Sharif Digital Repository

In this research MPA capped CdTe nanocrystals with sizes around 2.7-3.5 nm were grown in aqueous solution. The process was performed through the reaction of NaHTe with MPA and CdCl2 solution in high temperature. The synthesis was carried out in two different states of standard and modified forms. In the modified synthesis, the hydrazine hydrate material was added to the MPA plus CdCl2 solution before injection. The evolution of the nanocrystals size and PL quantum yield was monitored during the heating time for the growth. The results demonstrated that for the standard synthesis the growth rate was slow. The CdTe nanocrystals with high PL quantum yields were achieved in more than 10 h of... 

In this article, satisfying the second law of thermodynamics, we present a 3D constitutive model for shape memory polymers. The model is based on an additive decomposition of the strain into four parts. Also, evolution laws for internal variables during both cooling and heating processes are proposed. Since temperature has considerable effect on the shape memory polymer behavior, for simulation of a shape memory polymer-based structure, it is required to perform a heat-transfer analysis. Commonly, an experimentally observed temperature rate-dependent behavior of shape memory polymers is justified by a rate-dependent glassy temperature, but using the heat-transfer analysis, it is shown that... 

This article addresses a combined approach of sliding mode control (SMC) with generalized predictive control (GPC) to achieve fluid temperature control in the evaporator of a heat recovery steam generator. The evaporator is modelled as a first-order plus dead time process. The model is developed using the experimental data obtained at an actual power plant. An output error identification algorithm is used to minimize the error between the model and the experiments in different operating conditions. A GPC method is exploited to optimize the sliding surface and the coefficients of the switching functions used in SMC. The proposed control schemes are evaluated by thorough simulation for... 

The Steam Assisted Gravity Drainage (SAGD) process, a developed Enhanced Oil Recovery (EOR) process to recover oil and bitumen, has been studied theoretically and experimentally in conventional reservoirs and models and is found a promising EOR method for certain heavy oil reservoirs. In this work simulation studies of the SAGD process were made on different fractured models consisting of fractures in both Near Well Region (NWR) and Above Well Region (AWR) and even in the presence of networked fractures. At early stage of the SAGD process in fractured system, steam moves through the fractures first and then the matrix blocks are heated primarily by conduction and possibly some steam... 

In this work we report a new thermochemical method for the synthesis of ZnS:Mn nanocrystals. Zn(NO3)2 and Na2S 2O3 were used as the precursors and Mn(NO 3)2 was the source of impurity. Thioglycerol (TG,C 3H8O2S) was also used as the capping agent and the catalyst of the reaction. Na2S2O3 is a heat sensitive material which releases S species upon heating. Consequently, the reaction proceeds in temperatures higher than room temperature. The reaction was done in two steps. In the first step, the precursors were heated at 96 °C for an hour without TG. In the second step, TG was injected to the solution and the heating process was continued for longer heating durations. A fast growth occurred in...