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    The effect of HRT and carriers on the sludge specifications in MBR to remove VOCs from petrochemical wastewater

    , Article Desalination and Water Treatment ; Dec , 2015 , Pages 1-13 ; 19443994 (ISSN) Hazrati, H ; Shayegan, J ; Mojtaba Seyedi, S ; Sharif University of Technology
    Taylor and Francis Inc  2015
    Abstract
    This work employs two membrane bioreactors (with and without carrier) to evaluate the influence of carrier and hydraulic retention time (HRT) on the sludge specifications when removing organic volatile compounds (e.g. styrene and ethylbenzene) from petrochemical wastewater. This study is conducted during three various HRTs. The results indicate that the optimum HRT (e.g. 15 h.) was achieved in the reactor with carrier during biological removal and membrane fouling minimization. During the optimum HRT, the biological removal efficiency for styrene, ethylbenzene, and COD is 99.8 ± 0.1%, 99.8 ± 0.1%, and 99 ± 0.8%, respectively, and the concentration of styrene and ethylbenzene in the exit air... 

    The effect of HRT and carriers on the sludge specifications in MBR to remove VOCs from petrochemical wastewater

    , Article Desalination and Water Treatment ; Volume 57, Issue 46 , 2016 , Pages 21730-21742 ; 19443994 (ISSN) Hazrati, H ; Shayegan, J ; Mojtaba Seyedi, S ; Sharif University of Technology
    Taylor and Francis Inc  2016
    Abstract
    This work employs two membrane bioreactors (with and without carrier) to evaluate the influence of carrier and hydraulic retention time (HRT) on the sludge specifications when removing organic volatile compounds (e.g. styrene and ethylbenzene) from petrochemical wastewater. This study is conducted during three various HRTs. The results indicate that the optimum HRT (e.g. 15 h.) was achieved in the reactor with carrier during biological removal and membrane fouling minimization. During the optimum HRT, the biological removal efficiency for styrene, ethylbenzene, and COD is 99.8 ± 0.1%, 99.8 ± 0.1%, and 99 ± 0.8%, respectively, and the concentration of styrene and ethylbenzene in the exit air... 

    Preparation and characterization of polycarbonate/thermoplastic polyurethane blend membranes for wastewater filtration

    , Article Journal of Water Process Engineering ; Volume 16 , 2017 , Pages 170-182 ; 22147144 (ISSN) Nazemidashtarjandi, S ; Mousavi, S. A ; Bastani, D ; Sharif University of Technology
    Elsevier Ltd  2017
    Abstract
    The polycarbonate (PC)/thermoplastic polyurethane (TPU) blend membranes were prepared by phase inversion process applied to membrane bioreactor (MBR) to investigate the fouling characteristics. The impact of TPU and poly (vinylpyrrolidone) PVP concentration in polymer dopes on membrane structure, morphology, and performance were studied. The flat sheet fabricated membranes were characterized by scanning electron microscope (SEM), water contact angle (WCA), membrane surface roughness measurements and mechanical strength. The membrane performance was investigated at subcritical operating conditions. Pure water and critical flux through the fabricated membranes were measured for better... 

    Municipal wastewater treatment by semi-continuous and membrane algal-bacterial photo-bioreactors

    , Article Journal of Water Process Engineering ; Volume 36 , 2020 Amini, E ; Babaei, A ; Mehrnia, M. R ; Shayegan, J ; Safdari, M. S ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    Conventional wastewater treatment systems demand a high cost mechanical aeration. Using algal-bacterial systems helps to reach a cost-efficient treatment method by eliminating mechanical aeration, since algae produce the oxygen needed for treatment process. In this study, two groups of experiments were performed for domestic wastewater treatment processes. For the first group, semi-continuous microalgae-bacterial photo-bioreactors were cultivated. Chlorella Vulgaris and activated sludge (AS) were used as microalgae and bacterial inoculums, respectively. The effect of different algae and AS ratios on the chemical oxygen demand (COD), N-NH4 + and P-PO4 3− removal was studied. The removal... 

    Municipal wastewater treatment and fouling in microalgal-activated sludge membrane bioreactor: Cultivation in raw and treated wastewater

    , Article Journal of Water Process Engineering ; Volume 49 , 2022 ; 22147144 (ISSN) Najafi Chaleshtori, S ; Shamskilani, M ; Babaei, A ; Behrang, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Since the advent of conventional activated sludge biological treatment plants, their low efficiency in nitrogen and phosphorus removal has become a significant concern. Therefore, in this study, the performance of microalgal-activated sludge membrane bioreactor (MAS-MBR) as a self-biological treatment or as a post-treatment for conventional biological treatments was investigated. A continuous MAS-MBR with two ratios of algae/sludge (only microalgae and 5:1) was used to treat raw and treated wastewater. The optimum case was achieved with the cultivation of mixed algae/sludge in raw wastewater (R2 case). In this case, the ammonium and phosphorus removal efficiencies were 94.36 ± 3.5 and 88.37... 

    Comparison of different trophic cultivations in microalgal membrane bioreactor containing N-riched wastewater for simultaneous nutrient removal and biomass production

    , Article Process Biochemistry ; Volume 51, Issue 10 , 2016 , Pages 1568-1575 ; 13595113 (ISSN) Babaei, A ; Mehrnia, M. R ; Shayegan, J ; Sarrafzadeh, M. H ; Sharif University of Technology
    Elsevier Ltd  2016
    Abstract
    In this study, a submerged membrane was installed in a bioreactor to treat N-riched wastewater and obtain high biomass productivity. Chlorella vulgaris was cultivated under mixotrophic, heterotrophic, and photoautotrophic conditions in different kinds of nitrogen sources (nitrate and ammonium) to compare the microalgae growth and nutrient removal in a membrane bioreactor. Further, the respirometric and photosynthetic activities of microalgae were investigated to evaluate the viability of microalgae in different conditions. The highest biomass productivity was obtained under mixotrophic cultivation in ammonium source (0.230 ± 0.009 gr/L d). Moreover, with this type of cultivation and nitrogen... 

    Membrane Bioreactor for the Treatment of Dairy Industry Wastewater

    , M.Sc. Thesis Sharif University of Technology Zarinnal, Mahla (Author) ; Alemzadeh, Iran (Supervisor) ; Vossoughi, Manoochehr (Supervisor)
    Abstract
    The dairy industry wastewater has high biological oxygen demand(BOD) and high chemical oxygen demand(COD). In this study, membrane bioreactor(MBR) was used for the treatment dairy industry wastewater. Since two diffuser,submerged membrane modul and intermittent suction method were adpted to system. In this study, the response surface method and experimental design were applied as an alternative to conventional methods for the optimization of the treatment. A central composite design, with 5 replicates at the center point were used to build a model for predicting and optimizing the treatment. Mathematical model equations were derived by computer simulation programming with Design Expert... 

    Experimental Study on the Efficiency of Memberane Bioreactor (MBR) in Removal of Trace Persistent Pollutants

    , M.Sc. Thesis Sharif University of Technology Fouladi Ghale, Hosnie (Author) ; Borghei, Mahdi (Supervisor) ; Vosoughi, Manuchehr (Supervisor) ; Hesampour, Mehrdad (Supervisor)
    Abstract
    The removal of glyphosate, one of the most widely used herbicide, with membrane bioreactor (MBR) was studied. Beside of glyphosate, the synthetic wastewater contained molasses and other salts as nutrient source. The membrane was made from polypropylene and was immersed in the bioreactor. The COD of the feed was adjusted by varying the ratio of glyphosate to molasses. The total COD was 500, 750 and 1000 mg/L. The resulted showed that when the bioreactor coupled with membrane the removal efficiency increased. The increase was attributed to higher concentration of biomass or MLSS in the MBR. The average of MLSS in the MBR was 8500 mg/L while in bioreactor without cell recycling and in batch... 

    Effect of the Chemical Coagulant and Oxidizer on the Membrane Fouling During the Treatment of Wastewater Using a Membrane Bioreactor

    , M.Sc. Thesis Sharif University of Technology Zarei Baygi, Ali (Author) ; Moslemi, Mohammad Reza (Supervisor)
    Abstract
    Membrane bioreactor (MBR) is a combination of conventional activated sludge (CAS) and membrane filtration which owing to its advantages such as high quality effluent and low excess sludge production, has gained increasing application in wastewater treatment. The major drawback of a MBR is the membrane fouling that reduces the permeate flux, which in turn increases the overall operational costs due to high energy requirements. In existing study, the combination of sludge oxidation and coagulation/flocculation addition was investigated for mitigation of membrane fouling in a membrane bioreactor. Oxidation can facilitate sludge flocculation and hence improve the properties of mixed liquor. The... 

    Fabrication of Polymer Nano-composite Membrane to Increase its Hydrophilicity for using in MBR Process

    , M.Sc. Thesis Sharif University of Technology Ghazanfari, Davoud (Author) ; Bastani, Daruoosh (Supervisor) ; Musavi, Abbas (Supervisor)
    Abstract
    composite membranes with PVC as the matrix, Alumina nanoparticles as filler and PVP as additives, were optimized and built. First, the interaction of PVC, PVP and alumina particles on the membrane structure and its performance was investigated by using Design expert software. The membranes which the software proposed were prepared and pure water permeability and flux decline tests were done according to evaluate the membranes performance in membrane bioreactor (MBR). And the results were imported in software and material effects on the performance of each membrane were analyzed. In order to better assess the efficiency and effectiveness of alumina nanoparticles on membrane, different values... 

    Optimization and Offering a kinetic Model for Enzymatic Hydrolysis of Cellulosic Materials in a Membrane Bio-reactor

    , M.Sc. Thesis Sharif University of Technology Kashefi, Saeed (Author) ; Soltanieh, Mohammad (Supervisor) ; Shaygan Salek, Jalaloddin (Co-Advisor)
    Abstract
    Regarding decreasing resources of fossil fuels and their increasing costs in addition to their environmental pollutions, today, producing bio fuels from wastes such as lignocellulosic materials is of great interest. A fundamental stage in conversion of lignocellulosic materials into bio fuels, such as bio ethanol, is the enzymatic hydrolysis of these materials to produce reducing sugars. Researches have shown high costs of this stage. Optimization of enzymatic hydrolysisconditions is a major step in economization of this process.In this work corn hull is used to produce glucose. Corn hull is a kind of lignocellulosic material that due to high carbohydrate content is used as substrate. Our... 

    Construction of a New Membrane Bioreactor for Industrial Wastewater Treatment

    , M.Sc. Thesis Sharif University of Technology Anvari, Arezoo (Author) ; Seifkordi, Ali Akbar (Supervisor) ; Hemati, Mohmoud (Co-Advisor) ; Rekabdar, Fatemeh (Co-Advisor)
    Abstract
    In recent years membrane bioreactors (MBR) were widely used as an advanced process for industrial wastewater treatment. But fouling issue causes some restrictions in these systems. So for fouling reduction many researches were done.In this study for fouling improvement, blending of hydrophilic polymer (PAN) with main polymer PVDF was used. Blending membrane in phase inversion process with DMAC as solvent and water as non-solvent was made. For pore-forming in membranes, PVP as hydrophilic additive with three different composition was added and then for more enhancement of antifouling property of membrane, TiO2 nanoparticles with four different composition were added to polymeric... 

    Optimization of Membrane Structure in Membrane Bio-Reactor Application

    , M.Sc. Thesis Sharif University of Technology Khosravizade, Rouhollah (Author) ; Mousavi, Abbas (Supervisor) ; Bastani, Daruosh (Co-Advisor)
    Abstract
    Reusing valuable materials such as water is one of the ways to achieve sustainable development. Membrane bioreactor technology (MBR) is one of the ways to reuse water and this is an alternative to another way to upgrade existing refinery.Structure and porosity of the membranes used in MBR Systems, porosity distribution, Hydrophilic or hydrophobicity of the membrane and surface roughness are very important Parameters that impact the ultimate performance of membrane bioreactor. Hence, this project focuses on optimization membrane structure to purification a specific type of wastewater. So amount of polymer and nanoparticle membrane for MBR systems should determined by experiment design.In this... 

    Preparation of Polycarbonate Membrane for Industrial Wastewater Treatment in Membrane Bioreator

    , M.Sc. Thesis Sharif University of Technology Nazemi Dashtarjandi, Saeed (Author) ; Mousavi, Abbas (Supervisor) ; Bastani, Dariush (Supervisor)
    Abstract
    Today, membrane bioreactors (MBRs) process is one of the most important options in industrial and municipal wastewater treatment. In MBRs, membrane has an essential influence on their performance. In this study, polycarbonate was exploited as membrane to evaluate its performance in MBR since it has excellent mechanical properties. However, polycarbonate is brittle and breaks at low elongation at room temperature. Solution blending was utilized to improve polycarbonate’s properties. Blending membrane was characterized and assessed by scanning electron microscopy (SEM) and tensile strength. Polycarbonate solution blending with polyurehatne which has excellent toughness and flexibility enhance... 

    Study of the Effect of Ozonation in Reducing Mambrane Fouling

    , M.Sc. Thesis Sharif University of Technology Mashayekhi, Fatemeh (Author) ; Shaygan, Jallaledin (Supervisor) ; Hazrati, Hossein (Co-Advisor)
    Abstract
    Membrane bioreactors (MBRs) are a combination of activated sludg and mebrane technology. MBRs have been widely used as an advanced process for urban and industrial wastewater-treatment in recent years. Membrane fouling is the main issue that limits their performance and therefor, many studies have concentrated on testing different ways to mitigate the fouling. Ozonation process, that has been proved to reduce the MBR fouling, is studied in this project. Ozonation can provide the conditions for flocculation and therefor improves mixed-liqure properties. Ozon at two concentrations, 0.2 and 0.9 mg/lit was tested. Although results show little change in COD (chemical oxygen demand), but membrane... 

    Chemical Adjustment of Membrane Surface to Reduce Fouling in Membrane Bioreactors

    , M.Sc. Thesis Sharif University of Technology Vaghar-Mousavi, Danial (Author) ; Bastani, Dariush (Supervisor) ; Mousavi, Abbas (Supervisor)
    Abstract
    In this study, modification of Polyvinylidene fluoride membrane in order to reduce membrane fouling in membrane bioreactors is investiged. To achieve this goal, chemical modification and grafting methods were used. Initially, by chemical modification, the reaction was made to make hydroxyl groups on the membrane surface. The hydroxyl functional groups were used as a site for connecting of subsequent monomers. Finally, the lysozyme enzyme was used as the main modifier to improve the hydrophilicity and antibacterial properties of the membrane surface. To evaluate the performance of the modified membrane in comparison with the pristine membrane, different tests, such as water contact angle... 

    Influence of an Anaerobic Stage on Membrane Fouling in MBR

    , M.Sc. Thesis Sharif University of Technology Mehrazaran, Mehdi (Author) ; Borghei, Mehdi (Supervisor) ; Musavi, Abbas (Co-Advisor)
    Abstract
    Clean water is a growing need for humanity all around the Earth. Due to the shortage of clean water resources in most parts of our planet, wastewater treatment and reuse has been of great value in past decades. Much research has been conducted to improve treatment systems. One of the most recent advancements in water and wastewater treatment field is application of membrane bioreactor systems. Despite many advantages of these systems, membrane fouling has been the main drawback since the creation and application of them. The main objective of this research is to investigate the probable fouling reduction and head loss in flat sheet UF membranes due to the application of an anaerobic... 

    Evaluate the kinetic of Containment Removal and Improving the Effect of the Biological Factors on Membrane Bio Reactors and Fouling Problem

    , M.Sc. Thesis Sharif University of Technology Seyedi, Mojtaba (Author) ; Shaygan SaleK, Jalaloddin (Supervisor)
    Abstract
    In this study as representatives of alkenylbenzenes and mono-alkylbenzenes respectively were considered individually and as binary mixtures. It was observed that styrene, and ethyl benzene were inhibitory types of substrates across the tested concentration ranges. Thus, biodegradation kinetic is well described by the Haldane model. Kinetic parameter's assessments from single substrate degradation tests and these parameters were used to predict possibly interaction factors achieved from dual substrate experiments. The achieved outcomes from mixture of experiments revealed that the ratio of depletion for each substrate is affected by the presence of the other. It was also inferred that ethyl... 

    Characterization of Protein Content in Soluble Microbial Products Involved in Fouling of Membrane Bioreactor

    , M.Sc. Thesis Sharif University of Technology Tanhaee, Zahra (Author) ; Torkian, Ayoub (Supervisor) ; Mousavi, Reza (Supervisor)
    Abstract
    Membrane bioreactors are increasingly being used for treatment of domestic and industrial effluents. A major operational drawback of this system is membrane fouling attributed to soluble microbial products (SMPs). In this study sampling were taken from microbial products on the surface and within the membrane pores and mixed liquir for mass characterization of protein content. Water-washing was used for surface and reversible portion of pore samples. Chemical wash with urea was used for further cleansing of SMPs within the pores. All samples were concentrate by precipitation with ammonium sulfate salt prior to analysis. Total protein content of samples was measured by lowry method. SDS-PAGE... 

    Oily wastewater treatment using membrane bioreactor

    , Article International Journal of Global Warming ; Vol. 6, issue. 2-3 , 2014 , pp. 295-302 ; ISSN: 17582083 Safa, M ; Alemzadeh, I ; Vossoughi, M ; Sharif University of Technology
    Abstract
    A novel implementation of a membrane bioreactor (MBR) has been studied in this paper. It is utilised as combination of rotating biological contractor (RBC) and an external membrane for oily wastewater treatment. The performance of MBR was compared with the standalone RBC. The RBC used in this investigation is the same one combined with the membrane to form the MBR. Wastewater biodegradability has been evaluated by two factors: chemical oxygen demand (COD) and total petroleum hydrocarbon (TPH). They are both compared together for different hydraulic retention times (HRTs) and petroleum pollution concentrations in RBC and MBR. The ratio of TPH to COD of molasses has been varied between 0.2 to...