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The primary challenge of spectroscopic techniques in selective detection and characterization of tautomeric structures of DNA and RNA bases, and moreover, the accurate interpretation and explanation of the experimental results are the main motives of theoretical studies. Surface-enhanced Raman spectroscopy (SERS) can be a powerful approach to distinguish cytosine in the presence of its tautomers. For this respect, herein, the theoretical simulation of the SERS spectra of cytosine and its three most stable tautomers adsorbed on silver clusters is carried out. The calculations of SERS spectra is based on the excited-state energy gradient approximation as a well-established approach that gives... 

This paper investigates the relation between information technology (IT) and the change of business operations. We evaluate the geographical demand of companies for customer service interactions. The structure is a separate selection model in which districts play the role of distinguished products. The approximated demand structure is used to evaluate the results of IT on customer size, place selection, and cost preserving. The results verify the higher cost vulnerability of IT-thorough companies but propose that capability to utilize cost different is highly company-specified and that the influence of geographically restricted externalities is even existent. Because the productivity of many...