Sharif Digital Repository

In this thesis, functionalized Fe3O4 nanoparticles have been utilized as a support for immobilization of homogeneous catalysts. The catalytic activity of the supported heterogeneous nanocatalysts was investigated in hydrocarbon and sulfide oxidation reactions. In the first part of this research, imidazole functionalized Fe3O4 nanoparticles (Fe3O4@SiO2-Im) were used as a support to anchor manganese porphyrin complex, [MnT(4-OMeP)P]OAc; via axial ligation. Catalytic application of the immobilized manganese porphyrin was studied in oxidation of alkenes and sulfides. To find suitable reaction conditions, the effect of different parameters such as solvent and temperature on immobilization process... 

The process of implementing a damage detection strategy for aerospace, civil and mechanical engineering infrastructure is referred to as Structural Health Monitoring (SHM). Many portions of our technical infrastructure are approaching or exceeding their initial design life. As a result of economic issues, these civil, mechanical and aerospace structures are being used in spite of aging and the associated damage accumulation. Therefore, the ability to monitor the health of these structures is becoming increasingly important. In many cases, damage causes a structure that initially behaves in a predominantly linear manner to exhibit nonlinear response when subject to its operating environment.... 

The question of the time is one of the obscure and challenging subjects which has been discussed as a mysterious problem in various civilizations. In ancient Greece, the question has been debated among the supporters of existence and eternity. We observe the words of Plato, on the existence of the absolute essence of eternity against the change and transition time instantiated as a conducted river in the Heraclitus view. Other discussions focused on the relationship between the change and displacement, or the the spatial relations to which Aristotle paid attention. With the passing of time from the ancient and medieval eras to the Renaissance period, along with the growth of the science in... 

Free-Space Optical (FSO) communication has received an increasing attention in recent years with its ability to achieve ultra-high data rates (at the order of multiple gigabits per second) over unlicensed optical spectrum. A major degrading factor, particulary in long links is the stmospheric turbulence induced fading. In this thesis, we use spatial diversity and use and make several contributions to the performance analysis of MIMO (Mutli Input-Multi Output) FSO systems. We use MRC(Maximum Ratio Combining),EGC(Equal Gain Combinig),SC(Selection Combinig) and yield significant performance improvments. Finally we import the charectristic of different beamshapes and yields performance... 

In line with developments in the technology of integrated circuits, transistors are implemented in silicon. Although the price is reduced; design is more complicated, which causes the efficiency and power consumption to face some difficulties in such design. The reason why modern GDI-based circuit is the focus of attention is that in designing a digital circuit, less power is required while more efficiency is obtained. Lowering the complexity of the logic circuit can bring about reduction of power consumption and propagation delay and decrease the circuit space. GDI-based integrated circuits resemble MOSFET transistors but have fewer transistors and higher performance capability. This study...