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    Effects of nucleation agent particle size on properties, crystallisation and microstructure of glass-ceramics in TiO2-ZrO2-Li 2O-CaO- Al2O3-SiO2 system

    , Article Advances in Applied Ceramics ; Volume 109, Issue 6 , 2010 , Pages 318-323 ; 17436753 (ISSN) Nemati, A ; Goharian, P ; Shabanian, M ; Afshar, A ; Sharif University of Technology
    2010
    Abstract
    The objective of this study was to evaluate the effects of P 2O5 particle size distribution on the crystalline phases and microstructure of lithium disilicate glass-ceramics derived from the TiO2-ZrO2-Li2O-CaO-Al2O 3-SiO2 system for dentistry applications. The samples were made via fusion and casting procedure. Crystallisation as well as the morphology and microstructure of the samples were investigated using X-ray diffraction, differential scanning calorimetric and scanning electron microscopy. The results showed that the crystallisation of the samples occurred in the range of 500-650°C. The main crystalline phase was lithium disilicate (Li2Si2O5) along with Lithium metasilicate (Li2SiO3),...