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    Electrospun titania sol-gel-based ceramic composite nanofibers for online micro- solid-phase extraction with high-performance liquid chromatography

    , Article Journal of Separation Science ; Vol. 37, issue. 15 , August , 2014 , pp. 1982-1988 ; ISSN: 16159306 Bagher, H ; Piri-Moghadam, H ; Rastegar, S ; Taheri, N ; Sharif University of Technology
    Abstract
    Titanium(IV) tetraisopropoxide was employed as a metal oxide sol-gel precursor to prepare ceramic composite nanofibers by the electrospinning system. To facilitate this process and obtain the desired nanofibers with higher aspect ratios and surface area, poly(vinylpyrrolidone) was added to the sol of titania. Four ceramic nanofibers sheets based on titania were prepared while each sheet contained different transition metals such as Fe-Mn, Fe-Ni, Fe-Co, and Fe-Mn-Co-Ni. The scanning electron microscope images showed good homogeneity for all the prepared ceramic composites with a diameter range of 100-250 nm. The sorption efficiency was investigated by a micro-solid-phase extraction setup in...