Sharif Digital Repository

Photocatalytic reduction of CO2 is considered as a promising strategy for production of a wide range of renewable hydrocarbon fuels by solar energy. In this investigation, a series of Ni and Bi doped TiO2 catalysts with different Ni and Bi contents were synthesized by the conventional sol-gel method and tested for CO2 photoreduction under visible light irradiation. Synthesized nano-photo-catalysts were characterized by XRD, FESEM, TEM, DRS, PL, FTIR and BET analyses. BET results indicated that the doping of Ni or/and Bi in the TiO2 framework resulted in BET specific surface area increment with respect to pure TiO2. DRS analysis showed that Ni doped TiO2, Bi doped TiO2, and co-doped samples... 

Pt@Bi-TiO2 photocatalysts with different Bi (0–5 wt%) and Pt (0–2 wt%) contents were prepared by a two-step sol-gel and photo-deposition technique and were used in photo-reduction of CO2. The synthesized catalysts were characterized by X-ray powder diffraction (XRD), UV–Vis diffuse reflectance spectroscopy (DRS), scanning and transmission electron microscopy (SEM and TEM), nitrogen sorption measurement (BET), Raman spectroscopy, Electron paramagnetic resonance (EPR) spectroscopy and photoluminescence spectroscopy (PL). CO2 photo-reduction results revealed that the introduction of Bi into TiO2 structure and subsequent loading of Pt on its surface significantly increased the methane yield....