Sharif Digital Repository

In the present work, nanocrystalline Al-4wt%Cu alloy reinforced with nanometric Al2O3 particles was synthesized by in-situ reactive milling of Al and CuO powder mixture and hot extrusion. The effect of nanometric Al2O3 particles on the aging behavior and mechanical properties of this alloy was investigated. During mechanical milling, copper oxide were reduced and dissolved in the aluminum lattice. consequently, Al(Cu) solid solution matrix was produced. Also, nanometric Al2O3 particles were also distributed in the matrix uniformly. The powder blend was then pressed in an Al can at 100 MPa pressure and subsequently extruded at 450 0C at the extrusion ratio of 16:1. The density of the... 

Chronic wounds are among the serious injuries which have called the attention of scientists to invest in an effort to fabricate temporary skin grafts and wound dressing materials. One of the widely acceptable solutions to this obstacle is to design a bioactive scaffold capable of regenerating tissue as well as delivering active agents to the site specific area. To this end, natural biopolymers are considered as suitable candidates to be employed in regenerative medicine due to their excellent biocompatibility. In addition, nanoparticles possess special properties such as the ability in sequestering the drug release which make them promising candidates in the fabrication of the... 

Implant-associated infections are one of the most serious complications in orthopaedic and trauma surgery as it may result in poor functional outcome, implant failure, chronic osteomyelitis or even death. Great concerns have been taken to reduce implant-associated infections through progressing in operating standards, minimizing the possibility of contamination during surgery, reducing the establishment of infection by perioperative antibiotic prophylaxis, and confining of pathogenic strains by patient isolation. In spite of these preventions, the percentage of postoperative infections is still rising. Composite coatings with bone-bioactivity and drug-eluting capacity are considered as... 

In recent years, temporary skin grafts based on natural biopolymers modified with carbon nanostructures has received considerable for wound healing applications. In this study, Nanofibrous structures that mimic the native extracellular matrix and promote cell adhesion have attracted considerable interest for biomedical applications. Chitosan-polyvinylpyrrolidone (CS/PVP) films containing graphene oxide (GO) nanosheets (~1 nm thickness and micrometer length) were prepared by solvent casting methods. Experimental results showed that PVP concentration had a critical role on the water vapor permeability, transparency, hydrophilicity and thermal stability of the nanocomposite films. Antibacterial... 

Quite a few methods have been reported to synthesize monolayer MoS2, which has recently attracted scientist attentions. Fully controlled conditions, however, have not been achieved in these methods. In this research, two-dimensional MoS2 nanofilms have been synthesized by Chemical Vaper Deposition (CVD). Layer thickness of synthesized layer and effects of various parameters of used method have been investigated. Although every scientist synthesizes 2D MoS2 at 650°C in the CVD method by using seeds, in this research, it has been proved that MoS2 nanofilms can be produced at 575°C without using any seeds, which leads to lower consumption of time and price and increases the quality of... 

In recent years, much attention has been focused on quantum dot films due to their high amount of surface area and their size-dependant band-gap tenability. However, high surface area results in increase in energy traps in case of insufficient surface passivation. In this research, PbS colloidal quantum dots were synthesized via hot injection route having the size of 3 nm approximately. Then cationic doping with Zn, Ca and Cd and ligand exchange of long oleic acid with short organic mercaptopionic acid were done. Excitonic peak of these dots and photoluminescence peak appeard in wavelengths of 930 and 1100 nm respectively. Optimum film thickness was also determined as 300 nm. Quantum dot... 

Graphene based photodetectors which are modified with quantum dots, are the new generation of detectors. In these supplies an integration of graphene’s unique characteristics like high conductivity and mobility and the high light absorption of quantum dots, are used.In this research graphene by chemical vapor deposition in centimetric large scales, tungsten disulfide quantum dots, boron nitride and graphene quantum dots and 2D tungsten disulfide have been synthesized. In the next step each of them were characterized to modify the quality of used layers in heterostructure.Based on the characteristic tests, quantum dots aspect ratios were 1 to 5 nanometers. Also tungsten disulfide was obtained... 

Hot deformation behavior of Al-SiC nanocomposites was investigated in this study. Aluminum powders with mean size of 60 micron and SiC nanopowders (mean size of 45nm) in amounts of 1 and 2 volume percents, as reinforced part, were mixed and milled for 40 hours by planetary ball mill. After degassing at 450 oC for 1 hour, milled powders were pressed into Aluminum cans (in Argon atmosphere) and then hot extruded. Extrusion ratio was 1:14. High density billets (with 98% of theoretical density) were produced because of that high extrusion ratio. TEM microstructure studies showed that fine distribution of reinforcements and Aluminum Oxides obtained via this procedure. Hardness and Uniaxial... 

In this study, Al6063-Al203 nanocomposite powders were synthesized by reaction mechanical milling method. Nanometric reinforcement particles were formed via high- energy ball milling under a controlled oxygen containing atmosphere. Morphological and microstructural evolutions of nanocomposite powders were investigated by using X-ray diffraction (XRD), thermal analysis (DTA), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) methods at different milling times. The results showed that mechanical milling stages were accelerated and the time for reaching steady- state condition was decreased by an increase in the oxygen content in the milling atmosphere. The in-situ... 

Graphene is a newly developed nanomaterial that has resived considerable attention in recent years. Graphene – based structures having remarkable properties, e.g. high specific surface area, ultrahigh electrical conductivity and good biocompability, are ideal choices for nanomedical applications such as biosensors and cell culture scaffolds. So, in this project 2D graphene and 3D graphene foam structures were synthesized by chemical vapor deposition (CVD) method and their electrical and biological properties were evaluated. First step of this project was to design and make a CVD system suitable for the synthesis of high quality graphene structures, i.e. single layer graphene and 3D graphene... 

In recent years utilization of quantum dots for stem cells detection and clean energy production has received intensive attention. Graphene and its derivatives have been widely studied because of their effectiveness on electronical and optoelectronical devices, chemical sensors, nanocomposites, and energy storage. By use of metal nanoparticles, such as AuNPs, we can develop properties of graphene, and control them via shifting the absorption peak wavelength and increasing its biocompatibility. In this research, hybrid nanoparticles of gold-graphene as core-shell and conjugated by polymeric linkers containing amine or thiol functions are synthesized. Our purpose is stabilization the... 

Transition Metal Dichalcogenids (TMD) are types of 2D materials that exibit wide range of electronic, optical, mechanical, chemical, and thermal properties. These materials with MX2 general formula, have atract attentions with respect to their unusual properties because of their very limited dimensions. Their tunable properties and materials availibility make them attractive for wide range of applications. In recent years, chemical vapor deposition (CVD) methods are promising in preparing high quality TMD with scalable size, controllable thickness, and very excellent electronic properties. Also, chalenges are remaining in synthesis and transfering of TMD are difficulty for most of... 

Electrochemical sensing of glucose has received paramount attention in recent years, particularly, the non-enzymatic glucose sensing is one of the trends in the whole biosensing world. In this research, synthesis and evaluation of a hybrid structure of vertical oriented nickel nanorod-reduced graphene oxide sheets as a non-enzymatic glucose sensor were performed. The 3D array of nickel nanorods was synthesized by electrodeposition of nickel sulfate electrolyte in track-etched polycarbonate template with 100 nm pore size and 6-10 μm thickness. The electrodeposition performed in various conditions, and the best result was achieved by application of potential of 3 V for 60 minutes. The shiny... 

Boron Nitride Quantum Dots, as a new member of Heavy-metal-free Quantum dots has attracted many attention due to their unique properties. The hyroxylate functionalized BNQDs was synthesized with two steps fabrication approache which were contained mechanical milling and solvothermal process. It has been shown that 12 hours for mechanical milling and 24 hours for solvothermal process would be the most optimum time that produce well disperse functionalized BNQDs . The characterization results have proved that the as-prepared BNQDs have lateral size at around 5 nm with thickness in range of 4-6 layers. Also, it has been demonstrated that OH functional groups can attache into the surface of... 

The variety of 2D materials and their wide range of properties, as well as numerous methods to manipulate them, have made this class of materials among prominent candidates for the future of the energy industry. Among the means available to tailor nanomaterials performance for such applications, introducing dopants and the creation of heteroatom-doped structures are of great interest. In this study, mixtures of urea, boric acid, and graphene oxide, as cheap and available precursors, were used to synthesize C-doped h-BN nanosheets. After the implementation of TGA/DSC to select a suitable calcination temperature of 950 C°, the samples were successfully synthesized with relatively precise... 

In recent years, quantum dots specially NIR QDs like lead sulfide have attracted a lot of attentions in various bioapplications such as bioimaging, stem cell tracking, etc. However, these materials are generally synthesized by using organic lagands like oleic acid which is not appropriate for bioapplications. Moreover, the cytotoxicity of these materials have severely restricted their applications. In this research, lead sulfide quantum dots were synthesized via a hot injection route. The nanocrystals had an average size of 3 nm passivated with oleic acid ligands and graphene nanosheets. Excitonic and photoluminescence peaks were observed in wavelengths of 950 and 1100 nm, respectively.... 

Nowadays, storing solar renewable energy in hydrogen (as a clean fuel) is an attractive method for substitution of environmentally pollutant energy resources (fossil fuels) which is applicable through water splitting with the use of semiconductors. Among metal oxide photoanodes, WO3 as a moderate band gap semiconductor with high photo-stability, environmental compatibility, and low cost has attracted significant attention. However, photoelectron conversion efficiency of WO3 is still limited due to poor oxygen evolution reaction kinetics and charge carrier recombination. Herein, two strategies of nanostructuring and compositing with cocatalysts were applied to envisage with these limitations.... 

In this work, encapsulating cesium-based perovskite quantum dots (PQDs) in zeolitic imidazolate framework-8 (ZIF-8) was investigated in order to enhance their environmental, water and thermal stabilities. It was shown that physical mixing of pre-synthesized PQDs and nanocrystalline ZIF-8 (structure-I) does not have any influence on stability enhancement. In second structure, nanocrystals of perovskite were crystalized in ZIF-8 pores. These nanostructures kept 50% of their initial photoluminescence after 24 hours maintenance in water. In third structure, both perovskite nanoparticles and ZIF-8 structures were crystalized simultaneously which resulted in more efficient encapsulation and kept... 

Enhancing the detection range, sensitivity and stability of phototdetectors due to their vast applications are in great importance. In recent years, Lead sulfide quantum dots, in order to their absorption over a wide range of wavelengths including Near-infrared (NIR), multiple exciton generation effect and solution processability are promising materials.However, long organic surface ligands which are necessary in synthesis process can suppress the carrie transport and the common method to overcome this weakness, is ligand exchange process. In this way, using short organic ligands because of their low electron mobility and methylammonium lead iodide ligands in order to their instability,... 

Energy conversion and storage as well as life sciences are among the areas of our daily life. Interest in carbon nanomaterials for energy storage systems such as supercapacitors has enormously risen due to their attractive electrical conductivity, chemical inertness, and charge storage capacity. Producing these nanomaterials with a simple, scalable, and cost-effective method is the major problem for commercializing them. The reduction of graphitic oxide is a versatile procedure to prepare 3D graphene. Despite many green methods, the dynamics behind ultrafast thermal graphitization have remained elusive. Here, we demonstrate an effort to understand the graphitization mechanism of graphitic...