Sharif Digital Repository

Exhaust gases from poultry rendering facilities contain volatile organic compounds (VOCs) that are a nuisance, odorous, and smog and particulate matter precursors. Other available treatment options, such as thermal and catalytic incineration require temperature intensive inputs and form additional greenhouse gases. Hence, an inexpensive alternative technology is needed to eliminate these air pollutants. This research investigated the catalytic oxidation of toluene vapors using novel dispersed nano catalysts derived from new preparation method. The combined impregnation (IMP) and deposition-precipitation (DP) was used to prepare supported transition metal oxide catalyst over commercial and... 

Ruthenium based-oxide coatings on Titanium anodes are widely used as DSA (Dimensionally Stable Anode) for chlorine and chlorate production. Coatings consisting of composition of highly conductive oxide of noble metals (Ru, Ir and Pt) make them as long lasting anodes in chlor-alkali technology.In this work, a newly anode by a ternary coating of IrO2, RuO2, and TiO2 on the Pt-coated Ti was developed through thermal decomposition of iridium and titanium and ruthenium inorganic salts dissolved in n-pentane. The effect of deposition parameters such as current density, time, different condition of baking, heating, mole ratio and pulling up the samples was investigated to find out reasonable... 

Different nanocomposites were prepared based on the carbon nitride, structures and metal organic framework. The photocatalytic activities of a group of metal-organic metal frameworks were evaluted. Next step, the combination of binary and ternary composites based on carbon nitride/metal-organic frameworks structures with other semiconductors such as oxyacid, bismuth oxy halide and ferrite spinel was used. In addition, synthesis of varius type of metal oxides structures with metal organic framework precursors has also been another perpuse of this thesis.The catalytic and photocatalytic activities of designed nanocomposites were performed for a redox process (4-nitrophenol (4-Nip) to... 

In this study, ternary metal oxide coating consisting of Ti, Ru, Ir were prepared by sol-gel method. In order to achieve optimal conditions, the effect of number of layers, temperature and velocity of the heat treatment, the amount of ruthenium and iridium, polymeric additive on the coating and also, comparisons of binary and ternary oxide coatings were studied. The corrosion behavior was examined by anodic polarization and cyclic voltammetry tests and accelerated stability test (AST), the morphology of coatings was studied by field emission scanning electron microscopy (FESEM), phase and elemental analysis was performed using X-ray diffraction (XRD) and energy dispersive spectroscopy... 

Volatile Organic Compounds (VOCs) have become an important source of air pollution due to their extended use as solvents in many industrial processes. Aliphatic and aromatic VOC removal from contaminated air can be achieved by a variety of methods including catalytic oxidation, adsorption, and biological treatment. Catalytic oxidation is often the preferred process due to its low cost and high efficiency. Supported transition metal catalysts are effective and inexpensive catalysts for VOC removal from contaminated air. The objective of this project was to prepare low cost transition metal catalysts (Fe, Ni, Co, and Cu) supported on alumina for catalytic oxidation of cyclohexane (as a... 

In this research,Graphene Oxide nanoplatelets (GO) were synthesized by chemically modified Hummer's method.After the GO nanosheets electrochemically reduced to graphene, nanoparticles imposed to this thin film.This optimized nanostructure coating was utilized for investigating the Hydrogen Evolution Reaction (HER) over the copper substrate. In order to optimize the kinetic of electrodeposition and reduction, diverse electrochemical approaches such as cyclic voltammetry, chronoamperometic and potentiometric as well as pulse electrodeposition methods were employed. Electrochemical procedures were aligned by Design of Experiment (DOE) ... 

This research examines the issues of design and fabrication of Phase Shifter circuits on Silicon substrates. The Phase Shifter circuits are designed to have wide operation band width. They also should have very low sensitivity to process and temperature variation. A six bit phase shifter is designed at this research. We use a new topology for implementing the small phase shift steps and some circuits have been designed which their phase shifts can be adjusted after fabrication. All circuits are implemented with the 0.18µm CMOS technology. The research also explains all the necessary steps for measurement of fabricated circuits. The result of measurements shows good agreement with the... 

Diabetes is one of the most catastrophic diseases in the world. There will be an end to patients’ problems if scientists can invent the artificial pancreas, but there is no implantable sensing core available. All of the sensors used for measuring blood glucose level were based on an electrochemical sensor which will generate a glucose level dependent electric current. The chemical structure of that sensor will deny its usability for in vivo applications. By exploring several biological and electrical literatures we introduced a fully electrical method for sensing the blood glucose level by impedance measurement. In this thesis we introduced a new method for sensing the blood glucose... 

Impedance spectroscopy is known as one of the important integrated sensing methods in micro scale Biosensors and electrochemical sensors. Recently, Impedance spectroscopy has been noticed in many micro scale applications. These micro scale applications is being developed specially in bioelectronics and biomedical. The goal of this thesis is designing an on-chip impedance spectroscope system for high frequency with 10 bits resolution via fully electrical blood glucose concentration measurement. This system extracts the blood glucose concentration data through measuring the permittivity coefficient of blood at 1 GHz frequency. In this thesis, new method for high frequency high resolution... 

In line with developments in the technology of integrated circuits, transistors are implemented in silicon. Although the price is reduced; design is more complicated, which causes the efficiency and power consumption to face some difficulties in such design. The reason why modern GDI-based circuit is the focus of attention is that in designing a digital circuit, less power is required while more efficiency is obtained. Lowering the complexity of the logic circuit can bring about reduction of power consumption and propagation delay and decrease the circuit space. GDI-based integrated circuits resemble MOSFET transistors but have fewer transistors and higher performance capability. This study... 

In this thesis, a Ku-band (16.3-17.3) Variable Gain Amplifier (VGA) for realizing a phase array T/R module is designed, implemented and measured in CMOS 0.18μm technology. In order to achieve a maximum gain of 15dB and NF of 4.3dB and with the idea of improving the 1-dB compression point, two gain-stages and a novel inter-stage is proposed according to pre-distortion method. Applying this linearizing technique, makes it possible to get output P-1dB higher than 18dBm. Current steering technique is used for gain control mechanism. Gain tunabality range of 31.5dB is needed and this forces 6-bit operation with 0.5dB gain-step for the VGA. Because of loading effect of higher bits on the lower... 

In this thesis, an X band vector modulator chip in CMOS .18 um technology is designed, implemented and measured. The receiver with two RF signal path includes differential amplifier, hybrid, attenuaters, variable gain amplifiers (VGA) and power combiner blocks respectively. Capability of gain and phase control is provided by 14 digital bit. 6 bits are used to control gain of each RF path, so that changing the phase and gain of the output signal in a trigonometric quarter shall be possible. The trigonometric quarter is selected by two single pole double throw switch. Cascode structure is utilized in amplifiers stages for its stability and isolation feature. Furthermore, in order to to enhance... 

In this thesis, a new wide band variable gain distributed amplifier (VGDA) is presented. A novel approach to implement uniform gain control in the wide band frequency range of 8 – 18 GHz is demonstrated. A different technique has been employed to provide necessary DC bias current, avoiding large DC-Feed inductors. A five-section wideband VGDA has been designed and fabricated in 0.18 μm CMOS technology. The VGDA have a flat gain of 11 dB, noise figure better than 5 dB, P1dB of 14 dBm at the output, input and output matching better than -12 dB and -14 dB, respectively, for maximum gain state over the 10 GHz UWB band. The gain control range is between 3 – 11 dB with gain steps of 0.5 dB and rms... 

In this thesis, we have studied systems called Ruthenates, which are common in possessing Ru element in their chemical compounds. Ruthenates are a group of transition metal oxides which have attracted so attention, especially in last years duo to their rich phase diagram which shows different orbital, charge and spin orderings.They cover a vast range of materials properties, from a Superconductor to Mott Hubbard insulator, from a paramagnetic metal to an antiferromanetic insulator. In these systems, substituting a covalent atom with structure base, leads to a vast variety changing, not only in electronic properties but also in magnetic and structural ones: Although Sr"RuO£ is a... 

Fully integrated frequency synthesizer is one of the important system-on-chips building blocks. Among this circuit’s remarkable applications, Bioelectronics field is very common. In these applications, advanced microelectronic circuits are used in order to diagnosis and treatment of diseases. The aim of this thesis is design and implementation a wideband frequency synthesizer in a 0.18um CMOS technology. The main usage of this circuit is in a fully integrated implantable biomedical sensory chip. This circuit generates two necessary local signals in sensory chip to stimulus cells and process the information.
Frequency synthesizer is based on phased locked loop (PLL) circuit and produce...