Sharif Digital Repository

The main objective of this project is the deposition of photo-catalysts on cement and concrete blocks with an emphasis on commercialization. We started with an extensive study of common methods introduced in previous literature, and conclude with a number of suggestions for industrialization. First, slurry and sol-gel deposition of the photo-catalysts on blocks of type 2 commercial cement which is one of the most used materials in construction of buildings and waste-water treatment plants has been examined to reach a method of sample formation. Due to the simplicity of common methods and low quality of formed samples (less than 5 percent aging efficiency), the obtained experience was used to... 

Removing pollutants of water and, in general, wastewater treatment is one of the most important issues in the world. In this research, we synthesized a nanophotocatalyst based on znic-iron in the form of a magnetic core-shell Fe3O4@ZIF-8, and used to degrade the malachite green toxic color of wastewater. SEM, XRD and FT-IR analyzes have been taken and analyzed fore all three core, shell and core-shell composite catalysts.Due to the band gap of core-shell nanocomposite and the performance of the malachite green dye, a photocatalytic process under the visible light was obtained, which at an optimum amount of photocatalyst 0.003g, we reach 99.2% dye degradation at the 30ppm concentration. This... 

In recent decades, desulfurization processes have become necessary to reduce environmental pollution due to fuel sulfur emissions. In this research, in order to photocatalytic oxidation desulfurization of liquid fuel, a model fuel (normal octane) under visible light irradiation of 250 W sodium lamp, using H2O2 oxidant and methanol solvent in the presence of BMO/Fe@MIL(x%) composite. BMO and Fe@MIL were investigated. From the tests, X-ray diffraction, scanning and transmission electron microscope imaging, absorption and desorption of nitrogen gas, infrared spectrometer-Fourier transform, visible-ultraviolet reflection spectroscopy, optical radiation spectroscopy and vibration magnetometer in... 

In this thesis, graphene/titanium oxide and graphene/tungsten oxide composites were synthesized using arc discharge in liquid and their photocatalytic behavior was studied. Based on physical principles of the arc discharge in liquid, geometry of point-point was used for metallic Ti and W electrodes. TiO2 and WO3 nanoparticles and their nanocomposites with graphene and graphene oxide (GO) were studies using DLS, UV-vis, PL, ICP, FTIR, XRD, Raman and TEM characterization. The concentration of aqueous solution of Rhodamine B mixed with graphene/WO3 and GO/WO3 composites and WO3 nanoparticles under ultraviolet light was measured versus time and reached to 0.1, 0.6 and 0.6 of the initial value... 

Carbon dioxide photocatalytic reduction is one of the promising methods used to produce a wide range of renewable hydrocarbon fuels using sunlight in the presence of photocatalysts. In this study, a series of Nickel and Bismuth doped titanium dioxide samples were synthesized by Sol-gel method. After performing photocatalytic carbon dioxide recovery experiments and finding the optimum percentage of Nickel and Bismuth doped titanium dioxide,Ni and Bi co-doped TiO2 sample showed the highest photocatalytic activity. Amount of methane production was 21.13 μmol/gcat in the presence of co-doped sample that was about 6.5 times higher than the amount of methane produced in the presence of pure TiO2... 

Photocatalytic degradation is one of the developing modern and effective methods for decontamination of hazardous pollutants of chemical industrial wastewater. This method has several advantages including the possibility of using free and sustainable energy of sun. However, it is still needed to active photocatalysts under solar light and also the enhancement and optimization of operating parameters, and consequently, these topics are selected as goals of the present thesis. Accordingly in this research, first, to obtain a photocatalyst that is highly efficient (especially under visible and solar light), multi-doping and polyethylene glycol (PEG) were used and for the first time,... 

MOFs are new class of materials that are used in different scientific fields because of their hybrid structure. In this project, focused on two specific applications, and aim is synthesis of a nanostructure which has antibacterial and photocatalytic activity. ZIF-8 because of its chemical and physical stability has been studied. For improving antibacterial influence and photocatalytic activity, silver nanoparticles are added to the structure. Magnetic nanoparticles covered by silica were used as core to facilitate separation process, ZIF-8 structure was constructed as shell on SiO2@Fe2O3 nano spheres. Magnetic nanoparticles improving stability of ZIF-8 in aqueous solutions. Synthetic nano... 

due to high mineralization rate of Zinc oxide، chemical and physical stability, non-toxicity and low price as the most promising photocatalysts studied, although its use is not too satisfactory. Because of the wide energy gap(3.2 ev) and for photocatalytic activity needs to UV light Unfortunately, the solar spectrum is made up only 5-7% of UV light, while 46-47% is the spectrum of visible light and infrared. Doped zinc oxide nanoparticles with metal and non-metallic atoms could increase the photocatalytic properties under visible light irradiation. In this research, nanoparticles of zinc oxide was doped by fluorine as Dopant. The results showed that photocatalytic activity of the modified... 

Nowadays with the extension of industry and factories as well as different kinds of plants, a wide range of pollution and circumference hazardous has been entered to the people`s life. Industrial wastewater has been always a threat for health of our environment and efforts for reducing its dangerous effects are still under studies. Dairy wastewater is one of the main branches of food industrial pollutions and it has been studied in this specific project. The goal was to reduce the Chemical Oxygen Demands (COD) of dairy wastewater with oxidation of Titanium Dioxide Nanophotocatalyst oxidation under UV irradiation. Among the various methods for synthesizing of this Nanophotocatalyst, the... 

One of the Advanced Oxidation Process (AOP) is Photocatalyst method. Structure of this method is according to three foundation: 1. Catalyst, 2. Source of energy, 3. Wastewater. Progress of human activity around variety of fields such as pharmaceutical, plastic industry, and medical science has produced some micro pollutants such as Bisphenol A (BPA) that has aroused the public concerns in recent years. The half-life of this components in water, air and soil is too long, so typical methods such as biological method, activated sludge and carbon adsorption are inefficient in removing BPA. This work describes a visible light responsive Carbon Quantum Dots(CQDs) embedded on TiO_2 nanoparticles... 

In this thesis, photocatalytic oxidation as a potential method for the treatment of organic environmental contaminants is deeply investigated. While the photocatalytic degradation of various organic compounds under UV light irradiation has been widely investigated, visible-light-induced photocatalytic degradation of low-levels of the pollutants such as Dibenzothiophene (DBT) and 2-Nitrophenol (2-NP) are occasionally reported. In the present work, Lanthanide / Polyethylene glycol -modified TiO2 (La/PEG/TiO2) and Fe,Cu,S/TiO2 have been successfully synthesized by a sol–gel method. The photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission... 

In this advanced research, titanium dioxide nanotubes were initially synthesized using the hydrothermal method. Subsequently, they were coated with polyaniline, polyindole, or a combination of both polymers using oxidative polymerization. The application of these composites for the removal of the organic pollutant 4-nitrophenol in wastewater was investigated under visible light irradiation from a 250-watt sodium lamp and in the presence of hydrogen peroxide as an oxidizing agent. To characterize the synthesized photocatalysts, various tests were conducted, including X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS),...