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    Recovery of uranium from UCF liquid waste by anion exchange resin CG-400: Breakthrough curves, elution behavior and modeling studies

    , Article Annals of Nuclear Energy ; Volume 54 , April , 2013 , Pages 149-153 ; 03064549 (ISSN) Tavakoli, H ; Sepehrian, H ; Semnani, F ; Samadfam, M ; Sharif University of Technology
    2013
    Abstract
    Continuous fixed-bed column studies were carried out by using Amberlite CG-400 anion exchange resin for the recovery of uranium from aqueous solutions (synthetic solutions and uranium conversion facility (UCF) liquid waste). Effects of operating parameters such as flow rate and bed height were studied. The breakthrough capacity decreases with increasing flow rate, but this dependence was not significant with a long column. The maximum breakthrough capacity of uranium ions were achieved by CG-400 resin at a flow rate of 0.2 mL min-1 and bed height 9.1 cm (4 g resin). The elution behavior of uranium from CG-400 resin by various eluents have been investigated and the results show that 0.5 mol... 

    Uranium recovery from UCF liquid waste by nanoporous MCM-41: Breakthrough capacity and elution behavior studies

    , Article Research on Chemical Intermediates ; Volume 39, Issue 3 , 2013 , Pages 951-959 ; 09226168 (ISSN) Mousavi, S. M ; Tavakoli, H ; Samadfam, M ; Semnani, F ; Asadi, Z ; Sepehrian, H ; Sharif University of Technology
    2013
    Abstract
    Adsorption and recovery of uranium by nanoporous MCM-41 from aqueous solutions (synthetic solution and uranium conversion facility liquid waste) were investigated by use of a fixed-bed column (1.2 cm diameter and 3.0 cm height). Adsorption was carried out at flow rates 0.2 and 0.5 mL min-1, which correspond to retention times of 10 and 6 min. The maximum breakthrough capacity for uranium ions was achieved by use of nanoporous MCM-41 at the optimum pH of 3.6 and flow rate 0.2 mL min-1 (61.95 μg g-1). The Thomas and Yan models were applied to the experimental data, by use of linear regression, to determine the characteristics of the column for process design. The breakthrough curves calculated...