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    Experimental study and thermodynamic modeling for determining the effect of non-polar solvent (hexane)/polar solvent (methanol) ratio and moisture content on the lipid extraction efficiency from Chlorella vulgaris

    , Article Bioresource Technology ; Volume 201 , 2016 , Pages 304-311 ; 09608524 (ISSN) Malekzadeh, M ; Abedini Najafabadi, H ; Hakim, M ; Feilizadeh, M ; Vossoughi, M ; Rashtchian, D ; Sharif University of Technology
    Elsevier Ltd 
    Abstract
    In this research, organic solvent composed of hexane and methanol was used for lipid extraction from dry and wet biomass of Chlorella vulgaris. The results indicated that lipid and fatty acid extraction yield was decreased by increasing the moisture content of biomass. However, the maximum extraction efficiency was attained by applying equivolume mixture of hexane and methanol for both dry and wet biomass. Thermodynamic modeling was employed to estimate the effect of hexane/methanol ratio and moisture content on fatty acid extraction yield. Hansen solubility parameter was used in adjusting the interaction parameters of the model, which led to decrease the number of tuning parameters from 6... 

    Influence of additives on the morphology of PVDF membranes based on phase diagram: thermodynamic and experimental study

    , Article Journal of Applied Polymer Science ; Volume 135, Issue 21 , 2018 ; 00218995 (ISSN) Mohsenpour, S ; Khosravanian, A ; Sharif University of Technology
    John Wiley and Sons Inc  2018
    Abstract
    In the present study, the morphology of asymmetric poly(vinylidene fluoride) blend membranes which were prepared by the phase inversion method is rationalized by comparing two non-dimensional number represent thermodynamic and kinetic properties of the prepared membrane. These two parameters change phase diagram and demixing rate between solvent and nonsolvent. TiO2 nanoparticles and polyvinylpyrrolidone were used as additives. Hansen solubility parameters of the components are calculated by Van Krevelen method. Furthermore, kinetic and thermodynamic properties of the prepared solutions are determined by drawing phase diagrams and controlling mass transfer rate during precipitation of...