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    A ratiometric fluorescence nanoprobe using CdTe QDs for fast detection of carbaryl insecticide in apple

    , Article Talanta ; Volume 221 , 2021 ; 00399140 (ISSN) Shahdost fard, F ; Fahimi Kashani, N ; Hormozi nezhad, M. R ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    In this study, a novel, simple and sensitive ratiometric fluorescence method is presented for the detection of very low quantities of the carbaryl in Iranian apple using cadmium telluride quantum dots (CdTe QDs) nanoprobe. The principle of the proposed strategy relies on the rapid hydrolysis of the carbaryl under an alkaline condition and production of the 1-naphthol with a blue emission at 470 nm. Besides, using the CdTe QDs with a yellow emission at 580 nm, as a reference, improves the visual tracking of carbaryl through changes in color tonality. The herein described methodology is applied for enzyme-free visual detection of carbaryl with satisfactory results in the presence of other... 

    Graphene oxide-starch-based micro-solid phase extraction of antibiotic residues from milk samples

    , Article Journal of Chromatography A ; Volume 1591 , 2019 , Pages 7-14 ; 00219673 (ISSN) Golzari Aqda, T ; Behkami, S ; Raoofi, M ; Bagheri, H ; Sharif University of Technology
    Elsevier B.V  2019
    Abstract
    In this study, a method was described for the extraction of three antibiotic residues from cow milk samples using a graphene oxide–starch–based nanocomposite. The prepared nanocomposites were employed as an extractive phase for micro-solid phase extraction of antibiotics from cow milk samples. The extracted antibiotics, i.e. amoxicillin, ampicillin and cloxacillin, were subsequently analyzed by high-performance liquid chromatography–ultraviolet detection (HPLC–UV). Important variables associated with the extraction and desorption efficiency were optimized. High extraction efficiencies for the selected antibiotics were conveniently achieved using the starch–based nanocomposite as the...