Sharif Digital Repository

In this study, a noble robust superhydrophobic and highly oleophobic polyurethane (PU)–SiO2 nanoparticle (NP) coating is specially designed using sol-gel process. For this purpose the effective parameters on surface tension and durability of the synthesized coating investigated and optimized. This new superhydrophobic and highly oleophobic coating exhibits good pensile hardness as high as 6H with adhesive force grade of 5B and repels water and oil with contact angles (CAs) of 159° and 140° respectively. The synthesized PU-SiO2 composite also retains an excellent amphiphobicity after a 7 days immersion in water with water and oil with CAs of 150° and 130°. Facile fabrication of PU–SiO2... 

In this experimental study, the impacts of replacing cement by Mica and Feldspar on rheological, mechanical and thermal durability of self-compacting mortars (SCMs) are investigated. The cement was partially replaced by Mica and Feldspar at the substitution rates of 10%, 20% and 30%. In general, 14 mix designs of SCMs were considered in two series with w/b ratios of 0.4 and 0.3. For assessment of rheological properties, mini-cone slump flow test and mini V-funnel tests were performed. The compressive strengths after 3, 7, 28 and 90 days of curing, and the 28-day flexural strength were obtained. All mixes were subjected to water absorption and sorptivity tests. For investigating the thermal... 

The monolithic catalytic converter still is the main pollution control device for modern vehicles in order to reach the ever-increasing legislative demands for low emission standards. The catalytic converters require a large expansion from the exhaust pipe to the front face of the monolith. Unfortunately, packaging constraints often do not permit the use of long diffusers. Hence, flow separation within the diffuser leads to a non-uniform flow distribution across the monolith. A uniform flow distribution at the inlet monolith face is favorable for the conversion efficiency as well as the durability of the catalytic converter. Therefore the main problem is to optimize the flow distribution at... 

The properties of self-compacting concrete (SCC) can be manipulated by the addition of nano-montmorillonite (NMMT) clays. This paper presents the results of an experimental investigation on incorporating small dosages of NMMT clays (.25,.50,.75 and 1.00% addition by mass of total cementitious material) into SCC. Tests were conducted on fresh and hardened specimens to measure workability (by slump flow, V-funnel and L-box), mechanical (by compressive and splitting tensile strengths), durability (electrical resistivity and water penetration) and microstructural (X-ray diffraction and scanning electron microscopy) properties of control and NMMT-reinforced SCCs. The results showed that the... 

This paper investigated the combined utilization of recycled waste ceramic aggregate (RWCA) and waste carpet fibers (WCFs) in high strength concrete (HSC). Concrete mixes containing different percentages of RWCA including 20%, 40%, 60% (by weight) as partial replacement of natural coarse aggregate (NCA) were prepared. To enhance the tensile and flexural strength of concrete, 1.0% (by volume) WCF was added to the mixes. The slump and density of the fresh concrete were evaluated, both of which demonstrated a decreasing trend with incorporation of RWCA and WCF. With regard to the hardened concrete, replacing 40% of NCA with RWCA led to the optimum mechanical properties and increased the... 

Polymer concrete is well-known for quick repairing of concrete structures and pavement. However, there are relatively few studies on the durability of epoxy polymer concrete (EPC). This study aims to investigate the long-term environmental effects on the mechanical properties of EPC. Therefore, EPC and ordinary cement concrete (OCC) specimens were prepared and exposed to four chemical solutions with pH values of 2.5, 7, 12.5 and artificial seawater in intervals of 1, 3, 6, 9 and 12 months. Epoxy resin (10 and 12% by weight) and Portland cement were used as binder phase in EPC and OCC specimens, respectively. Scanning electron microscopy (SEM) was additionally applied to investigate the... 

Assessing the durability of concrete is of prime importance to provide an adequate service life and reduce the repairing cost of structures. Freeze-thaw is one such test that indicates the ability of concrete to last a long time without a significant loss in its performance. In this study, the freeze-thaw resistance of polymer concrete containing different polymer contents was explored and compared to various conventional cement concretes. Concretes’ fresh and hardened properties were assessed for their workability, air content, and compressive strength. The mass loss, length change, dynamic modulus of elasticity, and residual compressive strength were determined for all types of concretes... 

The popularity of self-compacting concrete (SCC), as an innovative construction materials in concrete industry, has increased all over the world in recent decades. SCC offers a safer construction process and durable concrete structure due to its typical fresh concrete behavior which is achieved by SCC's significantly different mixture composition. This modification of mix composition may have significant effect on the hardened mechanical properties of SCC as compared to normal vibrated concrete (NVC). Therefore, it is necessary to know whether the use of all rules and relations that have been formulated for NVC in current design codes based on years of experience are also valid for SCC.... 

At present study, Endurance Time (ET) method that is a new dynamic pushover procedure is introduced and its application in predicting concrete arch dam behavior in linear domain is investigated. In this method structure is subjected to gradually intensifying acceleration functions. DEZ arch dam was selected as case study. FE model of dam-reservoir-foundation was excited in three levels of MCL, MDL, DBL using six records scaled based on design spectrum of the site and results were compared with those obtained from ET analyses. It was found that results obtained from ET method at equivalent target time are in good agreement with extreme results obtained from exciting the system using natural... 

In Endurance Time (ET) method gradually intensifying acceleration functions are created in a manner that the linear and nonlinear response spectra of them, while being proportional to average of real earthquakes spectra, intensifies in a uniform manner with time. These functions are used as input functions for nonlinear time history analysis of structures and performance of structures is assessed based on the maximum time duration that they can meet the specified performance objectives. In this paper, application of the ET method in nonlinear seismic analysis of structures has been investigated. Numerical procedures and optimization techniques that are used for the production of acceleration... 

In Endurance Time (ET) method, structures are subjected to gradually intensifying accelerograms and their performance is judged based on the maximum time duration in which they can satisfy the predefined endurance criteria. Damage indexes are used in ET method as the endurance criteria. In this paper, correlation between the values of various damage indexes as obtained from nonlinear time-history analysis of steel moment frames subjected to scaled earthquakes are compared with those from ET method at the same level of spectral acceleration. It is shown that the average value of various damage indexes can be estimated from ET analysis results. Advantages, accuracy and limitations of this... 

The Endurance Time (ET) method is a time-history based dynamic pushover procedure for seismic analysis and design of structures. In this procedure, structures are subjected to a specially designed intensifying accelerogram and their Endurance Time is measured based on the time interval during which they can resist the imposed dynamic actions. In this paper, application of the ET method in linear seismic analysis of structures has been investigated. The procedure for generating code compliant uniformly intensifying ET accelerograms has been explained. A set of three such accelerograms have been applied to various moment and braced steel frames and the results of analysis are compared to... 

Valveless micropumps are widely used due to simple structure, durability and low maintenance. Understanding the fluid-membrane interaction and performance criteria is still a challenging problem for the scientists. In this work, a new model for side mounted valve micropumps is developed to obtain dynamic response of micropump with respect to piezoelectric actuation. The parameters of this model are obtained in terms of actuation frequency and geometrical dimensions of the micropump. Balancing elastic, inertial and damping forces result in the governing equation of the micropump system model. Analytical studies for the bottom mounted valve micropump indicate pump flux is independent of the... 

The properties of self-compacting concrete (SCC) can be manipulated by the addition of nano-montmorillonite (NMMT) clays. This paper presents the results of an experimental investigation on incorporating small dosages of NMMT clays (.25, .50, .75 and 1.00% addition by mass of total cementitious material) into SCC. Tests were conducted on fresh and hardened specimens to measure workability (by slump flow, V-funnel and L-box), mechanical (by compressive and splitting tensile strengths), durability (electrical resistivity and water penetration) and microstructural (X-ray diffraction and scanning electron microscopy) properties of control and NMMT-reinforced SCCs. The results showed that the... 

The aim of the present study is to investigate the effects of using hybrid fibers on rheological, mechanical and durability properties of the high-strength self-consolidating concrete (SCC). For this purpose, two types of fibers including hooked-end steel fibers and polypropylene fibers were used. In this study, a total of eleven mixtures were used: one as a control mix, one containing 0.5% steel fibers, four containing 0.5% hybrid fibers (steel and polypropylene), one containing 1.0% steel fibers and the four containing 1.0% hybrid fibers (steel and polypropylene). For investigating the rheological properties, slump flow, J-ring and V-funnel tests were performed. Mechanical properties were... 

Mechanism of removal of lead from silicate glass containing 68.5 wt% PbO by 0.5 N HNO3 was investigated by incorporation of the chemical-analyses/weight-loss data into shrinking-core model (SCM) and minimization of the difference. Scanning electron microscopy (SEM), emission spectrometry with inductively coupled plasma (ICP), X-ray diffraction (XRD) and energy dispersive X-ray analysis (EDS) were used to determine the compositional changes of the lead-silicate glass (LSG) samples. Dual inter-diffusion chemical reaction mechanisms having respective activation energies of 83.49 and 47.80 kJ/mol dominated the deleading process. © 2009 Elsevier B.V. All rights reserved  

This study presents the results of an experimental evaluation of the performance of high strength concrete (HSC)with basic oxygen steel-making (BOS)slag and nano-silica respectively used as a partial replacement of sand and cement. The properties of fresh and hardened concrete specimens containing 25%, 50%, 75%, and 100% BOS as partial replacement of sand and 2% of cement replaced with nano-silica were evaluated. According to the results, concrete samples containing nano-silica with higher BOS percentages, demonstrated improvements in strength and durability properties, while workability was reduced. For example, at 50% BOS content, about 18% increase in compressive strength and 50%...