Sharif Digital Repository

In this work we used the vacuum distillation residue from an Iranian heavy crude oil refinery in a solvent deasphalting (SDA) process using different temperatures (60-120°C), pressures (5-9 bar), solvents (n-pentane and ethyl acetate), and solvent to feed ratios (3 to 1, 5 to 1, and 7 to 1). The resulting products included deasphalted oil (DAO) and residue (PITCH). The DAO yields in SDA when n-pentane was used as solvent were significantly higher than those when ethyl acetate was used as solvent. The DAO was subsequently processed by thermal cracking at 500°C and atmospheric pressure to investigate the effect of solvent deasphalting processing conditions on the yield of coke and liquid... 

A family of Zn(II) complexes with naphthadiaza-crown macrocyclic host molecules (Ln = L1-L4) were prepared and characterized employing mass spectrometry, elemental microanalysis, 1H, 13C NMR, IR, UV–vis, fluorescence spectroscopy. The fluorescence study on [M(II)Ln]2+(M = Zn with n = 1–4, Hg with n = 5) complexes denoted on the presence of a notable selective supramolecular interaction with C60 in two different solvents, namely N-Methyl-2-pyrrolidone (NMP) and chloroform for both [Zn(II)L4]2+ and [Hg(II)L5]2+. Employing both UV–vis and fluorescence spectroscopy, 1:1 mol ratio were determined for [M(II)Ln]2+/C60 by applying the Job's plots. Comparing with their free ligands Ln interactions,... 

This study reports on the simulation of temperature distribution of human tooth under a laser beam based on non-Fourier models. The temperature in the tooth depth that directly results from the conduction heat transfer process is caused by the lengthy thermal relaxation time in the tooth layers. A detailed tooth composed of enamel, dentin, and pulp with unstructured shape, uneven boundaries, and realistic thicknesses was considered. A finite difference scheme was separately adopted to solve time-dependent equations in solid layers and soft tissue of the tooth. In this study, a dual-phase-lag non-Fourier heat conduction model was applied to evaluate temperature distribution induced by laser... 

In this study, a dental short pulse laser with a Gaussian beam profile was applied normally to the top surface of a mineral organ i.e. the human tooth for a root canal therapy. A numerical method of finite difference is adopted to solve the time-dependent heat transfer equation. The real boundary conditions of thermal insulation on the sharp segment of the root canal and periodic heat flux on the top boundary of the tooth were applied. The comparison of a three-phase-lag (TPL) bio-heat transfer model with other heat transfer studies has shown that this new bio-heat model (TPL) could accurately predict the thermal behaviour of a non-homogeneous structure such as the human tooth. It was... 

Drop formation in cross-junction micro-channels is numerically studied using the lattice Boltzmann method with pseudo-potential model. To verify the simulation, the results are compared to previous numerical and experimental data. Furthermore, the effects of capillary number, flow rate ratio, contact angle, and viscosity ratio on the flow patterns, drop length, and interval between drops are investigated and highlighted. The results show that the drop forming process has different regimes, namely, jetting, drop, and squeezing regimes. Also, it is shown that increasing in the flow rate ratio in the squeezing regime causes increment in drop length and decrement in drops interval distance. On...