Sharif Digital Repository

Using a model reduction method, a formula for the ideality factor of a pn junction as a function of the diffusion and generation terms of its reverse current is derived. Using this formula a method for separate computation of these two currents for a pn junction is presented. The validity of the method is investigated using computer simulations for an assumed diode with known ideality factor and total leakage current. Experimental results for two commercially available diodes validate the proposed technique  

During miscible displacements in fractured porous media, one of the most important factors that plays a significant role in oil production is the matrix-fracture interaction. In this work, a series of hydrocarbon injection experiments have been performed on a fractured glass micromodel that was designed specifically to study matrix-fracture interaction. A high quality image analysis method was used to determine the fluid flow behavior, solvent front movement, and viscous fingering associated with solvent movement in matrix and fractures. Observations showed that in the case of unit viscosity ratio, the injection rate increased the slope of recovery curve and consequently improved the final... 

Different concentrations of CaF2 were incorporated in mica glass-ceramics to evaluate their effects on the crystallization and microstructure. The kinetics of phase transformations, and the microstructures of the final crystalline phase were found to be dependent on the concentration of nucleation agents. The results showed that CaF2 in high concentration had a synergistic effect and enhanced the formation of interlocked mica crystals. Non-isothermal DTA experiments showed that the crystallization activation energies of base glasses were changed in the range of 235-405 kJ/mol, while the crystallization activation energies of samples with addition of CaF2 were changed in the range of 419-747... 

This work utilizes the direct simulation Monte Carlo (DSMC) calculations and examines the influence of rarefication on the mixing length and effective diffusion coefficient in a two-species mixing problem. There have been efforts in past rarefied mixing flow studies to bridge between the mixing evolution rate and Knudsen number. A careful review of those efforts shows that the past derived relations did not determine the weights of Reynolds (or Peclet) number in the rarefaction influences. Although they indicated that an increase in Knudsen would decrease the mixing length, such reductions were primarily due to the Reynolds (or Peclet) reduction. Therefore, those studies could not explicitly... 

This investigation aims at understanding the underlying fundamentals of the isothermal solidification phenomenon during the transient liquid phase (TLP) bonding process. The isothermal solidification is governed by solid-state diffusion of the melting point depressant (MPD) into the base material, which, in turn, is controlled by both kinetic and thermodynamic parameters; however, the latter factor is generally ignored. In this work, the competition between kinetics and thermodynamics of diffusion were considered in TLP bonding of a nickel alloy, Monel 400, using two distinct filler metals including pure copper (Cu) and Ni-Si-B filler metal. The joint generated by Ni-Si-B filler metal... 

In recent years, various nanocars have been synthesized in order to provide controlled mechanical function, transport other nanoparticles, or enable bottom-up assembly capability. There have even been racing competitions among well-known nanocars in which the wheels play an influential role. In this paper, the motion of thermally driven nanocars equipped with p-carborane wheels on Au(111) and Au(001) substrates is investigated. For the sake of comparison, classical all-atom molecular dynamics (MD) and rigid-body MD (RBMD) have been used to study the motion threshold as well as to analyze the effect of temperature, substrate crystalline direction, and chassis shape on the diffusive motion of... 

In recent years, various nanocars have been synthesized in order to provide controlled mechanical function, transport other nanoparticles, or enable bottom-up assembly capability. There have even been racing competitions among well-known nanocars in which the wheels play an influential role. In this paper, the motion of thermally driven nanocars equipped with p-carborane wheels on Au(111) and Au(001) substrates is investigated. For the sake of comparison, classical all-Atom molecular dynamics (MD) and rigid-body MD (RBMD) have been used to study the motion threshold as well as to analyze the effect of temperature, substrate crystalline direction, and chassis shape on the diffusive motion of... 

An efficient method for the synthesis of 4-amino-5-pyrimidinecarbonitriles by three-component reaction of malononitrile, aldehydes and N-unsubstituted amidines, under aqueous conditions, using CuO nanoparticles as catalyst is reported. The protocol offers advantages in terms of higher yields, short reaction times, and mild reaction conditions, with reusability of the catalyst  

Molecular diffusion of gases in crude oils plays a crucial role in several oil recovery processes especially in cold-based production process. However, experimental data concerning CO2 diffusivity in heavy oils due to the tedious nature of diffusivity measurements are relatively rare in the open literature. In this work, a comprehensive experimental investigation of the effective molecular diffusion determination of CO2-heavy oil systems in homogeneous porous media was studied. The so-called pressure decay method was applied to measure the molecular diffusivity of carbon dioxide in heavy oil. Furthermore, effect of various parameters such as initial pressure, temperature and porous media on... 

To improve the strength and toughness of AISI 4340 steel, different microstructures, containing full bainite, bainite-ferrite, martensite-ferrite and full martensite were produced by different heat treatment cycles. Tensile, impact and hardness tests were carried out at room temperature. The ductile-brittle transition temperature was determined from impact data at different temperatures. The results showed that steel with bainite - 0.34 ferrite microstructure has the highest elongation and charpy impact energy, while its tensile strength and yield stress decreased in comparison to other microstructures. This increment was noticeable when bainite - 0.34 ferrite steel was tempered. The... 

The as-cast FSX-414 Co-based superalloy samples were solution treated at 1150°C for 4h and then aged at 980°C for 4h. Specimens for joining were cut from the as-cast ingot and TLP bonding carried out at the same conditions as for the solution and solution+aging treatment, using MBF-30 interlayer. Microstructures were studied for as-cast, heat treated and TLP bonded specimens. These studies showed that the ununiform distributed carbides of MC type in the as-cast specimens replaced by M23C6 type carbides with uniform distribution in the heat treated microstructure. Due to complete isothermal solidification, no eutectic structure in the bond region were wasobserved, but some intermetallics in... 

The oxidation behavior of three types of stainless steels, namely AISI 321, AISI 316, and AISI 409, was compared. In all stainless steels, oxide layers were formed and their masses and thicknesses increased with oxidation time. Among them, AISI 409 ferritic stainless steel demonstrated higher oxidation rate. According to the kinetical oxidation behavior of them at elevated temperatures, the oxidation mechanism was determined. Among them, the AISI 409 ferritic stainless steel showed the lowest and AISI 321 austenitic stainless steel demonstrated the highest oxidation resistance. Based on the experimental results, it was suggested that the kinetic of oxide growth in stainless steels was... 

Isothermal solidification stage during transient liquid phase bonding is the key to preclude intermetallic phase formation during solidification of the liquid phase. The rate of isothermal solidification is controlled by solid-state diffusion. Therefore, the bonding time required to complete isothermal solidification is generally long. This paper reports a very short isothermal solidification time for transient liquid phase bonding of IN617 solid solution nickel-based superalloy using a boron-containing filler metal. A eutectic-free bond with limited grain growth in the base material with high shear strength is achievable by utilizing a short (i.e., 5 minutes) thermal bonding strategy. The... 

The effect of pulsed direct current (PDC) on solid-state diffusion in the Ni–Al binary system was investigated. Two experimental schemes were employed: in the presence and absence of an electric field. The diffusion couples were heat-treated for 1.5, 3, and 5 h at 803, 833, and 863 K. Under the investigated conditions, only two intermetallic phases (NiAl3 and Ni2Al3) formed at the boundary of the metals. It was shown that the PDC passing through the diffusion couple significantly enhanced the growth rates of both phases. The apparent reaction–diffusion coefficients were DNiAl3=4.0×10−9exp(−[Formula presented]) and DNi2Al3=9.7×10−9exp(−[Formula presented]) in the field-assisted scheme,... 

The present paper deals with different effects of homogenization time and cooling environment on Ni-42.5wt%Ti-7.5wt%Cu alloy. The alloy was prepared by vacuum arc melting. Afterwards, three homogenization times (half, one and two hour) and three cooling environments (water, air and furnace) at 1373 K were selected. Optical and Scanning Electron Microscopic methods, EDX, DSC and hardness tests have been used to evaluate the microstructure, transformation temperatures and hardness. Results indicate that specimens that were cooled in air are super-saturated. Also, the microstructure from furnace cooling has many disparities with the other cooling environments' microstructure and two types of... 

The quantification of carbon dioxide (CO2) dissolution in oil is crucial in predicting the potential and long-term behavior of CO2 in reservoir during secondary and tertiary oil recovery. Accurate predicting carbon dioxide molecular diffusion coefficient is a key parameter during carbon dioxide injection into oil reservoirs. In this study a new model based on adaptive neuro-fuzzy inference systems (ANFIS) is designed and developed for accurate prediction of carbon dioxide diffusivity in oils at elevated temperature and pressures. Particle Swarm Optimization (PSO) as population based stochastic search algorithms was applied to obtain the optimal ANFIS model parameters. Furthermore, a simple... 

Fluid particle diffusion through blood flow within a capillary tube is an important phenomenon to understand, especially for studies in mass transport in the microcirculation as well as in solving technical issues involved in mixing in biomedical microdevices. In this paper, the spreading of tracer particles through up to 20% hematocrit blood, flowing in a capillary tube, was studied using a confocal micro-PTV system. We tracked hundreds of particles in high-hematocrit blood and measured the radial dispersion coefficient. Results yielded significant enhancement of the particle diffusion, due to a micron-scale flow-field generated by red blood cell motions. By increasing the flow rate, the... 

4340 steel bars were austenitized at 850°C for 1 hour followed by heating at 700°C (ferrite and austenite region) for 90 min and quenching into a salt bath with different temperatures of 300, 350, 400 and 450°C. The steel bars were held for 1 hour at these temperatures before air cooling to room temperature. Various ferrite-bainite microstructures with 34% volume fraction of ferrite and different bainite morphologies were obtained. The results of SEM studies showed that by increasing the austempering temperature, the morphology of bainite varies from lower to upper bainite. According to the T-T-T diagram of the studied steel, the bainite transformation will not complete for the holding time... 

Coaxial electrospinning with the ability to use simultaneously two separate solvents provides a promising strategy for drug delivery. Nevertheless, controlled release of hydrophilic and sensitive therapeutics from slow biodegradable polymers is still challenging. To address this gap, we fabricated core-sheath fibers for dual delivery of lysozyme, as a model protein, and phenytoin sodium as a small therapeutic molecule. The sheath was processed by a gelatin solution while the core fibers were fabricated from an aqueous gelatin/PVA solution. Microstructural studies by transmission and scanning electron microscopy reveal the formation of homogeneous core-sheath nanofibers with an outer and...