Sharif Digital Repository

Today, base lead piezoelectrics are the center of attention due to their very good electrical properties, and low cost of production. Among these ceramics are PZT which is a combination of Pb(ZrxTi1-x)O3 and PCN which is a combination of Pb(CoxNb1-x)O3. PZT is a normal piezoelectric whose dielectric properties would be improved if relaxor is added. PCN is ferroelectric with perovskite structure and curie temperature -27℃ which is known as a relaxor with high constant dielectric properties. In this research, adding PCN to PZT was done by sol-gel seeding method. Calcination at a temperature of 900℃ was causing the creation of single-phase perovskite powder. After that, conventional sintering... 

The aim of this study is to investigate the effect of Copper oxide on the microstructure, properties, and grain growth kinetic in Tin oxide- Based varistors. Copper oxide was mixed in Tin oxide with different concentration, including 0, 0.1, 0.25, 0.5, and 1 mol% and the samples were sintered at 1250, 1300, and 1350 oC. Then, phase and microstructural characterization was investigated and consequently, electrical properties were evaluated. According to results, Copper Oxide with forming the liquid phase through the sintering process, accelerated grain growth. It was found that, by increasing concentration of CuO, mean grain size was increased from 2.6 µm in 1250 oC and 5 hours to 17.1 µm... 

In this research, the surface of multi-walled carbon nanotubes (CNTs), as template, were coated by Lead zirconate titanate (PZT) with composition of Pb(Zr0.52Ti0.48)O3 via sol-gel process. The final product is called PZT-CNT hybrid material. For functionalizing of CNTs, benzyl alcohol was used. Simultaneous thermal analysis (STA) proved that the as-derived amorphous material crystallized at 520 ˚C. Scanning Electron Microscope (SEM) images verified the deposition of a uniform coating of PZT on the surface of CNTs and proved that the functionalizing treatment was done successfully. X-ray diffraction (XRD) showed that the crystal structure of the hybrid was tetragonal perovskite.... 

Last generation of solar cells which are organo-metal halide perovskite solar cells (PSCs) with power conversion efficiency over 20% are increasingly comparable to the silicon types, these PSCs are poorly stable under working environment. Carbon-based PSCs with lower cost and more stability seem a better choice for commercialization in future. In these PSCs TiO2 and NiO are working as electron and hole transporting materials, respectively. In addition, ZrO2 film between two mentioned layers works as a buffer layer to prevent direct contact. In this thesis, the initial powder, necessary for fabricating the buffer layer is synthesized at the first place. Then, since the printing method is a... 

The goal of this project is production of composite laminated sheetswith bimodal microstructure using ARB process. It is planned to produce a laminated sheet having bimodal grain size distribution in microstructure to increase the formability while maintaining the strength. Two different aluminum alloys including AA 1050 and AA5083 were ARB processed up to 9 cycles, Then the ARB samples were annealed under controlled temperatures and times. Due to structural differences like stacking fault energy,stored cold work energy and solute atoms concentration, annealing ofThese two alloys lead to different recrystallized grain sizes. In order to evaluate the recovery and recrystallization behavior of... 

Polycarbonate (PC) is known as one of the engineering plastics with remarkable mechanical properties, but the application of this polymer is limited due to its high notch sensitivity. Blending polycarbonate with other polymers such as acrylonitrile butadiene styrene (ABS) is a method to resolve this disadvantage. PC/ABS blends are commonly used in automotive industry, electrical and electronic devices. As PC and ABS are not completely miscible, a variety of compatibilizers are used to achieve a suitable microstructure and high engineering properties. Considering crucial applications of PC/ABS blends, different flame retardants are also used to reduce the flammability. These flame retardants... 

Recently, Polypropylene has been extensively used in a variety of applications in the polymer industry, but its quite low stiffness and toughness limit this polyolefin’s application in the engineering functions; thus, the market of polymer blend and composite manufacturing has grown noticeably in the last few years. In the current project, short Flax fibers are used in order to reinforce the PP matrix. Firstly, Flax fibers were washed with the gentle and harsh condition during the alkalization process, then the optimized alkalization condition was determined through comparison of results from X-ray Diffraction (XRD ), Attenuated Total Reflectance FTIR (ATR-FTIR) and microscopic surface... 

Nowadays, the development of different polymer blend nanocomposites is of great importance for achieving electrical and antistatic properties for various applications such as auto parts and the packaging industry. Immiscible polymer blends with conductive nanoparticles such as carbon nanotube, graphene, etc. can reach the conductivity threshold with low amounts of nanoparticles and produce desired electrical properties. In the present study, we have attempted to develop a polystyrene(PS)/ethylene-octene copolymer(EOC)/carbon nanotube(CNT) blend nanocomposite with suitable electrical conductivity. The compounding was performed by melt mixing at two weight percent of 80/20 and 50/50 (PS/EOC)... 

Particulate ceramic reinforced aluminum matrix composites have high specific strength and stiffness; however, low fracture toughness and deformability have restricted their industrial applications. Among the methods introduced to overcome this shortcoming is fabricating the layered composites which contain alternative layers of aluminum (Al) and discontinuously reinforced aluminum (DRA). In this study, two different routes; i.e., "Powder extrusion - Casting - Rolling" and "Powder extrusion - Roll bonding" were employed to produce layered Al-DRA composites. After production of Al6061/SiCp composites via hot powder extrusion, mentioned processes were utilized to make DRA-Al-DRA laminate. In... 

In this research, friction and wear behaviors of 2024 Al and 2024 Al-20 vol.% SiC composite -prepared by powder metallurgy method- were investigated in the temperature range 20- 250°C. Dry sliding wear tests were conducted at a constant sliding velocity of 0.5 m/s, an applied load of 20 N, and a sliding distance of 2500m using a pin-on-disc apparatus. Some of the wear tests were carried out with artificially aged specimens in order to determine the aging effects. Worn surfaces and wear debris were also examined by using SEM, EDS and XRD techniques. All specimens showed a transition from mild to severe wear above a critical temperature. In the mild wear regime, the wear rate and the friction... 

Composites are made to obtain several mechanical and physical properties selectively. But joining and manufacturing of complex shapes restricts their usages. Transient liquid phase (TLP) bonding is a novel method for joining of these materials without any defects that occur in other welding methods, such as melting or solid state methods. In this research, temperture gradiant TLP bonding of AA6061/SiC/15p using gallium as interlayer was performed. To obtain the optimum conditions, joining was performed at 260, 310, 360 and 410 ˚C, and pressure of 5 and 10 Mpa with holding time of 5 and 10 minutes, the joined samples then solutionized at 530˚C for 70 minutes. Optical and scanning electron... 

In the present research, transient liquid phase bonding of dissimilar st52 low carbon manganese steel to 304 stainless steel by pure Cu foil, in induction furnace and SIC furnace, was investigated. Samples were bonded in induction and SIC furnace at 1150 0C for different bonding times. Samples were then cut transversely and cross section of samples was examined by optical and scanning electron microscope. Complete isothermal solidification time was more than 9 hours and 90 minutes for SIC and induction furnace, respectively. Micro hardness and shear strength tests were done on samples bonded in optimum condition. Shear strength of none homogenized samples which had been bonded in SIC... 

TLP diffusion bonding method refers to a method in which two metal pieces can be bonded by putting an interlayer between two pieces and heating to a temperature lower than base metal melting point. Theoretically, this process shows that the bonding line disappears completely at the end of the process and it is not possible to recognize it. However, these assumptions were not accomplished in practice. Therefore, various parameters such as material of interlayer, thickness of interlayer, temperature and time of bonding, temperature and time of homogenizing and applied pressure on metal pieces should be controlled to achieve the best shearing strength results. Aluminum based composites have... 

As contrast enhancement agent, two different structures of superparamagnetic nanoparticles were synthesized. Iron oxide nanoparticles were prepared through an alkaline coprecipitation method of Iron (II) and (III) ions. PEG-6000 was used as biocapping material and its effect on particle size, colloidal stability and cytotoxicity was evaluated. On the other hand, novel core/shell structures were produced by NaBH4 reduction process of iron (III) in an aqueous media following by further oxidation by two different methods using (CH3)3NO oxygen transferring agent and exposure to oxygen flow. In both cases, structural examinations were conducted via X-ray diffraction, electron microscopy and... 

Many efforts have been put into increasing the efficiency of dye-sensitized solar cells that part of it has been devoted to structure and chemical composition of photoanode electrode. In this thesis, the effect of changes in the composition and its influence on light scattering ability in photoanode of dye sensitized solar cells was studied.First, the nanoparticles of titanium dioxide powder through solvothermal method as well as spherical particle and barium titanate powder by sol-gel method were synthesized. XRD and FE-SEM analyses indicated that synthesized powders are in good size and morphology regarding the intended chemical composition. Optical properties of TiO2 particles were... 

The microstructure, morphology and quality of the perovskite organic-inorganic layer as an absorber layer in perovskite solar cells has a significant role on the efficiency and energy conversion of the device. Different solvent engineering methods have been employed to prepare the perovskite layer with the desired properties and thier reproducibility have been studied. Herein, we applied a two-step solution approach by solvent engineering method, using solvents such as isopropyl alcohol, acetone and thier mixture, for preparation of lead iodide films. Moreover, their metallurgical and photovoltaic properties were investigated. The impact of solvent engineering, using solvents such as... 

In the present investigation, the mechanical alloying (MA) technique was employed to produce nanocrystalline Al-Ti Powder mixtures. Elemental Al and Ti powders were mixed with different compositions (0, 5, 10, and 20 wt.% Ti) and then, milled in a vibratory mill up to 7 hr. The variations of powder morphology and particle size, apparent and tap densities, microstructure, grain size, lattice strain, and microhardness were studied with increasing the milling time. While dissolution of Ti in the Al matrix resulted to the formation of supersaturated Al-Ti solid solution in the samples containing 5 and 10 wt.% Ti, the specimen with 20 wt.% Ti, eventually, led to nanocomposite powder with... 

The aim of this research was to fabricate an in-situ Al-Al3Ti nanocomposite from pure microsized aluminum and titanium powders by mechanical alloying and hot extrusion without any usage of nanometric particles or applying secondary heat treatments. The focus of the present research was fabricating a nanocomposite material with high strength, modulus and hardness accompanied with high fracture toughness that could be comparable with aluminum alloys in terms of fracture toughness. Mechanical alloying and hot extrusion techniques were employed to produce in-situ fully dense Al-Ti composites. Platenary and high energy vibratiory mill was used to produce composites with different percent of... 

The primary purpose of the present thesis is to understand the dynamic behavior of partially premixed flames of counterflow burners. In this project, work has been done on the previously designed and built counterflow burner. By setting up partially premixed flames in this burner, acoustic excitation of these flames has been done, and finally data acquisition by taking video of the flame and then using image processing to extract the dynamic response of these flames. The flames that we have examined in this project are all in a laminar regime and the fuel used in these flames is also natural gas. The frequencies that we have examined in these flames are 25 and 40 Hz, and these tests were... 

In the present work, the local Chemiluminescence method has been implemented on a laminar premixed propane-air flame. The goal of this work is to achieve a system capable of measuring the intensity of Chemiluminescent radiations of CH* and OH* radicals locally and with high spatial and temporal accuracy. For this purpose, a setup has been designed and developed. In order to achieve high spatial accuracy for local measurements, a Cassegrain lens has been designed and built, which has the ability to collect light from a cylindrical control volume with a cross-sectional diameter of 58 μm and a depth of 3.4 mm. An optical system for dividing and filtering light based on wavelength has also been...