times. Analysing GC and redox potential results shows a moderate correlation between selectivity and activity. © 2004... 

    Use of computer-assisted methods for the modeling of the retention time of a variety of volatile organic compounds: A PCA-MLR-ANN approach

    , Article Journal of Chemical Information and Computer Sciences ; Volume 44, Issue 4 , 2004 , Pages 1328-1335 ; 00952338 (ISSN) Jalali Heravi, M ; Kyani, A ; Sharif University of Technology
    2004
    Abstract
    A hybrid method consisting of principal component analysis (PCA), multiple linear regressions (MLR), and artificial neural network (ANN) was developed to predict the retention time of 149 C3 - C12 volatile organic compounds for a DB-1 stationary phase. PCA and MLR methods were used as feature-selection tools, and a neural network was employed for predicting the retention times. The regression method was also used as a calibration model for calculating the retention time of VOCs and investigating their linear characteristics. The descriptors of the total information index of atomic composition, IAC, Wiener number, W, solvation connectivity index, Xlsol, and number of substituted aromatic... 

    Theoretical and Experimental Investigation of NOx Reduction in a CNG Turbocharged Internal Combustion Engines

    , Ph.D. Dissertation Sharif University of Technology Kharazmi, Shahaboddin (Author) ; Mozaffari, Ali Asghar (Supervisor) ; Hajilouy Benisi, Ali (Supervisor)
    Abstract
    Combustion and NOx emissions were simulated by quasi-dimensional and ratereaction methods respectively in a turbocharged CNG engine. Mean-value turbulence modeling was carried out during compression and combustion processes to simulate combustion process better. The most appropriate NG flame speed for the CNG turbocharged engine was applied and ignition delay was ended when flame radius became more than turbulence integral length scale. Hemispherical flame propagated from spark gap center and its intersection with reciprocating Mexican-hat piston bowl was calculated analytically. Thermal boundary layer, as a novel approach, was considered in the simulation and a better agreement of predicted... 

    Detailed analysis of the effects of biodiesel fraction increase on the combustion stability and characteristics of a reactivity‐ controlled compression ignition diesel‐biodiesel/natural gas engine

    , Article Energies ; Volume 15, Issue 3 , 2022 ; 19961073 (ISSN) Zarrinkolah, M. T ; Hosseini, V ; Sharif University of Technology
    MDPI  2022
    Abstract
    A single‐cylinder marine diesel engine was modified to be operated in reactivity controlled compression ignition (RCCI) combustion mode. The engine fueling system was upgraded to a common rail fuel injection system. Natural gas (NG) was used as port fuel injection, and a die-sel/sunflower methyl ester biodiesel mixture was used for direct fuel injection. The fraction of bio-diesel in the direct fuel injection was changed from 0% (B0; 0% biodiesel and 100% diesel) to 5% (B5) and 20% (B20) while keeping the total energy input into the engine constant. The objective was to understand the impacts of the increased biodiesel fraction on the combustion characteristics and stability, emissions, and... 

    Modeling of Ground-Level Ozone Concentrations in Tehran using CMAQ Model

    , M.Sc. Thesis Sharif University of Technology Hossein Nia, Bardia (Author) ; Arhami, Mohammad (Supervisor)
    Abstract
    Every year, air pollution is causing immense harm to humans and the environment. To cause Air pollution, several factors are involved. Among these are the sources of emissions such as factories, power plants and Cars, meteorological factors such as temperature and wind speed and geographical conditions such as altitude, postal and looming around the area, land slope and soil type region. The aim of this study is to identify factors that affect the ozone concentration in Tehran, which could help identifying other secondary pollutants. For this purpose, a combination tailored to the geography of Tehran using CMAQ-WRF-SMOKE-made programs. This model includes four intervals each of which lasting... 

    NOx Reduction from the Exhaust Gas of Marine Diesel Engines Using Non-Thermal Plasma

    , M.Sc. Thesis Sharif University of Technology Marizad, Marzieh (Author) ; Borghei, Mehdi (Supervisor) ; Hamzehlouyan, Tayebeh (Supervisor) ; Hajjar, Zeinab (Supervisor) ; Khani, Mohammad Reza (Supervisor)
    Abstract
    Environmental regulations with respect to the marine diesel emissions have become stricter during recent years, thereby imposing traffic limitations on Iranian ships preventing them to enter emission control areas. Nitrogen oxides (NOx), as one of most important air pollutants, have adverse impacts on public health and ecosystem, so as the ships are the primary source of NOx internationally, the after-treatment system finds more urge to be developed. In this study, a NOx reduction system using non-thermal plasma technology is studied in order to determine its application and efficiency for NOx removal from the exhaust gas of Iranian marine diesel engines. Meanwhile, important factors were...