Sharif Digital Repository

Design and fabrication of highly efficient and low-cost oxygen reduction reaction (ORR) electrocatalysts is of paramount importance for practical applications. Herein, we proposed a cost-effective, metal-free catalyst based on ZIF-8 metal-organic framework nanoparticles/electro-polymerized poly(3,4-ethylenedioxythiophene) (PEDOT) film on the surface of flexible carbon cloth (CC) electrode (ZIF-8/PEDOT/CC) via a two-step procedure. For this purpose, worm-like PEDOT nanostructures were deposited on the surface of carbon fibers using a pulse electro-polymerization technique followed by facile growth of ZIF-8 polyhedra nanoparticles via a chemical bath deposition method. The ORR measurements in... 

Design and fabrication of highly efficient and low-cost oxygen reduction reaction (ORR) electrocatalysts is of paramount importance for practical applications. Herein, we proposed a cost-effective, metal-free catalyst based on ZIF-8 metal-organic framework nanoparticles/electro-polymerized poly(3,4-ethylenedioxythiophene) (PEDOT) film on the surface of flexible carbon cloth (CC) electrode (ZIF-8/PEDOT/CC) via a two-step procedure. For this purpose, worm-like PEDOT nanostructures were deposited on the surface of carbon fibers using a pulse electro-polymerization technique followed by facile growth of ZIF-8 polyhedra nanoparticles via a chemical bath deposition method. The ORR measurements in... 

Catalyst layers are one of the most important parts of the PEM fuel cells and the cell performance is highly related to its structure. Catalyst layers are generally made by uniform distribution of catalyst on carbon cloth or carbon papers to form electrodes. In this paper, the idea of using non-uniform catalyst layer instead of common uniform catalyst layers is presented and simulated by a two-dimensional steady-state computational model. The model accounts for species transport, electrochemical kinetics, charge transport and current density distribution. A fuel cell test stand is designed and built to facilitate experimental validation of the model. Modeling results show that electrical... 

Active edge sites of MoS2 nanosheets exhibit promising futures for hydrogen evolution reaction (HER), comparable with remarkable performances of highly cost platinum. However, 3D structures of MoS2 suffer from a lack of high mobility and unexposed active sites which lower the electrocatalytic activity. In this study, we show that there is a balance between increasing the active sites on the one hand and managing the charge transfer to facilitate the reaction on the other hand, and achieving this balance increases the efficiency of the electrocatalyst tremendously. For this purpose, we directly attached exfoliated MoS2 nanosheets onto carbon cloth (CC) substrate as a 3D network of conductive... 

Nonprecious and effective electrocatalyst development is an essential requirement for boosting water-splitting efficiency to obtain clean and sustainable fuels for future renewable energy demands. Herein, we reported an ultrafast and feasible strategy for constructing an S-doped bimetallic iron/nickel oxy(hydroxide) (S-(Fe/Ni)OOH) as a superior electrocatalyst for oxygen evolution reaction (OER). It is prepared by consequent electroplating of nickel nanocone arrays (NiNCAs) on carbon cloth (CC) and stainless-steel mesh (SSM) and then formation of S-(Fe/Ni)OOH layers on them by ultrafast one-step oxidation solution-phase method in the solution of Fe3+ and sodium thiosulfate at room... 

Active edge sites of MoS2 nanosheets exhibit promising futures for hydrogen evolution reaction (HER), comparable with remarkable performances of highly cost platinum. However, 3D structures of MoS2 suffer from a lack of high mobility and unexposed active sites which lower the electrocatalytic activity. In this study, we show that there is a balance between increasing the active sites on the one hand and managing the charge transfer to facilitate the reaction on the other hand, and achieving this balance increases the efficiency of the electrocatalyst tremendously. For this purpose, we directly attached exfoliated MoS2 nanosheets onto carbon cloth (CC) substrate as a 3D network of conductive...