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Total 22 records

    Production of Copper Nanoparticles by Electromagnetic Levitation Melting Method

    , M.Sc. Thesis Sharif University of Technology Derakhshan, Rouzbeh (Author) ; Halali, Mohammad (Supervisor)
    Abstract
    In this research Copper Nanoparticles have been synthesized by electromagnetic levitation gas condensation method which is a novel method for producing fine and pure metallic powders. Copper samples with 2 gr weight were levitated and then melted.the supersaturated vapor above the melted droplet have been cooled exerting pure argon and helium as cooling and carrier medias. To investigate the morphology and particle size of the produced nanoparticles, SEM and DLS analysis have been used and for characterizing the elements exist in the powder ,XRD analysis have been carried out.SEM images and DLS analysis of produced powder showed spherical cooper nanoparticles with narrow size distribution... 

    Synthesis of Pure Aluminum Nanoparticles by Electromagnetic Levitation Melting Gas Condensation

    , M.Sc. Thesis Sharif University of Technology Sabooni Tabari, Ra’na (Author) ; Halali, Mohammad (Supervisor)
    Abstract
    In current project, high purity nanoparticles were synthesized by use of Electromagnetic Levitation Melting Gas Condensation (ELM-GC) method. In this case high purity aluminum samples were melted by this method to a temperature of 1683 0C in a silica tube. High purity argon and helium gases were employed as carrier gases and cooling agents. To study particle size, morphology, and purity of obtained nanoparticles, Field Emission Scanning Electron Microscopy (FE-SEM), X-ray Diffraction (XRD), Dynamics Light Scattering (DLS), and ADS analysis were employed. The FE-SEM and DLS tests confirmed narrow size distribute of spherical shape pure aluminum nanoparticles under both inert gases. The... 

    An Investigation on Production of Silver Nanopowder by Electromagnetic Levitation Melting Method

    , M.Sc. Thesis Sharif University of Technology Malekzadeh, Mahdieh (Author) ; Halali, Mohammad (Supervisor)
    Abstract
    Electromagnetic levitation gas condensation (ELGC) method was used to synthesize silver nanoparticles. Silver droplets were melted and levitated stably at about 1130 °C with appropriate flat coils in a 10 mm OD silica tube. High purity argon, nitrogen and helium were employed as carrier gases and cooling media. Morphology and particle size of the products were investigated by scanning and transmission electron microscopy (SEM and TEM), X-ray diffraction (XRD) energy dispersive X-ray analysis (EDAX) and dynamic light scattering (DLS). The DLS, SEM and TEM studies demonstrated narrow size distribution of spherical shape Ag nanoparticles with particle size of about 60, 45 and 35 nm synthesized... 

    Synthesis of Pure Titanium Nanoparticles by Electromagnetic Levitation Melting Gas Condensation

    , M.Sc. Thesis Sharif University of Technology Vahid Mohammadi, Armin (Author) ; Halali, Mohammad (Supervisor)
    Abstract
    High purity titanium nanoparticles were synthesized by utilizing Electromagnetic Levitation Melting Gas Condensation (ELM-GC) method. High purity titanium samples were melted by electromagnetic levitation to a temperature of 1700 ± 20 °C in a silica tube. High purity argon and helium were employed as carrier gases and cooling agent. Particlesize, morphology, and Purity of the produced nanoparticles were studied by Field-Emission Scanning Electron Microscopy (FE-SEM), X-ray Diffraction (XRD), Dynamic Light Scattering (DLS), X-ray fluorescence (XRF), and ICP-AES analysis. The FE-SEM, DLS and XRF studies confirmed narrow size distribution of almost spherical shape pure titanium nanoparticles... 

    Investigation of Nucleation and Growth of Metallic Nanoparticlaes from the Gas Phase by Molecular Dynamic Simulation

    , M.Sc. Thesis Sharif University of Technology Naghibi Nezhad, Mohsen (Author) ; Askari, Masoud (Supervisor) ; Simchi, Abdolreza (Supervisor)
    Abstract
    Formation of nanoparticles by the gas phase condensation process is one of the most promising methods for the nanoparticles synthesis. Finding the correlations between adjustable parameters of the process and nanoparticles properties depends on how parameters affect the mechanism of nucleation and growth. The use of classical nucleation theory at nanoscale leads to unacceptable results; hence, approaches such as molecular dynamic simulation (MD) have been proposed to investigate the mechanism of nucleation and growth at atomic scale. In the present work, the formation of iron clusters from a supersaturated gas phase was investigated via molecular dynamics simulation. For thermalization of... 

    Production of Magnesium Nanoparticles by Electromagnetinc Levitation Melting

    , M.Sc. Thesis Sharif University of Technology Ahmadi, Mahdi (Author) ; Halali, Mohammad (Supervisor)
    Abstract
    Electromagnetic levitation(EML) provides a process producing nanoparticles using gas condensation method. In gas condensation processes, vapor is produced by heating the sample then inert gas is applied to provide the inert atmosphere and also cool and condense the sample vapor into a nano powder to obtain a sample nanoparticle. In the EML method, rapidly alternating electromagnetic field induces eddy current in the conducting sample which will heat the sample. The current in the sample result in an induced magnetic field. Consequently, the sample droplet is heated and levitated simultaneously by an induction furnace as a generator. The sample temperature is dependent on parameters such as... 

    Effects of contaminants on the mass-transfer characteristics of a two-impinging-streams gas-liquid reactor

    , Article Chemical Engineering and Technology ; Volume 34, Issue 11 , 2011 , Pages 1797-1806 ; 09307516 (ISSN) Dehkordi, A. M ; Savari, C ; Sharif University of Technology
    Abstract
    The mass-transfer characteristics of a new type of two-impinging-streams reactor (TISR) was studied by means of sodium sulfite solution as the liquid phase and air as the gas phase, in the presence and absence of various types of surface-active agents (SAAs). The influences of anionic, cationic, and nonionic SAAs on the specific interfacial area and overall volumetric mass-transfer coefficient obtained in the TISR were investigated. It was found that the presence of a little amount of the above-mentioned contaminants increases the specific interfacial area and decreases the overall volumetric mass-transfer coefficient. On the basis of the experimental results obtained for various types of... 

    Prediction of water content of sour and acid gases

    , Article Fluid Phase Equilibria ; Volume 299, Issue 2 , December , 2010 , Pages 171-179 ; 03783812 (ISSN) Zirrahi, M ; Azin, R ; Hassanzadeh, H ; Moshfeghian, M ; Sharif University of Technology
    2010
    Abstract
    Estimating the feasibility of acid gas geological disposal requires the knowledge of the water content of the gas phase at moderate pressures and temperatures (typically below 50MPa, below 380K) and up to 6mol NaCl. In this paper, a non-iterative model is developed to predict the water content of sour and acid gases at equilibrium with pure water and brine. This model is based on equating the chemical potential of water and using the modified Redlich-Kwong equation of state to calculate the fugacity of the gas phase. The water content of pure CH4, CO2 and H2S are represented with average absolute deviations of less than 3.36, 7.04 and 8.4%, respectively. Experimental data of the water... 

    Numerical Modeling of Film Condensation in the Plate-Fin Heat Exchanger Used in the CO2 Capturing and Storage Process

    , M.Sc. Thesis Sharif University of Technology Khorampoor, Nima (Author) ; Saeedi, Mohammad Hassan (Supervisor)
    Abstract
    Due to the wide application of plate-fin heat exchangers in various industries such as the petrochemical industry, aerospace industry, air conditioning systems, separation and liquefaction of gases, especially natural gas, boiling, condensation, and transportation industries, proper design of these heat exchangers is necessary. Most of the previous researches in the field of heat exchanger modeling has been done in single-phase mode. The two-phase modeling has been performed, often thermodynamically, and the effects of turbulence and surface tension have been ignored. Thus, in the present study, numerical modeling of the two-phase plate-fin heat exchanger is presented. In this project,... 

    Effect of bubble size and angle of tapering upriser pipe on the performance of airlift pumps

    , Article Particulate Science and Technology ; Volume 28, Issue 4 , Aug , 2010 , Pages 332-347 ; 02726351 (ISSN) Hanafizadeh, P ; Saidi, M. H ; Karimi, A ; Zamiri, A ; Sharif University of Technology
    2010
    Abstract
    Airlift pumps are devices with the ability to lift liquid phase by injecting the gas phase. Parameters that affect the performance of these pumps are divided into two groups. The first group contains design parameters such as diameter of the pipe, tapering angle of the upriser pipe, and the submergence ratio, which is the ratio of immersed length to the total length of the upriser. The second group includes operating parameters such as the gas flow rate, bubble diameter, bubble distribution, and inlet gas pressure. In this research, the performance of an airlift pump is investigated numerically for different submergence ratios and different diameter of the upriser pipe. For this purpose, an... 

    Geometry effects in Eulerian/Granular simulation of a turbulent FCC riser with a (kg-g)-KTGF model

    , Article International Journal of Chemical Reactor Engineering ; Volume 8 , 2010 ; 15426580 (ISSN) Nazif, H. R ; Basirat Tabrizi, H ; Farhadpour, F. A ; Sharif University of Technology
    Abstract
    Three-dimensional, transient turbulent particulate flow in an FCC riser is modeled using an Eulerian/Granular approach. The turbulence in the gas phase is described by a modified realizable (kg-g) closure model and the kinetic theory of granular flow (KTGF) is employed for the particulate phase. Separate simulations are conducted for a rectangular and a cylindrical riser with similar dimensions. The model predictions are validated against experimental data of Sommerfeld et al (2002) and also compared with the previously reported LES-KTGF simulations of Hansen et al (2003) for the rectangular riser. The (kg-g)-KTGF model does not perform as well as the LES-KTGF model for the riser with a... 

    Effect of bubble size and angle of tapered upriser pipe on the effectiveness of a two phase lifting pump

    , Article 2009 ASME Fluids Engineering Division Summer Conference, 2nd August 2009 through 6 August 2009 ; Volume 1, Issue PART B , 2009 , Pages 807-814 ; 9780791843727 (ISBN) Hanafizadeh, P ; Saidi, M. H ; Zamiri, A ; Karimi, A ; Sharif University of Technology
    2009
    Abstract
    Two phase lifting pumps are devices with the ability of lifting liquid phase by injecting the gas phase. Parameters which affect the performance of these pumps are divided into two groups. The first group contains design parameters such as diameter of the pipe, tapering angle of the upriser pipe and the submergence ratio which is the ratio of immersed length to the total length of the upriser. The second group includes operating parameters, such as the gas flow rate, bubble diameter, bubble distribution and inlet gas pressure. In this research, the performance of two phase lifting pump is investigated numerically for different submergence ratios and different diameter of the upriser pipe.... 

    One-dimensional numerical investigation of a cylindrical micro combustor

    , Article Proceedings of the ASME Summer Heat Transfer Conference 2009, HT2009 ; Volume 3 , 2009 , Pages 115-123 ; 9780791843581 (ISBN) Irani R, A ; Saediamiri, M ; Saidi, M. S ; Saidi, M. H ; Shafii, M. B ; Sharif University of Technology
    Abstract
    In this paper, a one-dimensional numerical approach is used to study the effect of various parameters such as micro combustor diameter, mass flow rate and external convection heat transfer coefficient on the temperature and species mass fraction profiles. A premixed mixture of H2-Air with a multi-step chemistry (9 species and 19 reactions) is used and thermal conductivity of the mixture is considered as a function of species thermal conductivity and temperature by using a set of new relations. The transient gas phase energy and species conservation equations result in an Advection-Diffusion-Reaction system (A-D-R) that leads to two stiff systems of PDEs, which can not be solved by... 

    Nanoparticle catalysts

    , Article Journal of Physics D: Applied Physics ; Volume 42, Issue 23 , 2009 ; 00223727 (ISSN) Zaker Moshfegh, A. R ; Sharif University of Technology
    2009
    Abstract
    In this review, the importance of nanoparticles (NPs), with emphasis on their general and specific properties, especially the high surface-to-volume ratio (A/V), in many technological and industrial applications is studied. Some physical and chemical preparation methods for growing several metallic and binary alloy NP catalysts are reviewed. The growth and mechanism of catalytic reactions for synthesis of 1D nanostructures such as ZnO nanowires and multiwall carbon nanotubes (MWCNTs) are discussed. Gas-phase production with emphasis on dependence of catalytic activity and selectivity on size, shape and structure of NPs is also investigated. Application of NP catalysts in several... 

    How hydrogen-bonded MnO4- can influence oxidation of olefins in both gas phase and solution?

    , Article Journal of Physical Organic Chemistry ; Volume 25, Issue 12 , 2012 , Pages 1198-1209 ; 08943230 (ISSN) Javan, M. J ; Tehrani, Z. A ; Fattahi, A ; Hashemi, M. M ; Sharif University of Technology
    2012
    Abstract
    The reaction pathway (including the transition state) of ethylene addition to permanganate (MnO4-) in the presence of ethylene glycol (EG) has been qualitatively and quantitatively studied by means of B3LYP/6-311++G* theoretical analysis. Interestingly, by cluster formation of the EG with permanganate, oxidation reaction becomes thermodynamically and kinetically more favorable. The influences of electron-withdrawing as well as electron-donating substituents were also explored. Results of the quantum theory of atoms in molecules and natural bond orbital analyses revealed that [3 + 2] addition reaction of alkenes in the presence of EG as hydrogen bonding donor to MnO4- becomes more exothermic.... 

    Influence of the hydrogen bonding on the basicity of selected macrocyclic amines

    , Article Journal of Physical Organic Chemistry ; Volume 25, Issue 9 , 2012 , Pages 803-810 ; 08943230 (ISSN) Nasiri, M ; Shakourian Fard, M ; Fattahi, A ; Sharif University of Technology
    2012
    Abstract
    The optimized minimum-energy geometries of different macrocyclic amines and their protonated structures were determined by using ab initio and density functional theory (DFT) calculations. All the gas phase optimizations and energy calculations were performed at the DFT/B3LYP/6-311++G(d,p) level of theory. The HF/6-31 + G(d,p) level was used for all single point calculations in the solution phase. Geometry optimizations indicate that the most stable structures are stabilized by intramolecular hydrogen bonds. The proton affinity (PA) of macrocyclic amines is controlled by the strength of intramolecular hydrogen bonds of macrocyclic amines. These hydrogen bonds strongly influence the basicity... 

    What roles do boron substitutions play in structural, tautomeric, base pairing and electronic properties of uracil? NBO & AIM analysis

    , Article Journal of Physical Organic Chemistry ; Volume 25, Issue 9 , 2012 , Pages 787-796 ; 08943230 (ISSN) AliakbarTehrani, Z ; Abedin, A ; Shakourian Fard, M ; Fattahi, A ; Sharif University of Technology
    Wiley  2012
    Abstract
    The synthesis of modified versions of deoxyribonucleic acid is an area that is receiving much attention. The replacement of the nitrogen atom on the nucleobases with boron atom has provided insight into deoxyribonucleic acid and ribonucleic acid stability, recognition, and replication at the atomic level. In the present research, we investigated a detailed density functional theory study of the structural, tautomeric, base-pairing ability, bond dissociation energy, and electronic properties of two boron analogues (i.e., boron substitutions at 4-position and 5-position of uracil) of uracil nucleobase. The effects of these modifications on theirs acid-base properties have been considered. Our... 

    Experimental and computational bridgehead C-H bond dissociation enthalpies

    , Article Journal of Organic Chemistry ; Volume 77, Issue 4 , January , 2012 , Pages 1909-1914 ; 00223263 (ISSN) Fattahi, A ; Lis, L ; Tehrani, Z. A ; Marimanikkuppam, S. S ; Kass, S. R ; Sharif University of Technology
    Abstract
    Bridgehead C-H bond dissociation enthalpies of 105.7 ± 2.0, 102.9 ± 1.7, and 102.4 ± 1.9 kcal mol -1 for bicyclo[2.2.1]heptane, bicyclo[2.2.2]octane, and adamantane, respectively, were determined in the gas phase by making use of a thermodynamic cycle (i.e., BDE(R-H) = ΔH° acid(H-X) - IE(H •) + EA(X •)). These results are in good accord with high-level G3 theory calculations, and the experimental values along with G3 predictions for bicyclo[1.1.1]pentane, bicyclo[2.1.1]hexane, bicyclo[3.1.1]heptane, and bicyclo[4.2.1]nonane were found to correlate with the flexibility of the ring system. Rare examples of alkyl anions in the gas phase are also provided  

    Two-dimensional numerical investigation of a micro combustor

    , Article Scientia Iranica ; Volume 17, Issue 6 B , December , 2010 , Pages 433-442 ; 10263098 (ISSN) Irani Rahaghi, A ; Saidi, M. S ; Saidi, M. H ; Shafii, M. B ; Sharif University of Technology
    2010
    Abstract
    In this paper, a two-dimensional numerical approach is used to study the effect of micro combustor height, mass flow rate and external convection heat transfer coefficient on the temperature and species mass fraction profiles. A premixed mixture of H2-Air with a multi-step chemistry is used. The transient gas phase energy and species conservation equations result in an Advection-Diffusion-Reaction system that leads to two stiff systems of PDEs. In the present work, the computational domain is solved through the Strang splitting method, which is suitable for a nonlinear stiff system of PDEs. A revised boundary condition for the velocity equation is applied and its effect on the flow... 

    A wet cold-flow technology for tackling offshore flow-assurance problems

    , Article SPE Projects, Facilities and Construction ; Volume 5, Issue 2 , 2010 , Pages 58-64 ; 19422431 (ISSN) Azarinezhad, R ; Chapoy, A ; Anderson, R ; Tohidi, B ; Sharif University of Technology
    2010
    Abstract
    Flow assurance is a major challenge in offshore and deepwater operations. Conventional approaches for preventing gas-hydrate formation involve using thermodynamic inhibitors (e.g., methanol, glycol) or kinetic hydrate inhibitors or operating outside the hydratestability zone by insulating the pipeline and/or active heating. These techniques are not always economical and in some cases are not practical for deepwater operations, long tiebacks, or aging reservoirs with high water cuts. The industry needs new and novel flow-assurance techniques to address these challenging conditions. The approach presented in this paper is a wet cold-flow-based method in which gas-hydrate management rather than...