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    Selective storage and evolution of hydrogen on nafion/NaCl/graphene quantum dot mixed matrix using tensammetry as power electrochemical technique

    , Article International Journal of Hydrogen Energy ; Volume 42, Issue 15 , 2017 , Pages 9428-9439 ; 03603199 (ISSN) Deylaminezhad, M ; Zakipour, M ; Doroodmand, M. M ; Mehrtash, M ; Sharif University of Technology
    Abstract
    Hydrogen storage/evolution behavior of nafion/NaCl/graphene quantum dot (GQD) mixed matrix as selective hydrogen capacitor (power source) was evaluated in detail through an electrochemical process at two independent potential ranges. For this purpose, a three-electrode system included Pt disk as counter electrode, Ag/AgCl as reference electrode and GQD-based mixed matrix-modified Pt disk as working electrode. For hydrogen storage, the deposition potential and time were evaluated to −1.0 V (vs. Ag/AgCl) and 120 s, respectively under high basic solution generated using NaOH (1.0 M) solution, followed by evolution of hydrogen at +0.8 V (vs. Ag/AgCl) during formation of hydrogen bubbles. The...