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    Nanosheet arrays of TiO2synthesized by one step conversion of ZnO nanosheets: Boosting of electron transport rate and application in dye solar cells

    , Article RSC Advances ; Vol. 4, issue. 85 , 2014 , pp. 45174-45179 ; ISSN: 20462069 Alimirsalari, S ; Tajabadi, F ; Salehkoutahi, S. M ; Ghahary, R ; Taghavinia, N ; Sharif University of Technology
    Abstract
    A TiO2replica of ZnO nanosheet films is synthesized using a chemical replacement process. ZnO nanosheets are grown by electrodeposition on fluorine doped tin oxide (FTO) films, and a dissolution/deposition process is used to convert the ZnO template into a TiO2replica. Electron microscopy shows the final TiO2structure follows the morphology of the initial ZnO template. X-ray diffraction and energy dispersive spectroscopy verify the total transformation of ZnO to TiO2. The as-synthesized TiO2sheets are amorphous and after annealing turn into the anatase phase. The film of TiO2nanosheets is used as the photoanode of a dye sensitized solar cell. Despite the low roughness factor of 100, a... 

    Nickel-based nanosheets array as a binder free and highly efficient catalyst for electrochemical hydrogen evolution reaction

    , Article International Journal of Hydrogen Energy ; Volume 47, Issue 82 , 2022 , Pages 34887-34897 ; 03603199 (ISSN) Faraji, H ; Hemmati, K ; Mirabbaszadeh, K ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Hydrogen technology through water electrolyzer systems has attracted a great attention to overcome the energy crisis. So, rationally designed non-noble metal based-electrocatalysts with high activity and durability can lead to high performance water electrolyzer systems and high purity hydrogen generation. Herein, a facile two-step method: hydrothermal and electrodeposition, respectively, are developed to decorate highly porous three-dimensional binder-free structure NiFeO/NiO nanosheets array on Ni foam (NiFeO/NiO/NF) with robust adhesion as a high-performance electrode for Hydrogen Evolution Reaction (HER). The electrodeposition process applied after the initial hydrothermal process...