Sharif Digital Repository

In this research, data on liquid-liquid extraction of platinum from commercial spent catalysts by trioctylphosphine oxide (TOPO) in toluene were experimentally obtained. Alkaline metal salts were used to optimize the separation process. Best Salting-out effect was obtained by KCl which extracted up to 90% of platinum utilizing TOPO. Furthermore, extraction percentages of Pt and Al depending upon different factors were investigated. It was observed that the extraction process was kinetically fast and achieving the equilibrium time took less than 30 seconds. Optimized points obtained utilizing response surface methodology (RSM) by the "Design Expert" software in order to minimize the... 

Effects of cooling slope angle and the temperature of molten metal on the globular structure of M2 high speed steel after holding at the semisolid state have been investigated. The globular structure was achieved by pouring the molten metal at 1595 °C on the ceramic cooling slope with the length of 200 mm and the angle of 25°. The globular structure of M2 high speed steel in the form of rolled-annealed and as cast condition after holding at semisolid state has been achieved. The size of globular grains of cooling slope sample was smaller than that of the rolled-annealed and as cast samples. Solid particles of rolled-annealed sample after holding at semisolid state had better roundness... 

The objective of this study was to investigate the synergistic effect of TBP on the system D2EHPA/kerosense/M2+ with respect to the extraction of some transitional metals. Although the presence of M2EHPA as an impurity in D2EHPA shifts the extraction curves to lower pH, empirical results show that the extraction curves shift to the right due to the addition of TBP and the counterbalance effect of M2EHPA. The results indicate that the equivalent concentration of D2EHPA decreases as a function of concentration of TBP because of the formation of hydrogen bonds between TBP and D2EHPA. Based on this finding, the D2EHPA equivalent concentration was determined by using a modifying factor for TBP... 

Results of recent studies on the effect of heat treatment after cold rolling on mechanical properties and transformation temperatures of the cast 52Ni48Ti alloys are described. It is seen that stress-induced martensite is formed when both the as-rolled and the low-temperature (≤400 °C) heat-treated samples are strained. Martensite reorientation due to the stress action occurs in samples heat treated at 500 °C and higher. Optimum recovery occurs below 600 °C resulting in hardness reduction. Recrystallization starts at 600 °C resulting in parent phase yield stress enhancement. Yield stress starts to decrease when grain growth and order-disorder transformation both occur above 700 °C. © 2006... 

In this report, the efficacy of different factors such as temperature of reaction, time of reaction and depth of bed are investigated in a process of recovery of zinc oxide from zinc ore concentration residues in a fluidized bed furnace. Under optimum conditions, there was more than 93.5% zinc oxide in products  

This paper models the kinetics of dynamic recovery and recrystallization under hot working conditions. For doing so, the first-order kinetics equation is coupled with a thermo-viscoplastic finite element analysis to determine the kinetics of dynamic softening processes at different points of deforming metal. The proposed model can consider the effects of macro parameters, such as temperature and strain rate variations as well as the influences of microparameters as initial grain size on the rate of dynamic softening processes. © 2005 Elsevier B.V. All rights reserved  

The high amount of base metals poses an important challenge in gold bioleaching from spent printed circuit boards (PCBs). This study aims to investigate the bioleaching of important base metals (Cu, Ni, and Fe) from a mixture of spent PCBs (E-waste) using adapted Acidithiobacillus ferrooxidans in the bubble column bioreactors. Firstly, the adaptation process is done from 1 to 15 g/L in Erlenmeyer flasks in 187 days, then the concentration of E-waste increased to 40 g/L in bubble column bioreactors in 44 days. The concurrent recovery of copper, nickel, and iron using adapted bacterium in a bioreactor was optimized by central composite design. Various effective parameters such as aeration... 

This research aimed at finding the factors with more impact on the bioleaching of a spent hydrocracking catalyst by thermophilic acidophilic archaea called Acidianus brierleyi and determining the optimal condition in order to reach the maximum metals recovery. Initially, four more significant factors affecting the bioleaching efficiency including pH, pulp density, inoculation and elemental sulfur concentration, were screened and identified among ten key factors using Plackett-Burman factorial design. Next, a central composite design was applied to obtain the optimum conditions for achieving the maximum efficiency of the bioleaching process. pH 1.6, pulp density 0.6% (w/v), inoculation 4%... 

This study was designed to compare one-step, two-step and spent medium bioleaching of spent catalyst by adapted Aspergillus niger in batch cultures. Aspergillus niger, which was adapted to heavy metal ions, Ni, Mo, Fe, and W, was grown in medium containing up to 5% (w/v) of spent catalyst. The main lixiviant in bioleaching was gluconic acid, which was produced at all pulp densities in the one-step bioleaching process. Gluconic acid was also produced in the two-step bioleaching process when the spent catalyst was present at pulp densities greater than 1% (w/v). In the spent medium leaching, however, the primary agent was citric acid. The pulp density of the spent catalyst was varied, and this... 

Development of a model for optimal power generation from the thermal oxidation of a low concentration coal bed mine has been considered as the main objective of this investigation. The model has been applied to identify the optimal thermodynamic characteristics of the power generation system through using a mixture with 1.6% methane concentration in a recuperative lean-burn gas turbine and coupling a gas engine to the system for more power generation from the remaining coal bed methane. The implementation of the model based on the real site condition would lead to the generation of 6.97 MW electricity in Tabas coal mine of Iran. © 2016 Taylor & Francis  

The texture development during friction stir processing (FSP) of 1050 aluminum severely deformed at the strain magnitude of 2.32 was comprehensively discussed. It was observed that the component B¯ of the ideal shear texture along with the cube texture was developed in the severely deformed base metal. The effects of base metal texture on the texture development of stir zone, thermo-mechanically affected zone, and heat-affected zone during FSP were examined. Also, the developed texture components in the vicinity of the FSP tool and the stir zone were correlated to the deformation induced by the rotating tool which consisted of pin and shoulder. The observed texture components in the... 

A hybrid model based on the flow function and dislocation cell structure model by considering the Taylor assumption is utilized to model the dislocation structure evolution, cell size and mechanical properties of OFHC in severe plastic deformation. Here, the ECAP is chosen as a process of severe plastic deformation. In this study, the model is modified by taking the value of cell size coefficient as a function of strain and considering two different values of dynamic recovery coefficients of cell walls and cell interiors. These modifications lead to achieve the more accurate modeling results. From the flow function the strain rate distribution are achieved and then using the model the... 

An attempt was made to produce an iron bearing and a titanium bearing product, using solid state reduction of Fanouj mine titanomagnetite concentrate. For this purpose, the concentrate was mixed with pulverised coal and sodium carbonate and was reduced in a muffle furnace. The product was then subjected to magnetic separation. In this work, the effect of temperature, time, added coal and additive amount on reduction was studied. The Separation Efficiency (SE) index was used for optimisation of the process. Using SE is more appropriate than degree of metallization, which is usually used, for optimising reduction processes. The results show that the optimal conditions are 1325°C, 2.5 h, 25... 

Kinetics of dissolution of silver present in precious metal scraps in HNO3 was studied in temperature range of 26-85°C. Dissolution rate of silver was much faster than that of copper at all temperatures. Effects of particle size, stirring speed, acid concentration and temperature on the rate of dissolving of silver were evaluated. Dissolution rate decreases with particle size and increases with temperature. Dissolving was accelerated with acid concentrations less than 10 mol/L, Concentrations greater than 10 mol/L resulted in slowing down of the dissolution rate. Shrinking core model with internal diffusion equation t/τ = 1 - 3 (1-x)2/3 + 2 (1-x) could be used to explain the mechanism of the... 

A two-dimensional finite element analysis is coupled with dynamic recovery and dynamic strain aging models to achieve metal flow during warm deformation of a low carbon steel. In order to assess metal behavior, compression experiments are utilized under warm deformation conditions and the results are used in the model and temperature and velocity fields are predicted with regard to the effects of dynamic recovery and dynamic strain aging. In addition, warm rolling tests are performed to verify the modelling results. Comparison between the predicted and measured roll forces shows reliability of the employed model. © 2005 Elsevier Ltd. All rights reserved  

An attempt was made to produce an iron bearing and a titanium bearing product, using solid state reduction of Fanouj mine titanomagnetite concentrate. For this purpose, the concentrate was mixed with pulverised coal and sodium carbonate and was reduced in a muffle furnace. The product was then subjected to magnetic separation. In this work, the effect of temperature, time, added coal and additive amount on reduction was studied. The Separation Efficiency (SE) index was used for optimisation of the process. Using SE is more appropriate than degree of metallization, which is usually used, for optimising reduction processes. The results show that the optimal conditions are 1325°C, 2.5 h, 25... 

The present study examines the biorecovery of heavy metals from a spent refinery catalyst obtained from one of the oil refineries in Iran using Aspergillus niger. Bioleaching experiments were carried out in batch cultures using A. niger in the one-step process to mobilize Co, Mo and Ni from hazardous spent catalysts. Response surface methodology (RSM) was applied for the design and analysis of experiments with the optimization of pH, temperature, inoculum percentage, pulp density and rotation speed during the bioleaching of the metals. Experiments were designed as per the central composite design (CCD) technique. Three cubic mathematical models were derived for prediction of the responses.... 

A spent processing catalyst from an Iranian oil refinery was initially characterized physically and chemically. Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans were used to mobilize Al, Co, Mo and Ni from the spent catalysts under optimized conditions in batch cultures. The characteristics of the bioleach solution (pH, Eh, cell concentration and Fe(II)/Fe(III) concentration) were determined along with the concentration of metal values extracted from the catalyst. The results showed that after bioleaching using A. ferrooxidans in the presence of ferrous sulfate, maximum extractions of 63% Al, 96% Co, 84% Mo and 99% Ni were achieved after 30 days at pH 1.8-2.0. However, the... 

In this investigation, a spent processing catalyst from one of the oil refineries in Iran was initially characterized physically and chemically. Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans were used to mobilize aluminum, cobalt, molybdenum and nickel from hazardous spent catalysts. Bioleaching experiments were performed in batch cultures. The growth characteristics of the bacteria (pH, Eh, cell concentration and ferrous and ferric iron concentration) were determined during bioleaching along with the concentration of metal values extracted from the catalyst. The results obtained from Inductive coupled plasma-optical emission spectrometry (ICP-OES) showed that after the... 

In the present research work the 2024 aluminum alloy was reinforced with SiC particles via powder metallurgy method. The effect of heat treatment conditions on artificial aging kinetics was investigated. The solution treatment of the composite sample and the unreinforced alloy was carried out at 495 °C for 1, 2 and 3 h followed by aging at 191 °C for various aging times between 1 and 10 h. The existence of SiC particles led to increasing the peak hardness of the alloy. The peak hardness of the composite sample took place at shorter times than that of the unreinforced alloy for the samples solution treated for 2 and 3 h, but took place at longer times for the samples solution treated for 1 h....