Sharif Digital Repository

A series of novel pseudopeptides contained coumarin skeleton were synthesized through the Ugi-four-component reaction. The 3-substituted coumarin-3-carboxamides were formed through reaction of benzaldehyde derivatives, anilines, coumarin-3- carboxylic acid and isocyanides with high yields and high bond-forming efficiency at room temperature. These novel amidated coumarins exhibit brilliant fluorescence in range of 535-547 nm in chloroform  

In this paper, a new approach is presented for optimal control of large-scale chemical processes. In this approach, the chemical process is decomposed into smaller sub-systems at the first level, and a coordinator at the second level, for which a two-level hierarchical control strategy is designed. For this purpose, each sub-system in the first level can be solved separately, by using any conventional optimization algorithm. In the second level, the solutions obtained from the first level are coordinated using a new gradient-type strategy, which is updated by the error of the coordination vector. The proposed algorithm is used to solve the optimal control problem of a complex nonlinear... 

In this paper, an extended approach to the nonlinear DMC algorithm is proposed, which can handle constrained and MIMO systems under some defined conditions. This extension also admits higher control horizon, M and prediction horizon, P that are required to increase the performance of the controller in the most practical applications. Simulation results of the proposed method in the control of a stirred tank reactor with 2 inputs, 2 outputs nonlinear model and also a power unit nonlinear model with 3 inputs, 3 outputs are presented to illustrate effectiveness of the method and its justification. © 2005 Elsevier Ltd. All rights reserved  

A non-equilibrium simplex simulated annealing algorithm is applied as a global optimization method to parameter optimization for an equation of state based on the generalized statistical associating fluid theory incorporating potentials of variable range. The parameters are determined by optimizing the calculated phase behaviour of a number of pure solvents, such as water and alcohols, and aqueous electrolyte solutions. The optimized parameters obtained via the simulated annealing algorithm are compared to those obtained using the simplex method and, for the electrolyte solutions, a gradient-based quasi-Newton method. In the case of the pure solvents, the lowest values of the objective... 

Application of advanced process control methods in a chemical plant requires a model which represents the transient behaviour of the plant. However, only a few plant-wide identification methods have been proposed for chemical processes. In this paper, an objectoriented process identifier (OPI) framework has been introduced for plant-wide identification to show how using object-oriented design can provide a general plant-wide modelling framework for various systems including chemical processes. The interactions between units are considered in plant-wide identification methods. As a result, the obtained models can predict the system behaviour in new operating conditions better than those... 

Decentralized integral controllability (DIC) is an important property of industrial and process multivariable control systems. In this paper, some of the previously proposed conditions for the study of the DIC of certain systems are extended to treat systems with correlated and independent uncertainty. These conditions are based on the concept of the stability of Polytopic and Interval family of matrices, and evaluation of the Lyapunov condition only at special vertices of these families. By comparison with previous sufficient conditions, and known necessary conditions, it is demonstrated that the newly proposed criteria are significantly less conservative, especially in the case of... 

Supersonic separators (3Ss) are applied in gas separation processes. Two-dimensional simulation is employed to investigate the effect of operational and thermophysical parameters on the shockwave position. In addition, the impact of the cyclonic part and wet outlet geometry is evaluated by proposing four cases. Increasing the length of the cyclonic part exerts positive and negative influences on the performance of the 3S and the pressure recovery coefficient, respectively. The optimum length is determined between 10 and 15 cm. To demonstrate negative effects of wasted air from the wet outlet, its flow has been increased from 3.6 to 8.1 % of the inlet flow. Improved performance of the 3S is... 

Magnetite nanoparticles with an average particle size of 28.8 nm were synthesized, coated with oleic acid, and characterized using various techniques such as DLS, FT-IR, SEM, XRD, VSM, and UV-Vis analysis. A nanofluid consisting of synthesized nanoparticles and 5 wt % acetic acid in toluene as the dispersed phase was prepared and used in the chemical test system, Toluene-Acetic Acid-Water, for the single drop extraction in the presence and absence of an external oscillating magnetic field. Influences of various operating and design parameters such as nanoparticle concentration, drop diameter, and the applied current and frequency on the overall mass-transfer coefficients for the... 

The light scattering and harvesting effects in dye-sensitized solar cells (DSSCs) is studied by controlling morphology, phase composition, and thickness of monolayer and double-layer TiO2 photoanode electrodes. The starting materials for preparation of TiO2 cells, including 25 nm mesoporous anatase nanoparticles, 200 nm anatase microspheres, 10 µm dandelion-like rutile particles and 40 nm nanoparticles containing 80% anatase-20% rutile, are synthesized by evaporation-induced self-assembly, sol-gel, and hydrothermal processes. It was found that the mesoporous anatase nanoparticles may improve light harvesting and dye-sensitization due to their high surface area and small particle size,... 

Exergy and exergoeconomic analyses have been used to set out weaknesses of the postcombustion CO2 capture unit of Besat power plant that uses an ammonia absorption refrigeration system for CO2 liquefaction. The energy required for the absorption system is provided by the flue gas. The liquefied CO2 is used for beverage and food industries. The exergoeconomic costs of all utility streams and processes are calculated through a systematic method of assigning exergetic cost relations to the streams. The results point out that the exergy destruction of the CO2 stripper and absorber columns are the highest, and according to the cost-based information, potential locations for the process... 

Fuzzy sliding mode control (FSMC) as a robust and intelligent nonlinear control technique is proposed to control processes with severe nonlinearity and unknown models. The performance of the proposed method has been evaluated for both single input single output (SISO) and MIMO nonlinear systems through its application in three severely nonlinear processes that are frequently used as benchmarks of nonlinear process control strategies. The evaluation shows that, despite its lack of dependence on the process model, the proposed method performs almost the same as conventional sliding mode control alternatives that utilize all the information that exists in the mathematical model of the process.... 

One of the main issues of wastewater treatment is the silica deposition in steam turbines. Evaporation of silica with the steam in adequate concentration is one of the main sources of scale formation in steam turbines. In this study, the authors introduce the utilization of a genetic-based approach—gene expression programming (GEP)—for solubility prognostication of the silica in superheated steam of boilers with respect to water silica content and pressure. The result of GEP mathematical approach is a new algebraic formula to achieve our goals. Developed model predicts the silica solubility in the range of 0.8–22.1 MPa and 1–500 mg/kg for pressure and boiler water silica content,... 

We outline a comprehensive numerical procedure for modeling of species transport and surface reaction kinetics in electrokinetically actuated microfluidic devices of rectangular cross section. Our results confirm the findings of previous simplified approaches that a concentration wave is created for sufficiently long microreactors. An analytical solution, developed for the wave propagation speed, shows that, when normalizing with the fluid mean velocity, it becomes a function of three parameters comprising the channel aspect ratio, the relative adsorption capacity, and the kinetic equilibrium constant. Our studies also reveal that the reactor geometry idealized as a slit, instead of a... 

Mass-transfer rates to and from drops in liquid-liquid extraction processes are often reduced by the presence of contaminants. To design an industrial extractor, it is essential to consider this contamination effect in a quantitative manner. To achieve this goal, an experimental investigation was conducted on the mass transfer into single drops for n-butanol-succinic acid-water, as the recommended test system by the European Federation of Chemical Engineering (EFCE). The effects of anionic (sodium dodecyl sulfate, SDS), cationic (dodecyl trimethyl ammonium chloride, DTMAC), and nonionic (octylphenol decaethylene glycol ether, Triton X-100) surfactants on the hydrodynamic and mass-transfer... 

In industrial liquid-liquid extraction processes, the feed is not clean liquid but there are various kinds of contaminants in the feed entering the extractors. In this regard, a two-impinging-jets contacting device (TIJCD) was tested through the standard test system recommended by the European Federation of Chemical Engineering (EFCE), namely toluene-acetone-water, in the presence and absence of various types of surface-active agents (SAAs). The influences of anionic, cationic, and nonionic SAAs such as sodium dodecyl sulfate (SDS), dodecyl trimethyl ammonium chloride (DTMAC), and octylphenol decaethylene glycol ether (Triton X-100), respectively, on the extraction efficiency and overall...