Sharif Digital Repository

Hollow structures show both light scattering and light trapping, which makes them promising for dye-sensitized solar cell (DSSC) applications. In this work, nanoparticulate hollow TiO 2 fibers are prepared by layer-by-layer (LbL) self-assembly deposition of TiO 2 nanoparticles on natural cellulose fibers as template, followed by thermal removal of the template. The effect of LbL parameters such as the type and molecular weight of polyelectrolyte, number of dip cycles, and the TiO 2 dispersion (amorphous or crystalline sol) are investigated. LbL deposition with weak polyelectrolytes (polyethylenimine, PEI) gives greater nanoparticle deposition yield compared to strong polyelectrolytes... 

Smart multilayered pH-sensitive nanocapsules were successfully fabricated using a Layer by Layer (LbL) process. The obtained products were characterized using FESEM, TEM, EDS and elemental mapping, zeta-potential, FTIR, TGA, SIMS and the Tafel polarization techniques. A 55% enhancement in ZrO2 particle size was detected in FESEM and TEM images with a corona view after the LbL process. EDS and elemental mapping analysis and measurements of zeta potential indicated the well-defined layered deposition. FTIR showed the electrostatic bonding between tolyltriazole (TTA) molecules and different overlapping layers. The thermal analysis and SIMS confirmed that 2.7% TTA loaded in nanocapsules. Tafel... 

Nanoparticles for biomedical use must be cytocompatible with the biological environment that they are exposed to. Current research has focused on the surface functionalization of nanoparticles by using proteins, polymers, thiols and other organic compounds. Here we show that inorganic nanoparticles such as titanium oxide can be coated by pyrolytic carbon (PyC) and that the coating has cytocompatible properties. Pyrolization and condensation of methane formed a thin layer of pyrolytic carbon on the titanium oxide core. The formation of the PyC shell retards coalescence and sintering of the ceramic phase. Our MTT assay shows that the PyC-coated particles are cytocompatible at employed doses  

The mechanism of interface formation during sinter–joining of nanostructured yttria stabilized zirconia (27 nm) compacts with chromium powder was investigated. The effect of sintering atmosphere, i.e. argon or vacuum, was studied. Microstructural evaluation and phase formation was examined by scanning electron microscopy (SEM), electron probe micro-analysis (EPMA), and micro-focused X-ray diffraction (MFXRD) methods. It is shown that spreading and evaporation–condensation mechanisms are responsible for the interface formation. An improved joint shear-strength was obtained after sintering in vacuum (74 MPa) compared with argon (41 MPa). The result of MFXRD indicated formation of Cr-island at... 

A glassy carbon electrode was coated with a thin layer of multi-walled carbon nanotubes and subsequently was electro-polymerized with polypyrrole. The prepared electrode was used for the voltammetric determination of olanzapine (OLZ). The peak current of OLZ increases remarkably on the surface of the modified electrode. This is due to the large increase in the microscopic area of the electrode surface along with the strong adsorption of OLZ on the surface of the electrode. The film modifier was characterized by scanning electron microscopy, atomic force microscopy and cyclic voltammetry techniques. Experimental variables, such as deposited amount of nanotube suspension, pH of the supporting... 

The steady 2-D boundary layer flow over a flat plate is studied analytically by homotopy perturbation method to analyze the entropy generation inside the boundary layer with constant wall temperature. By the transformations of go-verning equations including continuity, momentum, and energy by similarity va-riables, a dimensionless equation for entropy generation inside the boundary layer is obtained. The effects of important parameters such as Reynolds and Eck-ert numbers are investigated and the physical interpretations of the results are explained in details  

Antisolvent crystallization is known as an effective approach for the deposition of pinhole-free solution-processed perovskite layers for high-performance solar cells. Here, we introduce a modified antisolvent dripping method by adding tetra ethyl orthosilicate (TEOS) into chlorobenzene as a conventional antisolvent. Through TEOS modification, perovskite solar cells show efficiencies as high as 16% with more than 85% retention after 290 h storage at ambient conditions in comparison to 20% in pristine cells. This significant enhancement in efficiency and stability mainly related to the decrement of the density of surface defects, which is confirmed by considerably enhanced photoluminescence... 

In this paper, nanoscale vibrational analysis of a multi-layered graphene sheet embedded in an elastic medium is investigated and the corresponding resonant modes and frequencies are determined. It is known that the elastic moduli of a graphene sheet in two orientations x, y are different, so the graphene sheet is assumed to be a general form of an orthotropic plate. The orthotropic sheets stacking at the top of each other bond with carbon-carbon van der Waals forces, also the whole multi-layered graphene sheet is influenced by polymer-carbon van der Waals forces from the surrounding elastic medium  

The growth of cobalt silicides layer has been studied in Co/Ta, Co/Ta0.5W0.5 and Co/W bilayers grown on Si(100) substrate. The Co and Ta-W films were deposited using thermal evaporation and sputtering techniques, respectively. All these samples were annealed at a temperature range from 400 to 1000 °C in an N2 (80%)+H2 (20%) environment for 60 min. The phase identification and electrical property of the annealed samples were determined by XRD and RS methods. In the Co/Ta/Si(100) system, we have obtained nearly a single crystalline CoSi2(200) layer with RS value of approximately 0.9 Ω/□ at 900 °C. However, reappearance of Co2Ta phase at 1000 °C exhibits unsatisfactory thermal stability for... 

This paper shows how the structure and dynamics of a lightlike thin shell in general relativity can be obtained from a distributional approach  

Nanofiber layers have exciting properties such as fine fiber diameter, small pores, suitable connectivity between pores, high surface area and high porosity. These properties make nanofibers applicable for a variety of applications, such as high-performance filters and tissue engineering scaffolds. Different applications of electrospinning layers require different porosities. Therefore, it is very important to measure the porosity of nanofiber layers to express their application. To date, many methods have been expressed for this purpose, but all methods have disadvantages. Therefore, finding the best method is a challenge that will be addressed in this project. © 2022 The Author  

This letter presents an efficient polar code-based physical layer encryption (PLE) scheme with a short key length in comparison to the conventional symmetric key cryptosystems. By using the properties of polar codes, we consider several efficient techniques to reduce the key length and the computational overhead of the presented PLE scheme. Moreover, the results of the security analyses show that the proposed scheme has a high level of security against conventional attacks on the PLE schemes. In fact, reducing the key length and the computational overhead of the presented PLE scheme has no effect on its security level, which makes it suitable for secure mobile communication devices with... 

The aim of this research is bonding of three-layered St/AZ31/St composite by roll-bonding process. The roll-bonding process was performed at three preheating temperatures, 340, 400 and 450°C, with thickness reduction of 30 to 68% and different thicknesses of intermediate layer (AZ31). In order to improve the bonding strength, the as-rolled specimens were annealed at constant temperature of 375°C. For evaluation of bond strength and investigating the formation of a diffusion layer, the results of peel test and microscopic images were studied. Tensile specimens were prepared along the rolling direction to measure the mechanical properties of the composite. The results showed that by increasing... 

In this study, the boundary layer velocity profile on the upper surface of a supercritical airfoil in a forced sinusoidal pitching motion was measured and experimentally investigated. Measurements were performed using a boundary layer rake, including total pressure tubes positioned at 25 % of the chord far from the leading edge on the upper surface. For static measurements, the effects of the angle of attack between −3° and 14° and free-stream velocity between 40 m/s and 70 m/s were investigated; for dynamic measurements, the effects of oscillation amplitude variation between ±3° and ±10°, reduced frequency from 0.007 to 0.0313, and mean angle of attack between −3° and 6° were studied during... 

Recently, preparation of lightweight absorbers with high performance capability are urgently needed for practical demanded in order to solve the severe electromagnetic pollution. In the present study, two different composites (Fe3O4/carbon fiber and Fe3O4/rGO) were uniformly incorporated into resin epoxy matrix to obtain single and double layer X-band absorber with 20 wt% filler loading. Each of the composites were prepared via solvothermal process. According to the results, the minimum reflection loss values for each single layer Fe3O4/carbon fiber and Fe3O4/rGO absorber were −15 dB (3 mm thickness and 1.5 GHz bandwidth) and −50 dB (3 mm thickness and 4 GHz bandwidth) respectively. By... 

Molecular dynamics simulations are carried out to investigate the manipulation of metallic clusters on double-layer surfaces. The system parts are made of transition metals. The conditions which are subjected to change in the tests are material combinations for cluster, main substrate and lubricant layer (adlayer). In addition to qualitative observations, two criteria which represent the particle deformation and substrate abrasion are utilized as evaluation tools and are computed for each case. Obtaining this sort of knowledge is highly beneficial for further experiments in order to be able to plan the conditions and routines, which guarantee better success in the manipulation process  

Efficient storage and handling of data stored in a peer-to-peer (P2P) network, proves vital for various applications such as query processing and data mining. This paper presents a distributed, scalable and robust layered overlay (L-overlay) to index and manage multidimensional data in a dynamic P2P network. The proposed method distinguishes between the data and peer layers, with efficient mapping between the two. The data is organized such that semantically similar data objects are accessed hastily. Grid and tree structures are proposed for the peer layer. As application examples of L-overlay in query processing and data mining, k-nearest neighbors query processing and distributed Naïve... 

We present a new TiO2 morphology, featuring high surface area and open structure, synthesized by a two-step chemical route for the manufacture of dye-sensitized solar cells (DSSCs). This construct is sets of intertwined one-dimensional (1D) nanostructures (i.e., nanotubes), so-called skein-like nanotubes (NTs). Such morphology is produced by a combination of TiC oxidation and hydrothermal processes. The mesoporous TiO2 nanoparticles, as the product of TiC oxidation operation, is used as the precursor of hydrothermal process to grow the skein-like NTs. The effect of processing parameters of TiC oxidation and hydrothermal processes is studied. The skein-like morphology enables to eliminate the... 

The focus of the paper is on cross-layer transmission based on rateless coding for relay networks. In the proposed method, rateless coding is used at the packet level and a separate physical layer coding is used at the physical layer. As rateless codes are originally designed and optimized for erasure channels, using these codes at the physical layer can lead to significant performance degradation. The proposed scheme has the advantage of a cross-layer design which uses a rateless code at the packet level modeled by an erasure channel. Based on the analysis and simulation results provided in this paper, the cross-layer scheme results in earlier successful decoding at the destination