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    Synthesis of Alumina Support Modified with X and Y Zeolites as a Catalyst of Diesel Hydrodesulfurization Process

    , M.Sc. Thesis Sharif University of Technology Karami, Hamid (Author) ; Kazemeini, Mohammad (Supervisor) ; Soltanali, Saeed (Supervisor) ; Rashidzadeh, Mehdi (Co-Supervisor)
    Abstract
    Environmental destructive effects of gases caused by combustion of sulfur compounds in the fuel, poisoning of catalysts, corrosion of equipment, as well as intensification of environmental considerations and new standards adopted for maximum sulfur content has made the desulfurization of fuels important; The desulfurization method using hydrogen has a high potential to remove sulfur. One of the major challenges in this process is to find the proper catalyst that has the best performance for this process. Ni (or Co) Mo (or W)/ γ-Al2O3 catalysts have high potential for using as a catalyst for the desulfurization process from a variety of large-scale or industrial hydrocarbon cuts. According to... 

    Manufacturing and Evaluation of Carbon Dioxide Hydrogenation Reaction Catalyst for Methanol Production

    , M.Sc. Thesis Sharif University of Technology Esmaeili, Mohammad (Author) ; Fotovat, Farzam (Supervisor) ; Zamaniyan, Akbar (Supervisor) ; Zamani, Yahya (Co-Supervisor) ; Rashidzadeh, Mehdi (Co-Supervisor)
    Abstract
    The hydrogenation of carbon dioxide to methanol represents a promising route for the efficient use of an anthropogenic greenhouse gas, in which catalysts play a key role in carbon dioxide conversion and methanol selectivity. In this study, firstly, CuO-ZnO-Al2O3, CuO-ZnO-ZrO2, CuO-ZnO-ZrO2-Al2O3, CuO-ZnO-Al2O3-CeO2 and CuO-ZnO-ZrO2-CeO2 catalysts were made using co-precipitation method, then these catalysts were characterized by inductively coupled plasma optical emission spectrometry, specific surface area and pore size distribution, X-ray diffraction, Field Emission Scanning Electron Microscopy, temperature programmed reduction. Finally, in order to compare the performance of the catalysts... 

    Washcoating and testing of monolithic palladium-only catalytic converters for automobiles

    , Article CHISA 2006 - 17th International Congress of Chemical and Process Engineering, Prague, 27 August 2006 through 31 August 2006 ; 2006 ; 8086059456 (ISBN); 9788086059457 (ISBN) Irani, M ; Soltanieh, M ; Rashidzadeh, M ; Sharif University of Technology
    2006
    Abstract
    This article presents the research results on production and performance of palladium-only catalytic converters. Monolith is used as catalyst carrier and gamma alumina as substrate. Dipping method is used for monolith washcoating. Palladium as the active metal is impregnated on gamma alumina using wet impregnation to produce catalyst samples. The effects of factors such as percent solid in slurry, milling time, calcination time and temperature, pH and existence of Al(NO3)3 on wash-coat characteristics were studied experimentally. SEM, XRD, and BET tests were carried out on the samples. Catalyst performance was tested in an experimental reactor that was designed for this research. The results... 

    Synthesis and Evaluation of Alumina Nanocomposite Membranes for Gas Separation

    , M.Sc. Thesis Sharif University of Technology Farrokhnia, Mohammad Reza (Author) ; Safekordi, Aliakbar (Supervisor) ; Rashidzadeh, Mehdi (Supervisor) ; Khanbabaei, Ghader (Co-Advisor) ; Rahimpour, Mohammad Reza (Co-Advisor)
    Abstract
    Membrane processes are accounted as the newest technology for gas separation and nowadays are more applicable in different petroleum, gas and petrochemical industries because of abundant advantages. One of important application of membrane gas separation technology is syngas adjustment and hydrogen enrichment. In this research, the appropriate alumina nanocomposite membranes for this purpose are prepared and their gas separation performance is investigated. Therefore the mixed matrix membranes, containing the continues polymeric phase polyethersulfone and dispersed phase alumina nanoparticles is synthesized by using methods of experimental design. As the best of our knowledge, there is no... 

    The effect of acid treatment and calcination on the modification of zeolite X in diesel fuel hydrodesulphurization

    , Article Canadian Journal of Chemical Engineering ; Volume 100, Issue 11 , 2022 , Pages 3357-3366 ; 00084034 (ISSN) Karami, H ; Kazemeini, M ; Soltanali, S ; Rashidzadeh, M ; Sharif University of Technology
    John Wiley and Sons Inc  2022
    Abstract
    Faujasite (X, Y) zeolites are considered the main and important catalysts in hydrorefining processes. In order to obtain zeolites with higher acidity and volume of mesopores, post-synthesis modification, dealumination by different pickling techniques (using ethylenediamine tetraacetic acid [EDTA] chelating agent), and thermal treatment (calcination) were employed. The dealumination process led to the removal of the aluminum atoms from the zeolite structure and a rise in acidity while maintaining the zeolite crystalline lattice. X-ray diffraction (XRD), atomic absorption spectrometry (AAS), Fourier-transform infrared (FT-IR), field-emission scanning electron microscopy (FE-SEM),... 

    Influence of adding a modified zeolite-Y onto the NiMo/Al2O3 catalyst utilized to produce a diesel fuel with highly reduced sulfur content

    , Article Microporous and Mesoporous Materials ; Volume 332 , 2022 ; 13871811 (ISSN) Karami, H ; Kazemeini, M ; Soltanali, S ; Rashidzadeh, M ; Sharif University of Technology
    Elsevier B.V  2022
    Abstract
    In order to make a Na–Y zeolite with Si/Al ratio of 2.27 more acidic with a higher volume of mesopores, a combination of different and consecutive methods including; chemical (i.e.; utilizing different compounds, such as NH4F and EDTA) and thermal/hydrothermal (i.e.; implementing calcination/steaming) methods, were employed for modification and dealumination. The combination of acidic-hydrothermal dealumination method led to a further structural collapse compared to that of the acidic calcination. In comparison with the other dealumination methods, the fluorination strategy (i.e.; utilizing NH4F) resulted in a zeolite with higher crystallinity, acidity, and specific surface area. The... 

    Hydrogenation of crude terephthalic acid by supported Pd and Pd-Sn catalysts on functionalized multiwall carbon nanotubes

    , Article Chemical Engineering Research and Design ; Volume 109 , 2016 , Pages 41-52 ; 02638762 (ISSN) Tourani, S ; Safekordi, A. A ; Rashidzadeh, M ; Rashidi, A. M ; Khorasheh, F ; Sharif University of Technology
    Institution of Chemical Engineers  2016
    Abstract
    Liquid phase hydro-purification of crude terephthalic acid (CTA) was performed using supported Pd and Pd-Sn catalysts on functionalized multi-wall carbon nanotubes (FMWCNT). Pd/FMWCNT catalysts were prepared by wet impregnation with Pd loadings of 0.05 to 0.6 wt.%. Pd-Sn/FMWCNT catalysts were prepared by co-impregnation (CI) and successive impregnation (SI) using 0.3 wt.% Pd loading and Sn/Pd molar ratios of 0.1 and 0.35 for the CI method and 0.05 to 0.35 for the SI method. Pd loading of 0.3 wt.% for Pd/FMWCNT was sufficient to decrease the 4-carboxybenzaldehyde (4-CBA) content of CTA from 2100 ppm to 5.5 ppm without excessive hydrogenation of terephthalic acid (TA). The commercial catalyst... 

    Development of porous nanocomposite membranes for gas separation by identifying the effective fabrication parameters with Plackett–Burman experimental design

    , Article Journal of Porous Materials ; Volume 23, Issue 5 , 2016 , Pages 1279-1295 ; 13802224 (ISSN) Farrokhnia, M ; Safekordi, A ; Rashidzadeh, M ; Khanbabaei, G ; Akbari Anari, R ; Rahimpour, M ; Sharif University of Technology
    Springer New York LLC  2016
    Abstract
    In this research, Plackett–Burman experimental design was used as a screening method to investigate seven processing factors in the preparation of new polyethersulfone based porous nanocomposite membrane. Polymer concentration, nanoparticle type, nanoparticle concentration, solvent type, solution mixing time, evaporation time, and annealing temperature are variables that were evaluated to fabricate mixed matrix membranes using the evaporation phase inversion method for gas separation. According to obtained results, polymer concentration, nanoparticle concentration, solution mixing time, and evaporation time processing factors had significant effects on gas permeation. In addition, the... 

    , M.Sc. Thesis Sharif University of Technology Mardiha, Milad (Author) ; Vakilian, Mehdi (Supervisor) ; Fardmanesh, Mehdi (Supervisor)

    Design and Fabrication of Inductive High Temperature Superconducting Fault Current Limiter

    , Ph.D. Dissertation Sharif University of Technology Hekmati, Arsalan (Author) ; Vakilian, Mehdi (Supervisor) ; Fardmanesh, Mehdi (Supervisor)
    Abstract
    The continuous rise in electricity demand and the ever growing power generation in different power networks over the world have caused the short circuit level in the power systems to exceed the operational rating of the installed power devices (including cables, circuit breakers and buses). Replacing these devices with new higher rating devices is an expensive solution. From this point of view, utilizing fault current limiters is an economical solution. Superconducting fault current limiters form an efficient category of current limiters. This type is expected to be studied and used widely in future due to their advantages. In this thesis, the first chapter reviews the superconductivity... 

    Enhancement of THz Radiation from Josephson Junctions in Superconductors Using Electromagnetic Resonators

    , M.Sc. Thesis Sharif University of Technology Iranmehr, Masoud (Author) ; Ahmadi Boroujeni, Mehdi (Supervisor) ; Fardmanesh, Mehdi (Supervisor)
    Abstract
    Terahertz waves which includes frequencies between 100 GHz to 10 THz of electromagnetic spectrum have found many applications in science, medical treatments and industry. One of the recent methods to produce these waves is using nonlinear properties of superconductors based on Josephson junctions which inherently appear in some superconductors called BSCCO. Stack of intrinsic junctions of these superconducting materials can radiate terahertz waves by only applying a DC voltage across them. This Thesis investigates some of these structures based on Josephson junctions to produce coherent radiation of terahertz waves. For the optimization of the radiation power, this study also investigates... 

    On the Spectrum of Modified Theories of Gravity

    , M.Sc. Thesis Sharif University of Technology Seraj, Ali (Author) ; Golshani, Mehdi (Supervisor) ; Sheikh Jabbari, Mohammad Mehdi (Supervisor)
    Abstract
    There are different approaches in modifications of General Relativity as the theory of gravity. The modified theories of gravity are important cases in this context, which mostly start by modifying the Einstein-Hilbert action, while keeping the general covariance. Within the modified theories of gravity, we consider two cases. The first is the f(R) theories of gravity, and the second is curvature squared theories of gravity with an action like S = ∫d4x pg( 116GR + (R)2 + R2 +(R)2). Curvature squared theories of gravity have interesting feautures, most important of which is renormalizability, in contrast with General Relativity. But this advantage, as noted by K.S. Stelle in 1977 comes at... 

    On Thermodynamics and Phase Space of Near Horizon Extremal Geometries

    , Ph.D. Dissertation Sharif University of Technology Hajian, Kamal (Author) ; Sheikh-Jabbari, Mohammad Mehdi (Supervisor) ; Golshani, Mehdi (Co-Advisor)
    Abstract
    Near Horizon Extremal Geometries (NHEG), are geometries which may appear in the near horizon region of the extremal black holes. These geometries have SL(2;R)U(1)n isometry, and constitute a family of solutions to the theory under consideration. In the first part of this report,their thermodynamic properties are reviewed, and their three universal laws are derived. In addition, at the end of the first part, the role of these laws in black hole thermodynamics is presented. In the second part of this thesis, we review building their classical phase space in the Einstein-Hilbert theory. The elements in the NHEG phase space manifold are built by appropriately chosen coordinate transformations of... 

    Optimal Multicriteria Design of HTS Transformer and Construction of a Laboratory Scale Sample

    , Ph.D. Dissertation Sharif University of Technology Moradnouri, Ahmad (Author) ; Vakilian, Mehdi (Supervisor) ; Fardmanesh, Mehdi (Co-Supervisor) ; Hekmati, Arsalan (Co-Supervisor)
    Abstract
    Employing high-temperature superconducting (HTS) tapes, instead of copper or aluminum wires for winding in a superconducting transformer, results in a series of significant advantages; such as: smaller volume, lighter weight, higher efficieny, greatly extended overload capability, better voltage regulation, lower life cycle cost, fault current limiting capability, lower environmental pollution and lower risk potential against fire hazards.In this thesis, optimal design of flux diverter using genetic algorithm for axial short circuit force reduction in HTS transformers has been performed. Then, multilayered flux diverters have been proposed for reduction of weight and losses. The impact of... 

    Critique and Survey of Various Formulation of Multiverse Theory

    , Ph.D. Dissertation Sharif University of Technology Masoumi, Saeed (Author) ; Golshani, Mehdi (Supervisor) ; Sheikh Jabbari, Mohammad Mehdi (Supervisor)
    Abstract
    Multiverse scenario has been recently addressed by physicists and they have found it useful in many areas of physics. In this dissertation, I have treated some issues about multiverse such as the kinds of multiverses, the arguments for or against multiverse, areas in which multiverse is introduced, etc. This dissertation has six chapters and an appendix. In the chapter one, some classifications of multiverse is introduced, and also some definitions of the concept of a world is presented. Then, my classification and definition of a multiverse and a world is introduced. In the chapter two, the concept of possible worlds in philosophy and its relationship with multiverse hypothesis is examined.... 

    Monitoring of Valve Leakage in Internal Combustion Engine Using Acoustic Emission Method

    , Ph.D. Dissertation Sharif University of Technology Jafari, Mohammad (Author) ; Behzad, Mehdi (Supervisor) ; Mehdigholi, Hamid (Supervisor) ; Ahmadi, Mohammad Mehdi (Co-Advisor)
    Abstract
    Valve leak detection is very important due to bad direct effects on parts life and engine power. Acoustic emission (AE) has a good known ability on leak detection between fault detection methods. The aim of this thesis is presenting the ability of AE method for valve leak detection in internal combustion engines. The research method in a general framework based on the idea that firstly some evaluations were done in static tests for leakage due to three faults including clearance, quasi-crack and notch. Then, the evaluations were continued with dynamic analysis of rotational speeds and different loads on the engine. Finally, the neural network approach was used to automatically detect all... 

    A Multi-Objective Robust Optimization Model for Logistics Planning in the Earthquake Response Phase [electronic resource]

    , Article Transportation Research Part E: Logistics and Transportation Review, Elsevier ; Volume 49, Issue 1, January 2013, , Pages 217–249 Najafi, M. (Mehdi) ; Eshghi, Kourosh ; Dullaert, Wout ; Sharif University of Technology
    Abstract
    Usually, resources are short in supply when earthquakes occur. In such emergency situations, disaster relief organizations must use these scarce resources efficiently to achieve the best possible emergency relief. This paper therefore proposes a multi-objective, multi-mode, multi-commodity, and multi-period stochastic model to manage the logistics of both commodities and injured people in the earthquake response. Also, a robust approach is developed and used to make sure that the distribution plan performs well under the various situations that can follow an earthquake. Afterwards, it proposes a solution methodology according to hierarchical objective functions and uses it to illustrate the... 

    Distributed Generation Planning in Deregulated Electric Industry Using Multi-objective Optimization

    , M.Sc. Thesis Sharif University of Technology Ahmadi, Mohammad (Author) ; Ehsan, Mehdi (Supervisor)

    Modeling of HV Substation Automation Systems and Evaluating of Operation Failure

    , M.Sc. Thesis Sharif University of Technology Falahati, Bamdad (Author) ; Vakilian, Mehdi (Supervisor)
    Abstract
    In two past decades, a revolution has occurred by emerging of substation automation system in field of substation control and protection system. The traditional control system has changed to the modern automation systems which are based on computer networks. The development of this project become possible by having experience in and being familiar with automation systems, studying equipment specifications, tasks, and criteria and analyzing operation of various systems. The main target of this thesis is evaluating the automation system precisely and exhaustively and developing a model based on mathematical relations. This model is founded based on the application and analysis of the networks.... 

    Relative Merits of the Two Famous Formulations of Bohmian Mechanics

    , Ph.D. Dissertation Sharif University of Technology Atiq, Mahdi (Author) ; Golshani, Mehdi (Supervisor)
    Abstract
    The goal of this thesis is to evaluate the strengths and weaknesses of the two existing formulations of Bohmian mechanics. The first one was proposed by Bohm, and emphasizes on the dynamics being second-order, and in which, the key tool for explaining the quantum phenomena is a non-classical potential, called "the quantum potential". In this approach, the postulates of de Broglie's "pilot-wave" theory, which now is known as Bohmian mechanics, are non-fundamental and are special to the atomic level. The possibility is proposed that these postulates become subjected to some modifications at the nuclear or lower levels, but no particular way for performing such modifications is suggested. The...