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yousefalizadegan--fazile
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Synthesis, Characterization, Crystal Structure Determination and Theoretical Calculations of Some new Adducts of Cu (I) with Nitrogen-Donor and Phosphine Ligands
, M.Sc. Thesis Sharif University of Technology ; Kia, Reza (Supervisor)
Abstract
In the first part, two copper(I) complexes were synthesized as additive products of nitrogen-donor, phosphine and stibine ligands and copper(I) iodide, and in the second part, the triple-core copper(I) complex was synthesized with a phosphine ligand. The synthesized complexes were identified by FT-IR, 1H-NMR, 31P-NMR spectroscopy and the structure of these complexes was investigated using single crystal X-ray diffraction. In addition, the possibility of Cuprophilic interactions using structural parameters, And theoretical studies were reviewed. On the other hand, molecular structure determination allowed us to fully investigate the intramolecular and intermolecular interactions of the...