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      Synthesis, X-ray studies, and catalytic activity of tridentate Schiff base dioxo-molybdenum(VI)

      , Article Journal of Coordination Chemistry ; Volume 67, Issue 14 , 2014 ; ISSN: 00958972 Amini, M ; Khaksar, M ; Boghaei, D. M ; Bagherzadeh, M ; Ellern, A ; Woo, L. K ; Sharif University of Technology
      Abstract
      The reaction of a solution of MoO2(acac)2 in CH3OH and salicylidene 2-picoloyl hydrazone as a tridentate ONO donor Schiff base (ONO) afford a six-coordinated Mo(VI) complex [MoO2(ONO)(CH3OH)], with a distorted octahedral configuration. [MoO2(ONO)(CH3OH)] was isolated as an air-stable crystalline solid and fully characterized by single-crystal X-ray structure analysis. [MoO2(ONO)(CH3OH)] shows reactivity in the oxidation of sulfides to their corresponding sulfoxides using urea hydrogen peroxide as the oxidant at room temperature under air  
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