Sharif Digital Repository

A kinetic model based on a mechanistic approach was developed for thermal hydrocracking of a paraffinic feedstock. The hydrocarbon feed was described as a mixture of representative molecules based on structural group analysis (SGA) where information from elemental analysis, H1, and C13-NMR of the feed were used to obtain the average concentration of various structural groups from which representative molecules were constructed. The behavior of the feedstock under reaction conditions was described in terms of the reaction of the individual molecules. The reaction of each of the representative molecules and the corresponding product distribution was based on free radical mechanisms. The... 

The biofluids being manipulated in lab-on-a-chip devices usually contain elastic macromolecules. Accordingly, for an accurate modeling of the relevant flow physics one should invoke viscoelastic constitutive equations. In this paper, attention is paid toward the hydrodynamic dispersion by the fully developed electroosmotic flow of PTT viscoelastic fluids in slit microchannels of low zeta potential. Adopting the Taylor–Aris approach, analytical solutions are derived for late-time solute concentration and effective dispersion coefficient. Finite element-based numerical simulations are also conducted to monitor the broadening of an analyte band from the moment of injection. Both approaches are... 

The present study compared different approaches to assessing the environmental cost-effectiveness of energy policy scenarios. As a case study, the megacity of Tehran in Iran was studied. A key policy challenge in this city is to curb high concentrations of PM2.5 and mitigate the associated adverse impacts. The results demonstrated that in the business as usual case, the spatially averaged primary and secondary PM2.5 concentration in Tehran will increase by 30% in the 2010–2030 period. Adopting certain planned policy scenarios and the corresponding pollutant concentration reductions in Tehran shows that although most of the emission comes from industrial activities around the city, the... 

The present study has been conducted to investigate the effect of inlet flow regimes on vertical velocity and concentration profiles of the turbidity current. Experiments carried out on small scale channel and Kaolin with a density of 2.65 kg/m3 and a mean particle diameter of 4.5 μm, was used to generate the currents. Velocities were obtained at a rate of 10 Hz using an acoustic Doppler velocimeter. Using the siphon sampling approach, the acoustic backscattering intensity was calibrated and concentration was determined using a backscattering analysis. Results showed that the ratio of maximum velocity height to the height of the current was around 0.4-0.5 in sub- and super-critical regimes.... 

This study investigates the effects of polymer concentration and solvent type on the pore size distribution (PSD) of the fabricated gas-liquid membrane contactors (MCs). Eighteen flat-sheet MCs are fabricated using polysulfone (PSf) and polyethersulfone (PES) polymers, with polymer concentration of 10%, 15%, and 20%. Dimethylformamide (DMF) and n-methyl-2-pyrrolidone (NMP) solvents are used to prepare the polymeric solutions. The role of polyvinylpyrrolidone (PVP) on the mean pore size of MCs is also studied. Scanning electron microscope (SEM) analysis is applied to visualize the pore system of the fabricated MCs. Image processing technique is used to obtain the PSD of the fabricated MCs...