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catecholase-like-activity
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Synthesis, characterization, electrochemical studies and catecholase-like activity of dinuclear copper(II) complexes of a phenol-based compartmental ligand
, Article Journal of Coordination Chemistry ; Volume 60, Issue 21 , 2007 , Pages 2283-2295 ; 00958972 (ISSN) ; Gharagozlou, M ; Sayadi, M ; Sharif University of Technology
2007
Abstract
The new dinuclear copper(II) complexes, Cu(II)M(II) (M = Mn, Co, Ni, Cu), of a phenol-based compartmental ligand, having dissimilar N(amine)2O2 and N(imine)2O2 coordination sites have been synthesized. In this system there are two different compartments, one has piperazinyl nitrogens and phenolic oxygens and the other compartment has meso-stilbenediamine nitrogens and phenolic oxygens as coordinating sites. The complexes were characterized by elemental analysis, IR and electronic spectra as well as conductivity measurements. Dinuclear complexes were prepared through the CuIIPbII precursor complex by transmetalation of the Pb(II) for the M(II) ion. The electrochemistry and catecholase-like...