Sharif Digital Repository

This research aims to introduce a nanocatalyst based on open-cell nickel foam (NiFm) with 40 pore per inch(ppi) to save energy during methane steam reforming (MSR), an endothermic reaction, by increasing catalyst thermal properties with improved progressive compression strength. The nanocatalyst is synthesized with a chemical stepwise synthesis approach, thermal-chemical pretreatment, pulsed electrocodeposition of Ni-Al2O3 (γ) nanoparticles, and calcination. Herein, a polyurethane (PU) nonconductive substrate is transformed to nickel foam by using replication sponge method. The purchased PU became conductive by nickel electroless bath using sodium hypophosphite with 5-15 (µm) thickness... 

Methane steam reforming (MSR) is an assuring reaction using steam to produce H2 as clean energy over a nickel-based catalyst. We synthesized monometallic NiMgAl2O4 and bimetallic NiCoMgAl2O4 catalysts in a two-step combustion method using urea, glycine, and sucrose, as fuel. BET-BJH, XRD, TGA, TPR, FESEM, and EDX-mapping characterized surface area, porosity, morphology, crystalline structure, and metal-support interaction behavior. The products exhibited well-structured, simple MgAl2O4 spinel and NiO without NiAl2O4, in both specimens. The MSR evaluation tests at 750℃ under atmospheric pressure, CH4: H2O feed ratio of 1:1.6 showed the bimetallic catalyst has the highest conversion (99.30%)...