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carbon-nitride-nanorod
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Microwave Assisted Synthesis of Sno2 Nanoparticles from Sn Coated Cu Wire Scraps
, M.Sc. Thesis Sharif University of Technology ; Sadrnezhaad, Kh (Supervisor) ; Mohammadi, MohammadReza (Supervisor)
Abstract
Tin Oxide Nanoparticle (SnO2) with the band gap of around 3.6 eV is one of the promising materials in various fields such as photocatalysis water splitting, pollutant removal and also biotechnology. Inorder to use this material in a visible-light rang, some promotions should be conducted.By combining SnO2 nanoparticles with the non-metalic graphitic carbon nitride (g-C3N4), a proper nanocomposite with wide range of application can be obtained. But, in order to industrialize this material, the cost of the final product is an imperative issue to consider.Here we have introduced a novel and low-cost method for synthesis of g-C3N4/SnO2 nanocomposite by using urea as a precursor for g-C3N4 and...
Nanocarbon-based Nanocatalyst Design & Synthesis for Hydrogen Sulfide Removal from Gas Feed
, M.Sc. Thesis Sharif University of Technology ; Baghalha, Morteza (Supervisor) ; Eskandari, Mohammad Mehdi (Supervisor)
Abstract
well known metal-free nanostructure carbon-based catalyst, mesoporous graphitic carbon nitride, with diverse morphologies were synthesized by using ethylendiamine/carbontetrachloride as a precursor, SBA-15 and SBA-15 nanorod as hard templates. We have investigated morphology effect on the catalytic performance. The catalysts were characterized by means of low angle and wide angle XRD, BET, FT-IR, CHNOS, FE-SEM analysis. Because of high surface area, pore volume and high nitrogen content, which acts as lewis basic site, for the first time, carbon nitride is chosen for selective catalytic oxidation of hydrogen sulfide to sulfure. Reaction was taken place in a fixed-bed reactor and at...
Nanorod carbon nitride as a carbo catalyst for selective oxidation of hydrogen sulfide to sulfur
, Article Journal of Hazardous Materials ; Volume 364 , 2019 , Pages 218-226 ; 03043894 (ISSN) ; Eskandari, M. M ; Rashidi, A ; Baghalha, M ; Hassanisadi, M ; Hamzehlouyan, T ; Sharif University of Technology
Elsevier B.V
2019
Abstract
Two-dimensional mesoporous carbon nitride and its highly efficient nanorod framework were prepared via hard-templating method. The obtained materials were fully characterized. The results showed that the samples structural ordering and morphology were similar to those of the parent silica templates; they had large pore volumes as well as high surface area structures. Carbon nitride carbocatalysts were used for H2S selective oxidation. The catalytic tests were carried out at 190, 210 and 230 °C in a fixed bed reactor. The obtained selectivity values for mesoporous carbon nitride rod and mesoporous carbon nitride toward elemental sulfur at 190 °C were 88.8% and 83%, respectively. Both samples...