Loading...
Search for: hydrophobic-chromatography
0.009 seconds

    Simultaneous voltammetric detection of ascorbic acid and uric acid at a carbon-paste modified electrode incorporating thionine-nafion ion-pair as an electron mediator

    , Article Electrochimica Acta ; Volume 51, Issue 13 , 2006 , Pages 2599-2606 ; 00134686 (ISSN) Shahrokhian, S ; Ghalkhani, M ; Sharif University of Technology
    2006
    Abstract
    The electrochemical behavior of ascorbic acid (AA) and uric acid (UA) at the surface of a carbon-paste electrode modified with incorporate thionine-nafion ion-paired was thoroughly investigated. The results show the presence of nafion inside the matrix of modified electrode, because of the effective ion-pairing and hydrophobic interactions, significantly enhances the stability of thionine as an electron mediator inside the modified electrode. A high reproducibility in voltammetric response to analyte species results because of this enhancement. The cyclic voltammetric studies using the prepared modified electrode show the best electrocatalytic property for the electro-oxidation of AA and...