Sharif Digital Repository

We study Hydrogen sulfide gas detection properties of pure and 1% copper oxide added WO3 thin films. The spin coated deposits on alumina substrates were annealed at 500 C for 1 hour in order to improve the crystallinity of the films. The sensitivity of pure tungsten oxide is poor even at temperatures of about 100 C but the doped samples exhibit good response to H2S gas. Our data show sensitivity of about 1500 in 10 ppm diluted gas in air at 100 C. The films are sensitive to the gas even at 250 ppb (sensitivity about 2) H2S concentration at 100 C but with rather long recovery time. Crystal structure, morphology and chemical composition of samples were studied by X-Ray diffraction (XRD),... 

This work describes the development of a novel electrochemical sensor based on electrodeposition of copper oxide nanoparticles onto carbon nanoparticle (CNP) film modified electrode for the analysis of the anti-HIV drug, nevirapine (NEV). The electrochemical experiments were performed using linear sweep and cyclic voltammetry. Atomic force microscopy was applied for surface characterization of the deposited modifier film (CuO-CNP) on glassy carbon electrode (GCE). No oxidation peak was observed for NEV on the bare GCE, but both CNP-GCE and CuO-CNP-GCE showed a distinctive anodic response towards NEV with considerable enhancement (276-fold and 350-fold, respectively) compared to CuO-GCE. The... 

A facile hydrothermal method and subsequent electroactivation have been developed to fabricate three-dimensional (3D) CuO nanosheet arrays on the copper foil substrate, which can be used directly as a binder-free electrode for supercapacitor applications. Under optimum conditions, by using this facile method, a high capacitance of 125 mF/cm2 at a current density of 0.3 mA/cm2 is obtained. The prepared supercapacitor showed a good rate capability (46.4% capacitance retention, when the current density is increased to more than 30 times) and an excellent cyclability (more than 88% capacitance retention after 3000 cycles). © 2017 Elsevier B.V  

Since oil reservoirs are limited and energy demand is increasing, seeking for high efficient EOR processes or enhancing the efficiency of current proposed EOR methods for producing trapped oil from reservoirs are highly investigated. As a way out, it is possible to couple the EOR and nanotechnology to utilize the efficiency of both methods together. Regarding this possibility, in the present study, in the first stage of investigation stable and uniform water-based solution of nano-sized particles of copper oxide with different concentrations (0.01–0.05 M) were prepared and then injected into the core samples. In the first stage, the effects of different surfactants with respect to their... 

Three-dimensional reduced graphene oxide (3D-rGO) structures decorated with CuO particles (GCu) are synthesized through a simple and scalable method for detection of hydrogen sulfide (H2S) gas. For characterization and investigation of porous structure various techniques were employed. Decorated 3D structures demonstrated higher sensitivity and selectivity in comparison to pure structure. Optimized structure for sensing was obtained through introducing different amounts of CuO. The GCu heterostructures containing 35 μmol of CuO powder demonstrated reproducible response of about 30% to the concentration of 10 ppm at room temperature, while complete recovery was obtained through heating to 150... 

In this paper, CuO/CNT nanocomposite was synthesized and its photocatalytic dye degradation ability for colored textile wastewater was studied. The characteristics of the nanocomposite were investigated by XRD, SEM and FTIR. The photodegradation of Direct Red 31 (DR31) and Reactive Red 120 (RR120) by CuO/CNT in presence of H2O2 was investigated. Photocatalytic dye degradation was determined by UV-vis spectrophotometer. Effects of catalyst dosage, initial dye concentration and salt on photodegradation performance were studied. The photocatalytic dye degradation ability of pure CuO and CuO/CNT nanocomposite is 78 % and 89 % for DR31 and 70 % and 87 % for RR120, respectively. The results showed... 

A practical coplanar Josephson junction left-handed transmission line based on a step-edge junction technique is proposed in high-temperature superconductor technology and analyzed by electromagnetic simulations. The layout is designed for monolayer Yttrium Barium Copper Oxide thin film fabrication process. The propagation stopbands are tunable by controlling bias currents of Josephson junction arrays acting as parallel inductors for unit cells of the transmission line. Unlike the reported designs, each unit cell of our left-handed transmission line is independently biasable due to dc isolation of the unit cells along the transmission line. Being individually biasable is practically... 

Detectivity optimization of large-area freestanding-type YBCO superconducting bolometric detectors is theoretically and experimentally investigated. The effect of the device thermal parameters on the theoretical total noise-equivalent power based on background radiation, thermal fluctuation, and Johnson noise is considered. By analytical optimization of the total noise-equivalent power (NEP) of the device with respect to the thermal parameters and radiation modulation frequency, the maximum sensitivity and optimal thermal parameters of the bolometric detector are obtained. Relating device thermal parameters to the special case of the large substrate dimensions, the optimum device geometry is... 

Cu2O is an attractive material in terms of semiconducting properties and is considered a leading candidate in all-oxide photovoltaics. Electrochemical analysis of Cu2O, including Mott-Schottky (MS) and impedance spectroscopy (IS), provides a wealth of data on charge carriers, Fermi level and interface properties. MS and IS are usually measured in aqueous solutions. However, Cu2O is easily reduced or oxidized to Cu or CuO in aqueous solutions, the layer peels off after the analysis and there is a small voltage window for the tests. In some cases, an anti-corrosive n-type barrier layer is employed on top of the bare Cu2O electrode to make the measurement possible, which could result in... 

We have investigated the dependence of the optimal Non Destructive Evaluation (NDE) characterization on different excitation parameters in an eddy current SQUID NDE system for samples with known flaw depths. The considered parameters in our study include the configuration of the excitation-coil and its current frequency. The system is based on a High-YBCO gradiometer RF-SQUID sensor with a flux noise level below 100 μa I-y/Hz at 100 Hz in an unshielded environment, while being shielded against external rf EMI (Electromagnetic Interference). According to experimental results and the associated numerical analysis using Finite element (FEM) simulations, we have derived the optimized parameters... 

The phase formation and the variation of the normal phonon frequencies of high temperature superconductors YBa2Cu3O7-δ and GdBa2Cu3O7-δ upon doping Tb and Ce for Y and Gd, respectively, have been investigated using XRD and Raman spectroscopy measurements. It is found that the increase of doping content causes the formation of impurity phases that can be detected in the XRD and Raman spectra, and results in the suppression of superconductivity. Moreover, analysis of the Raman peaks reveals that substitutions of Tb and Ce for Y and Gd in the parent structure are restricted to low concentrations in favor of impurity island formation. © 2008  

We present an analytical thermal model to explain the crosstalk in YBCO edge-transition bolometer arrays. The verification of the model was tested on sample array devices made of 200 and 400 nm YBCO films on LaAlO3 and SrTiO3 substrates. The model presented was able to explain the effects of the various physical parameters of the devices, such as the film thickness, operating temperature, and the device separation, which cause different response behaviours based on the variation of the related thermal crosstalk characteristics. In addition, the model is valid above the crosstalk-free modulation frequencies, where the effects of the thermal crosstalk on the response of the devices are...