Loading...
Search for: hybrid-nanocomposite
0.006 seconds
Total 31 records

    Influence of Microstructure on Mechanical Properties and Fracture Behavior of Hybrid PP/GF/CaCO3 Composites

    , M.Sc. Thesis Sharif University of Technology Tabatabaei Ardakani, Ramin (Author) ; Ekrami, Ali Akbar (Supervisor) ; Bagheri, Reza (Supervisor)
    Abstract
    Homo-polymer of Polypropylene is a commodity thermoplastic with good physical and mechanical properties along with fair recyclability and cost. However, its application is limited in some cases, especially in automotive industry, due to a lack of toughness. One of the approaches for PP toughening is the copolymerization of PP with some ethylene co-monomers. However, existence of elastomers in this kind of polymers causes a decrease in tensile properties. Besides, glass fibers improve tensile properties of homo-and co-PP and decrease toughness of co-polymers but result in an increase for homo-polymers. A rise in expenditure of energy due to increasing the processing temperature and... 

    Study the Toughening Mechanisms in Hybrid Epoxy/Rubber/CNT Nanocomposites

    , M.Sc. Thesis Sharif University of Technology Jafari, Mohadeseh (Author) ; Bagheri, Reza (Supervisor) ; Pircheraghi, Gholamreza (Supervisor)
    Abstract
    Epoxy resins are used for a wide number of application due to good stiffness, chemical resistant and dimensional stability. This is the reason of their use as matrix in composite material. The incorporation of a small amount of carbon nanotubes (CNTs) in epoxy increases mechanical properties if nanocomposite have strong interfacial interaction between epoxy and CNTs, fine dispersion of CNTs and high final aspect ratio CNTs. In Noncovalent functionalization by polymer surfactant, CNTs are dispersed in a solvent/surfactant solution by ultra-sonication and then added to epoxy. In this thesis a novel study of toughening and mechanical properties of epoxy/ rubber/ CNT nanocomposite is presented.... 

    Effect of Microstructure Factors on Fracture Behavior of Clay-Rubber-Epoxy Hybrid Nanocomposites

    , Ph.D. Dissertation Sharif University of Technology Tekyeh Marouf, Bahereh (Author) ; Bagheri, Reza (Supervisor)
    Abstract
    The aim of this study is to investigate the effects of nanoclay and rubber particles morphologies on fracture behavior of a lightly cross-linked epoxy. In addition, the role of cavitation resistance of rubber particles on fracture behavior of the nanoclay-rubber-epoxy hybrids was studied. Two types of organoclay and three kinds of rubber modifiers (in micron and nano-size) were incorporated into the epoxy. The results obtained indicate that addition of either intercalated or exfoliated clay increases fracture toughness of the epoxy resin, although the increases in toughness are modest (a 50% increase). The microscopy examinations and the micromechanical models revealed that the... 

    Mechanical and Microstructural Behavior of Al1050/TiO2-Gr Nano-Composite Produced via Friction Stir Processing

    , M.Sc. Thesis Sharif University of Technology Farshbaf Ahmadi Pour, Mohammad (Author) ; Movahedi, Mojtaba (Supervisor) ; Kokabi, Amir Hossein (Supervisor)
    Abstract
    In the presented research, feasibility of producing hybrid nano-composite on the surface of Al1050 with TiO2 (~15 nm) and Graphite (~100 μm) reinforcement particles via Friction Stir Processing (FSP) has been investigated. 1.93%, 1.68% and 1.44% are the weight percentage of added reinforcement particles in the nano-composite. Rotational and travelling speeds (and their ratio, ω/v) and volume fraction of the embedded reinforcement particles, mentioned as variable parameters in this research. Despite, effect of these parameters on the microstructural evolution and mechanical properties such as strength, hardness and wear, were studied. Results in the ratio of Gr/TiO2 = 1/3, revealed that by... 

    Friction-Stir Processed Al-Al3Ti-MgO Hybrid Nanocomposites

    , M.Sc. Thesis Sharif University of Technology Sahandi Zangabad, Parham (Author) ; Kokabi, Amir Hossein (Supervisor) ; Simchi, Abdolreza (Supervisor)
    Abstract
    In recent years, investigation of mechanical properties of micro- and nano-structure materials, and peculiarly nanocomposites have been attracted a wide variety of researches. In this regard, friction-stir-processed (FSPed) metal matrix nanocomposites have been considered an important case with appropriate mechanical properties especially for fabrication of ultra-fine grained Al alloys and Al-matrix nanocomposites. In this research, Al matrix hybrid nanocomposites were fabricated via multi passes-friction stir processing (FSP) of Al-Mg alloy (AA5052) with different amounts (~2 and 3 vol%) of pre-placed TiO2 (30 nm) particles nanoparticles. It was revealed that employing of cumulative FSP up... 

    On the nonlinear dynamics of a multi-scale hybrid nanocomposite disk

    , Article Engineering with Computers ; 2020 Safarpour, M ; Ebrahimi, F ; Habibi, M ; Safarpour, H ; Sharif University of Technology
    Springer  2020
    Abstract
    This is the first research on the nonlinear frequency analysis of a multi-scale hybrid nanocomposite (MHC) disk (MHCD) resting on an elastic foundation subjected to nonlinear temperature gradient and mechanical loading is investigated. The matrix material is reinforced with carbon nanotubes (CNTs) or carbon fibers (CF) at the nano- or macroscale, respectively. We present a modified Halpin–Tsai model to predict the effective properties of the MHCD. The displacement–strain of nonlinear vibration of multi-scale laminated disk via third-order shear deformation theory (TSDT) and using Von Karman nonlinear shell theory is obtained. Hamilton’s principle is employed to establish the governing... 

    A hybrid nanocomposite of poly(styrene-methyl methacrylate- acrylic acid) /clay as a novel rheology-improvement additive for drilling fluids

    , Article Journal of Polymer Research ; Volume 26, Issue 2 , 2019 ; 10229760 (ISSN) Mohamadian, N ; Ghorbani, H ; Wood, D. A ; Abdollahi Khoshmardan, M ; Sharif University of Technology
    Springer Netherlands  2019
    Abstract
    The hybrid-polymer nanocomposite poly(styrene-methyl methacrylate- acrylic acid) /nanoclay was synthesized by miniemulsion polymerization for novel use as a drilling fluid additive. Three low-solid-drilling fluids (bentonite-based; natural polymer-based; nanoclay-based) were formulated using the hybrid nanocomposite as an additive and their rheological performance compared. The polymer/clay hybrid nanoparticles significantly improve rheological and filtration properties of the drilling fluids and they remain stable at high pressure, high temperature and harsh salinity conditions. The fluids’ filtration properties improve as the concentration of the polymer/nanoclay-hybrid-nanoparticles... 

    Fabrication and Characterization of Hybrid NanoComposites Based on Epoxy/NanoDiamond/CarbonFiber

    , M.Sc. Thesis Sharif University of Technology Sepehri Sadeghian, Mohammad Sajjad (Author) ;
    Abstract
    Polymer composites, due to its exclusive properties, has a special place in industry. Epoxy resin with high adhesion property, low density, thermal stability and high chemical resistance has a special place as matrix in fabrication of high technology hybrid composites. Hybrid composites, due to its high strength and long fatigue life, used to reinforcing building structures and manufacturing fuselage. Layer and reactive structure near the firm core and wear-resistant of NDs, used to improvement of epoxy reisn and hybrid NanoComposite interphase properties. In this study, for improvement of the properties of hybrid NanoComposites, used the NDs in 0.25, 0.5 and 1 %wt with amine and carboxyl... 

    The Growth and Characterization of Two-Dimensional Molybdenum Diselenide Crystals as Photodetectors

    , M.Sc. Thesis Sharif University of Technology Karimi, Fatemeh (Author) ; Esfandiar, Ali (Supervisor)
    Abstract
    A novel optoelectronic property of two-dimensional (2D) materials suggests they can be used for high-performance photodetector design. There has been a lot of attention paid to MoS2 and Despite its higher optical absorbance, MoSe2 has received little attention. A chemical vapor deposition system was used to prepare atomically thin MoSe2 films. Our research developed a method of preparing hexagon-shaped MoSe2 photodetector on Si/SiO2 substrates in atmospheric pressure with sawtooth edges, leading to large-scale MoSe2 layers with the size of ∼ 70µm . The Raman characterization of the grown flakes indicated that they possessed high quality few layers of MoSe2 and the distance between the two... 

    A mathematical method for XRD pattern interpretation in clay containing nano composites

    , Article Applied Surface Science ; Volume 318 , 1 November , 2014 , Pages 90-94 ; ISSN: 01694332 Khederlou, K ; Bagheri, R ; Shojaei, A ; Sharif University of Technology
    Abstract
    X-ray diffraction and rheological measurements were used to characterize nanoparticle dispersion in LDPE/LLDPE/nanoclay hybrid nanocomposites. XRD patterns were interpreted with a novel distribution formula and rheological measurements were used to confirm the results. Results of these two methods indicated that increasing clay in all the prepared nanocomposites exhibited a significant improvement in filler-matrix interaction because of increasing the probability of polymer diffusion but further exfoliation need more compatibilizing situations. It seems that this mathematical method could be used for predicting the overall change in clay gallery d-spacing and the extent of... 

    Influence of hard inclusions on microstructural characteristics and textural components during dissimilar friction-stir welding of an PM Al–Al2O3–SiC hybrid nanocomposite with AA1050 alloy

    , Article Science and Technology of Welding and Joining ; 2016 , Pages 1-16 ; 13621718 (ISSN) Khodabakhshi, F ; Simchi, A ; Kokabi, A. H ; Gerlich, A. P ; Nosko, M ; Švec, P ; Sharif University of Technology
    Taylor and Francis Ltd  2016
    Abstract
    Owing to the advantages of nanocomposites for structural applications, we present microstructural evolutions and texture development during dissimilar friction stir welding (DFSW) of an Al-matrix hybrid nanocomposite (Al-2 vol.-% Al2O3-2 vol.-% SiC) with AA1050. It is shown that DFSW can successfully be performed at a rotating speed of 1200 rev min−1 and a transverse speed of 50 mm min−1 while locating the nanocomposite at retreating side. Formation of macro-, micro-, and nano-mechanical interlocks between dissimilar base materials (BMs) as a result of FSW tool stirring action possessed an impact influence on the mechanical performance of dissimilar welds. Electron microscopy revealed... 

    Synthesis of metal-organic framework hybrid nanocomposites based on GO and CNT with high adsorption capacity for dye removal

    , Article Chemical Engineering Journal ; Volume 326 , 2017 , Pages 1145-1158 ; 13858947 (ISSN) Abdi, J ; Vossoughi, M ; Mahmoodi, N. M ; Alemzadeh, I ; Sharif University of Technology
    Abstract
    In this study, zeolitic imidazolate framework (ZIF-8) as a metal-organic framework (MOF) and its hybrid nanocomposites based on graphene oxide (GO) and carbon nanotubes (CNTs) were synthesized by facile method at an ambient temperature. The sufficiency of GO and CNT substrates as the main components of the composites to grow nanoscale MOFs and increase dispersive forces were investigated. The characteristics of the MOF and hybrid nanocomposites were studied using FTIR, SEM, XRD, BET and TGA techniques. The prepared nanomaterials applied as adsorbents to remove malachite green (MG) as a cationic dye from colored wastewater. The removal rates of the hybrid nanocomposites were greater than that... 

    On the nonlinear dynamics of a multi-scale hybrid nanocomposite disk

    , Article Engineering with Computers ; Volume 37, Issue 3 , 2021 , Pages 2369-2388 ; 01770667 (ISSN) Safarpour, M ; Ebrahimi, F ; Habibi, M ; Safarpour, H ; Sharif University of Technology
    Springer Science and Business Media Deutschland GmbH  2021
    Abstract
    This is the first research on the nonlinear frequency analysis of a multi-scale hybrid nanocomposite (MHC) disk (MHCD) resting on an elastic foundation subjected to nonlinear temperature gradient and mechanical loading is investigated. The matrix material is reinforced with carbon nanotubes (CNTs) or carbon fibers (CF) at the nano- or macroscale, respectively. We present a modified Halpin–Tsai model to predict the effective properties of the MHCD. The displacement–strain of nonlinear vibration of multi-scale laminated disk via third-order shear deformation theory (TSDT) and using Von Karman nonlinear shell theory is obtained. Hamilton’s principle is employed to establish the governing... 

    Hot deformation behavior of an aluminum-matrix hybrid nanocomposite fabricated by friction stir processing

    , Article Materials Science and Engineering A ; Volume 626 , 2015 , Pages 458-466 ; 09215093 (ISSN) Khodabakhshi, F ; Gerlich, A. P ; Simchi, A ; Kokabi, A. H ; Sharif University of Technology
    Abstract
    A fine-grained aluminum-matrix hybrid nanocomposite reinforced with TiO2, MgO and Al3Ti nanoparticles was prepared via reactive friction stir processing (FSP) of an Al-Mg sheet with pre-placed TiO2 particles (50nm; 3.1vol%). The microstructure of the hybrid nanocomposite comprises high-angle grain boundaries (~90%) with an average size of 2μm and hard inclusions with sizes in the range of 30-50nm. Evaluation of the hot deformation behavior of the nanocomposite by uniaxial tensile testing at different temperatures (300-450°C) and strain rates (0.001-0.1s-1) shows that the deformation apparent activation energy of the nanocomposite is 137kJmol-1 at ≤300°C. The values of the activation energy... 

    Synthesis of Metal-organic Frameworks (MOFs) Nano-hybrids for Removal of Organic Pollutants from Petrochemical and Colored Wastewaters

    , Ph.D. Dissertation Sharif University of Technology Abdi, Jafar (Author) ; Vossoughi, Manouchehr (Supervisor) ; Mahmoodi, Niyaz Mohammad (Supervisor) ; Alemzadeh, Iran (Supervisor)
    Abstract
    Physical processes such as adsorption and membrane filtration are in progress and considered as efficient methods in separation and treatment of organic pollutants from petrochemical and colored wastewaters. The advantages of these methods include high energy efficiency, low cost, facile process, and regeneration and implementation ability for a wide range of contaminants. Nevertheless,requirement of suitable materials as adsorbents with high adsorption capacity, capability of preparing membranes based on these materials, optimization of process conditions and removal improvement have still remained as the main challenges; therefore, these topics have been mentioned as main aims of this... 

    Synthesis, Characterization and Investigation of Electrocatalytic Activity of Nanoparticle/Cerium Oxide Composites in Oxygen Evolution and Reduction Reactions

    , M.Sc. Thesis Sharif University of Technology Moravvej, Heydar (Author) ; Taherinia, Davood (Supervisor)
    Abstract
    The sluggish kinetics of oxygen evolution and reduction on the surface of electrodes is a major problem for the widespread use of devices that are based on sustainable, renewable and clean technologies, such as fuel cells and metal–air batteries. Therefore, the development of efficient and cost–effective materials for the oxygen evolution (OER: Oxygen Evolution Reaction) and reduction reactions (ORR: Oxygen Reduction Reaction) is highly desirable. In recent years, Metal–organic frameworks (MOFs) and their derivatives, have drawn considerable attention as potential catalysts and electrocatalyst due to their high surface area and porous structure. In this study, cerium (IV) oxide was... 

    Synthesis, Characterization and Investigation of Electrocatalytic Activity of Nanoparticle/Cerium Oxide Composites in Oxygen Evolution and Reduction Reactions

    , M.Sc. Thesis Sharif University of Technology Moravvej, Heydar (Author) ; Taherinia, Davood (Supervisor)
    Abstract
    The sluggish kinetics of oxygen evolution and reduction on the surface of electrodes is a major problem for the widespread use of devices that are based on sustainable, renewable and clean technologies, such as fuel cells and metal–air batteries. Therefore, the development of efficient and cost–effective materials for the oxygen evolution (OER: Oxygen Evolution Reaction) and reduction reactions (ORR: Oxygen Reduction Reaction) is highly desirable. In recent years, Metal–organic frameworks (MOFs) and their derivatives, have drawn considerable attention as potential catalysts and electrocatalyst due to their high surface area and porous structure. In this study, cerium (IV) oxide was... 

    Investigaion Properties of Electrocatalytic Transition Metal Chalcogenids Nanocomposite in Hydrogen and Oxygen Evolution Reactions

    , M.Sc. Thesis Sharif University of Technology Moazzeni, Mohammad (Author) ; Taherinia, Davood (Supervisor)
    Abstract
    Electrochemical water splitting which consists of two half-reactions, namely; the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER), is an important process in electrochemical energy storage and sustainable production of energy. Therefore, the development of cost-effective and efficient electrocatalysts for water splitting has attracted a lot of interest. In this work, a new nanocomposite was prepared from cobalt diselenide and cerium (IV) oxide derived from calcination of a cerium-based metal-organic framework (Ce-MOF), via hydrothermal and electrodeposition methods. The structure and morphology of synthesized materials were investigated by XRD, FE-SEM, EDX, and BET... 

    Synthesis of Fe-TiC-Al2O3 hybrid nanocomposite via carbothermal reduction enhanced by mechanical activation

    , Article Ceramics International ; Volume 37, Issue 2 , March , 2011 , Pages 443-449 ; 02728842 (ISSN) Razavi, M ; Rajabi Zamani, A. H ; Rahimipour, M. R ; Kaboli, R ; Shabani, M.O ; Yazdani Rad, R ; Sharif University of Technology
    Abstract
    In this study, the feasibility of the synthesis of Fe-TiC-Al 2O3 hybrid nanocomposite via mechanical activation followed by carbothermal reduction was investigated. The raw materials including ilmenite, carbon black and aluminum powder were milled in a high energy planetary ball mill. At different time intervals, samples were taken for characterization. After phase evaluation with XRD, some samples were heat treated in an atmosphere controlled tube furnace. Studies proved that increasing the milling time of the raw materials resulted in the formation of more amorphous phase and more active materials. Furthermore, investigations showed that after carbothermal reduction, the synthesized TiC... 

    Fatigue fracture of friction-stir processed Al-Al3Ti-MgO hybrid nanocomposites

    , Article International Journal of Fatigue ; Volume 87 , 2016 , Pages 266-278 ; 01421123 (ISSN) Sahandi Zangabad, P ; Khodabakhshi, F ; Simchi, A ; Kokabi, A. H ; Sharif University of Technology
    Elsevier Ltd 
    Abstract
    This paper presents experimental results on the fatigue properties of Al-matrix nanocomposites prepared by the friction stir processing (FSP) technique. An Al-Mg alloy (AA5052) with different amounts (∼2 and 3.5 vol%) of pre-placed TiO2 nanoparticles were FSPed up to 6 passes to attain homogenous dispersion of nano-metric inclusions. Microstructural studies by electron microscopic and electron back scattering diffraction (EBSD) techniques showed that nano-metric Al3Ti (50 nm), TiO2 (30 nm), and MgO (50 nm) particles were distributed throughout a fine-grained Al matrix (<2 μm). Consequently, a significant improvement in the tensile strength and hardness was attained. Uniaxial...