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    Heat transfer and entropy generation analysis of hybrid graphene/Fe3O4 ferro-nanofluid flow under the influence of a magnetic field

    , Article Powder Technology ; Volume 308 , 2017 , Pages 149-157 ; 00325910 (ISSN) Mehrali, M ; Sadeghinezhad, E ; Akhiani, A. R ; Tahan Latibari, S ; Metselaar, H. S. C ; Kherbeet, A. S ; Mehrali, M ; Sharif University of Technology
    Elsevier B.V  2017
    Abstract
    The heat transfer characteristics and entropy generation rate of hybrid graphene-magnetite nanofluids under forced laminar flow that subjected to the permanent magnetic fields were investigated. For this purpose, a nanoscale reduced graphene oxide-Fe3O4 hybrid was synthesized by using graphene oxide, iron salts and tannic acid as the reductant and stabilizer. The thermophysical and magnetic properties of the hybrid nanofluid have been widely characterized and thermal conductivity has shown an enhancement of 11%. The experimental results indicated that the heat transfer enhancement of hybrid magnetite nanofluid compared to the case of distilled was negligible when no magnetic field was... 

    Roles of metal, ligand and post synthetic modification on metal organic frameworks to extend their hydrophobicity and applicability toward ultra–trace determination of priority organic pollutants

    , Article Analytica Chimica Acta ; Volume 1125 , 2020 , Pages 231-246 Javanmardi, H ; Abbasi, A ; Bagheri, H ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    Implementation of metal organic frameworks (MOFs) in the separation science has attracted many researchers attention. In this study, the role of metal, ligand, the reaction condition and modification on the extraction efficiency of some MOFs was investigated. Among the prevalent reported MOFs, some members of the MIL and MOF–5 families were chosen, and eleven MOF–based sorbents were prepared by changing the metal and ligand type, reaction condition, and/or functionality through post synthetic modification (PSM). MIL–101 and MIL–101–NH2 based structures were initially synthesized based on the chromium and iron salts. Also, three zinc–based structures including MOF–5, [NH2(CH3)2]2...