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    Performance enhancement of dissolved air flotation column in removing low concentrations of heavy fuel oil by adding powdered activated carbon

    , Article Desalination and Water Treatment ; Volume 51, Issue 16-18 , 2013 , Pages 3353-3360 ; 19443994 (ISSN) Hosseinzadeh, H ; Shayegan, J ; Jalali, M ; Sharif University of Technology
    Taylor and Francis Inc  2013
    Abstract
    In this study, the effect of adding walnut shell-based powdered activated carbon (WS) to a bench-scale dissolved air flotation (DAF) column on oil removal was investigated. All experiments were conducted using synthetically prepared wastewater containing low but stable concentrations of heavy fuel oil. After comparing the effect of different WS doses from 0 (blank) to 40 mg/L at the saturator pressure of 5 bar and 10 min flotation time, 20 mg/L WS was chosen as the optimal concentration. In order to find the best flotation time for efficient use of WS capacity, experiments were repeated with and without 20 mg/L WS at longer flotation times. According to the obtained results, by adding WS,... 

    Modeling of Heavy Residual oil Conversion to Synthetic Gas

    , M.Sc. Thesis Sharif University of Technology Alipour, Amin (Author) ; Badakhshan, Amir (Supervisor) ; khorashe, Farhad (Supervisor)
    Abstract
    According to global improving consumption of distillate products, like gasoline and diesel, reduction in light petroleum production and growth in exploring and extraction of heavy and sour petroleum, changing in refining structure of worldwide oil refineries is necessary and it is crucial to apply special processes for refining, conversion and cleaning of these heavy and extra-heavy petroleum. Gasification of these fuels, i.e. partial thermal oxidation of feed in the presence of gasifying agent (air, oxygen, steam or mixture of them) in the gasifier, is one of the new ways to convert heavy fuel oil to synthetic gas (syngas), that this gas can be used widely in downstream processes. Here,... 

    Numerical Simulation of Reacting Flow in Large Scale Heavy Fuel Oil Fired Furnaces to Control Temperature Field and NOx Emission

    , M.Sc. Thesis Sharif University of Technology Fatin, Ali (Author) ; Darbandi, Masoud (Supervisor)
    Abstract
    Heavy fuel oil (HFO) is usually consumed in large scale furnaces, e.g., those of power plants. Experience shows that its combustion produces large amount of NOx emission. In present study, a large scale heavy fuel oil fired furnace is numerically simulated to investigate different possible solutions for NOx reduction. In this regard, a computational framework is firstly designed benefiting from the researches reported previously in literature. The results of this framework are then compared with available measurements to evaluate the accuracy of current designed computational framework. Second, the influences of a number of different controlling parameters are studied carefully to improve... 

    Numerical study on NOx reduction in a large-scale heavy fuel oil-fired boiler using suitable burner adjustments

    , Article Energy ; Volume 199 , 2020 Darbandi, M ; Fatin, A ; Bordbar, H ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    A numerical framework was carefully developed to simulate the combustion of heavy-fuel-oil (HFO) in a large-scale boiler. The present numerical solutions were compared with the measured data of a laboratory benchmark test and on-site operational data of the chosen HFO-fired boiler. Next, the developed framework was used to perform sensitivity analyses aiming to reduce the NO emission from the HFO-fired boiler without any adverse effect on its combustion performance. Practically, this study focused on re-adjustments of 24 working burners, which could control combustion in the HFO-fired boiler. The early outcome showed that the boiler NO emission and its combustion performance could be... 

    Resolution and quantification of complex mixtures of polycyclic aromatic hydrocarbons in heavy fuel oil sample by means of GC × GC-TOFMS combined to multivariate curve resolution

    , Article Analytical Chemistry ; Volume 83, Issue 24 , 2011 , Pages 9289-9297 ; 00032700 (ISSN) Parastar, H ; Radović, J. R ; Jalali-Heravi, M ; Diez, S ; Bayona, J. M ; Tauler, R ; Sharif University of Technology
    Abstract
    Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC × GC-TOFMS) combined to multivariate curve resolution-alternating least-squares (MCR-ALS) is proposed for the resolution and quantification of very complex mixtures of compounds such as polycyclic aromatic hydrocarbons (PAHs) in heavy fuel oil (HFO). Different GC × GC-TOFMS data slices acquired during the analysis of HFO samples and PAH standards were simultaneously analyzed using the MCR-ALS method to resolve the pure component elution profiles in the two chromatographic dimensions as well as their pure mass spectra. Outstandingly, retention time shifts within and between GC × GC runs were not affecting...