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Matrix acidizing aims at bypassing near wellbore damages in typical carbonate reservoirs or enhancing permeability and hydraulic conductivity in naturally fracture ones. The simulation of acidizing process at pore scale and complex geometries by LBM will lead to gain more knowledge about molecular mechanisms that govern rock dissolution, diffusion and advection of reactive fluid and help the evaluation of acidizing efficiency.In this thesis, simulation of acidizing includes the following steps:
• Multicomponent fluid convection
• Fluid diffusion into the solid
• Fluid-rock reaction
• Boundary conditions including periodic, bounceback, non-equilibrium bounceback, Dirichlet,... 

Heterogeneity is the major cause of the uneven acid distribution in carbonate acidizing. Traditional acidizing involves the injection of mineral acids, such as hydrochloric acid into the formation, which the bulk of the acidic solution permeates into the high-permeable layers and the low-permeability layers remain unreacted. So far, many chemical and mechanical techniques have been used to avoid the uneven distribution of acid. Using surfactant-based viscoelastic acids is one of the effective chemical method to divert acid to low-permeable zones. The unique feature of these acids is increasing viscosity of acidic solution as the pH increases. In this study, a two-scale continuum model... 

Carbonate matrix acidizing using hydrochloric acid which causes CO2 generation is one of the most popular well stimulation techniques in recent decades. Lots of the wormhole propagation models developed for laboratory scale, assumes that the cores are fully saturated with aqueous solution and no CO2 gas is produced. Final purpose of this research is to develop a geochemical model describing equilibrium composition of a 3 phase system of acidic solution-gas-rock accurately in common pressure and temperature conditions of carbonate matrix acidizing to obtain main inputs of acid reactive flow in porous media from it. In this regard, concept of the “extent of the reaction” is defined and after... 

Carbonate Matrix acidizing in order to improve or increase initial permeability, leads to different dissolution patterns under different operating and environmental conditions. In a specific rock / reactive fluid system, when a reactive fluid injects into the system in an optimal velocity, the dissolution pattern proceeds like a finger, names Wormhole. Formation of Wormhole is known as a success in acidizing process, because of its optimum porosity and permeability evolution and minimum pore volume injected of reactive fluid to breakthrough. So prediction of optimum injection velocity and analysis of dissolution patterns variation by change in operational and environmental conditions,... 

Well stimulation techniques are used to increase the productivity of oil and gas wells. One of the effective well stimulation methods, is matrix acidizing. During matrix acidizing, acidic solution is injected into the formation at pressure below the formation fracture pressure. Most of the time, acid needs to be reached to low permeability layers for more efficient damage removal. Divertors are used for diverting acid from high permeability to low permeability layers.Successful performance of a viscoelastic acid during an acid job, is highly dependent on the surfactant rheological properties. For a betaine viscoelastic surfactant, we have studied the effect of different parameters on the... 

One of the best stimulation methods for oil and gas wells is matrix acidizing in order to increase the near wellbore permeability. in acidizing, good acid coverage in different layers is one the main goals. so, various methods have been presented. important part in using these methods is to not damage formation and economic matters. modern methods utilize VES acids for this purpose. viscoelastic characteristics of these materials by formation of miscellaneous, increases the apparent viscosity by a large degree. for this reason, VES fluids can be used to improve acid divergence in acid injection operation. acid system based on viscoelastic surfactants that is changed to gel instantly, can be... 

Reactive flow through porous media is a phenomenon of high importance in various study subjects i.e. groundwater, mining, geology, and petroleum reservoirs. In petroleum engineering, a related topic to this phenomenon is the dissolution of the rock matrix due to acidizing. Near_wellbore carbonate rock acidizing has been used for decades in the petroleum industry to enhance the productivity of the well. Optimal injection rate is a key question in such operations. Various models have been used to simulate reactive flow in porous media many of which are continuum-scale that face significant uncertainty regarding the pore-scale nature of the flow, mass transfer, reaction, and subsequent changes... 

Acidizing is one of the common methods of stimulating the well to remove formation damage and Skin factor. In carbonate reservoirs, hydrochloric acid creates permeable channels called wormholes due to the reaction with the porous medium. Previous researches have studied the effect of the main rock and fluid parameters (temperature, pressure, type and concentration of acid and rock lithology) at the core scale. However, wellbore scale will different from core scale due to the difference in the wormhole density, the flow geometry, the amount of acid leakage from wormhole wall and competition. Very limited models predict these effects for large scales. In this research, the geometry of linear...