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    Preparation, Characterization and Catalytic Application of Some Polyoxometalates for Esterification Reaction

    , M.Sc. Thesis Sharif University of Technology Nazari, Pegah (Author) ; Rahman Setayesh, Shahrbanoo (Supervisor)
    Abstract
    Catalytic esterification of acetic acid with 1-hexanol was investigated over polyoxometalates. H3PW12O40 and H3PMo6W6O40 polyoxometalates with keggin structures were synthesized. Catalytic activity and recyclability of them were improved by loading on the γ-Al2O3 with impregnation method and Cs, K and NH4 salts preparing.Catalysts were characterized by XRD, SEM, FT-IR, BET, DRS and NMR techniques. According to XRD's results, catalysts have ace-centered cubic crystal systems. Loading on supports and preparing the salts do not destroy the structures of polyoxometalates. SEM images show the uniformity of catalysts' surface and catalysts' fixing on the support. It was seen that the keggin... 

    Ni and Cu recovery by bioleaching from the printed circuit boards of mobile phones in non-conventional medium

    , Article Journal of Environmental Management ; Volume 250 , 2019 ; 03014797 (ISSN) Arshadi, M ; Nili, S ; Yaghmaei, S ; Sharif University of Technology
    Academic Press  2019
    Abstract
    There is a substantial volume of mobile phone waste every year. Due to the disadvantages of traditional methods, it is necessary to look for biological processes that are more eco-friendly and economical to recover metals from e-waste. Fungi provide large amounts of organic acids and dissolve metals but using sucrose in the medium is not economical. In this paper, the main objective is to find a suitable alternative carbon substrate instead of sucrose for fungi bioleaching of Ni and Cu in printed circuit boards (PCBs) of mobile phones using Penicillium simplicissimum. Four kinds of carbon sources (including sucrose, cheese whey, sugar, and sugar cane molasses) were selected. Also, pH and... 

    Enhancement of biological nitrogen removal performance using novel carriers based on the recycling of waste materials

    , Article Water Research ; Volume 170 , March , 2020 Massoompour, A. R ; Borghei, S. M ; Raie, M ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    This study aims to enhance biological nitrogen removal performance by the innovative carbon-based carriers. The new carriers were produced based on recycling waste materials. In these carriers, the advantages of the hybrid system and physicochemical properties of activated carbon were integrated to promote microbial attachment. To verify the performance of the new carriers compared to the conventional moving carriers, the experiments were conducted in two parallel laboratory-scale sequencing batch reactors under various operating conditions. The analysis revealed that the specific surface area of the new carrier with a total pore volume of 0.0015cm3/gr was 10.9 times the specific surface... 

    Biodegradation of styrene laden waste gas stream using a compost-based biofilter

    , Article Chemosphere ; Volume 60, Issue 3 , 2005 , Pages 434-439 ; 00456535 (ISSN) Dehghanzadeh, R ; Torkian, A ; Bina, B ; Poormoghaddas, H ; Kalantary, A ; Sharif University of Technology
    Elsevier Ltd  2005
    Abstract
    Biological treatment of waste gas styrene vapor was investigated in a three-stage bench-scale biofilter. Yard waste compost mixed with shredded hard plastics in a 25:75 v/v ratio of plastics:compost was inoculated with thickened municipal activated sludge. Microbial acclimation to styrene was achieved by exposing the system to an inlet concentration (CIn) of 0.25 g m -3 styrene and an empty bed retention time (EBRT) of 360 s for 30 days. Under steady-state conditions, maximum elimination capacity (EC) obtained was 45 g m-3 h-1 at a loading rate (L) of 60 g m -3 h-1 (CIn of 2 g m-3 and EBRT of 120 s). Reduction of retention time adversely impacted the performance resulting in the maximum EC... 

    The effect of different light intensities and light/dark regimes on the performance of photosynthetic microalgae microbial fuel cell

    , Article Bioresource Technology ; Volume 261 , 2018 , Pages 350-360 ; 09608524 (ISSN) Bazdar, E ; Roshandel, R ; Yaghmaei, S ; Mardanpour, M. M ; Sharif University of Technology
    Elsevier Ltd  2018
    Abstract
    This study develops a photosynthetic microalgae microbial fuel cell (PMMFC) engaged Chlorella vulgaris microalgae to investigate effect of light intensities and illumination regimes on simultaneous production of bioelectricity, biomass and wastewater treatment. The performance of the system under different light intensity (3500, 5000, 7000 and 10,000 lx) and light/dark regimes (24/00, 12/12, 16/8 h) was investigated. The optimum light intensity and light/dark regimes for achieving maximum yield of PMMFC were obtained. The maximum power density of 126 mW m−3, the coulombic efficiency of 78% and COD removal of 5.47% were achieved. The maximum biomass concentration of 4 g l−1 (or biomass yield... 

    Biological activated carbon process for biotransformation of azo dye carmoisine by klebsiella spp

    , Article Environmental Technology (United Kingdom) ; Volume 43, Issue 18 , 2022 , Pages 2713-2729 ; 09593330 (ISSN) Poorasadollah, D ; Bagheri Lotfabad, T ; Heydarinasab, A ; Yaghmaei, S ; Mohseni, F. A ; Sharif University of Technology
    Taylor and Francis Ltd  2022
    Abstract
    The feasibility of employing the biological activated carbon (BAC) process to debilitate azo dye Carmoisine by Klebsiella spp. was investigated. Plate assay revealed the capability of Klebsiella spp. for removal of Carmoisine via degradation. Kinetic parameters were measured for Carmoisine debilitation by Klebsiella spp. using the suspended anaerobic process. Two types of granular and rod-shaped activated carbon were used to form the biological beds in order to study the Carmoisine debilitation in batch processes. Scanning electron microscopy (SEM) and confocal laser scanning microscopy (CLSM) were used to indicate the colonization and biofilm formation of bacteria grown on activated carbon... 

    Development of bioreactors for comparative study of natural attenuation, biostimulation, and bioaugmentation of petroleum-hydrocarbon contaminated soil

    , Article Journal of Hazardous Materials ; Volume 342 , 2018 , Pages 270-278 ; 03043894 (ISSN) Safdari, M. S ; Kariminia, H. R ; Rahmati, M ; Fazlollahi, F ; Polasko, A ; Mahendra, S ; Wilding, W. V ; Fletcher, T. H ; Sharif University of Technology
    Elsevier B.V  2018
    Abstract
    Bioremediation of soil and groundwater sites contaminated by petroleum hydrocarbons is known as a technically viable, cost-effective, and environmentally sustainable technology. The purpose of this study is to investigate laboratory-scale bioremediation of petroleum-hydrocarbon contaminated soil through development of eight bioreactors, two bioreactors for each bioremediation mode. The modes were: (1) natural attenuation (NA); (2) biostimulation (BS) with oxygen and nutrients; (3) bioaugmentation (BA) with hydrocarbon degrading isolates; (4) a combination of biostimulation and bioaugmentation (BS-BA). Total petroleum hydrocarbons (TPH) mass balance over the bioreactors showed about 2% of...