Sharif Digital Repository

Vortex flow reactor (VFR) is used for biochemical reactions and separation applications. By using the second flow regime, called Taylor-Couette flow, VFR provides high amounts of mass transfer and mixing for biological components sensitive to shear stress. Mass transfer in a bench-scale Taylor-Couette contactor with a radius ratio, equal to 0.77 and an aspect ratio, equal to 30.7 was studied for solid particles dissolution. The working fluid was water and the suspended particles were benzoic acid. In this project the concentration of fluid phase was measured by injection of definite amount of the solid particles in to the contactor and sampling in different time intervals and the effects of... 

According to the growth in the world population and the decrease in fossil fuels resources and also according to the pollution caused by these unrenewable resources, using hydrogen as an alternative energy resource seems to be unavoidable. In the past decades, semi-conductor metal oxides were being used widely in the energy domain of study, due to their appropriate band gap in the ultra-violet and visible spectra. Among these metal oxides, ZnO has been under special attention because of its electron mobility and its reasonable production cost and also its friendliness to environment. But the high band gap of ZnO (3.2 eV) has impeded its use in visible light spectrum. In this project,... 

The sustainable development in societies and the global energy challenge requires usage of clean energy systems that have attracted the attention of many researchers in recent decades. One of the major challenges in generating renewable resources is the problem of energy storage and imbalance between supply and demand cycles. Hydrogen as one of the clean energy carriers and due to having the highest energy density in terms of weight, is one of the important research topics. From this point of view, the preparation of electrocatalysts for hydrogen production, based on available materials, via simple and environmentally friendly production methods, was considered in this research.... 

The core behaviour of a nuclear reactor might be fluctuated (deviations from the normal operating conditions) in operating conditions due to various reasons. Control rod vibrations and the alterations of coolant temperature and velocity could be the main reasons for the fluctuations. These fluctuations lead to neutronic flux noise and subsequently power noise. The main objective of the current thesis was to study the thermal-hydraulic noise of the PWRs in two-phase with the emphasis on VVER-1000, which is similar to the Bushehr-1 nuclear reactor. By considering the possibility of existing two-phase flow (maximum allowable quality is about 14%) in hot channel of the PWRs, thermal-hydraulic... 

Conventional solid phase microextraction fibers posses relatively low recommended operating temperature, instability and swelling in organic solvents, breakage of the fiber, stripping of coatings, and bending of the needle. Some of these problems have been obviated by covalent bonding of the polymer phase to the fused-silica substrate by sol-gel technology, but the easy breakage of the fiber still is a remaining challenge In this work, after successful fabrication of unbreakable SPME fibers based on 3-(trimethoxysilyl)propyl methacrylate precursor deposited on the surface of copper wire, the same approach was carried out to synthesis new sol-gel based SPME fibers. Three different coated... 

The aim of this paper is to perform macro stress test for one of Iran’s private banks using bank’s quarterly data from Q-4 1383 to Q-4 1389. To do this, the relation of bank’s default rate with macroeconomic indicators like house prices and the growth rate of value added of services; as macroeconomic risk factors; was investigated by a linear model. Results show that the bank’s default rate has a negative relation with both risk factors.Stress testing, using monte carlo simulation; shows that reverse shocks to both house prices and the growth rate of value added of services leads to severe increase in bank’s default rate; so that with decrease of both house prices to 4 million rials at... 

In this thesis, the improving effects of TiO2 nanotubes (TiO2NTs) fabricated by anodizing of titanium as suitable substrate for deposition active materiales in supercapacitors were considered. PANI/Pd/TiO2NTs electrodes with highly porous structures and good capacitive characteristics were prepared by electrodeposition of polyaniline on palladium nanoparticles loaded TiO2 nanotubes. The results illustrated that the specific capacitance of these electrodes was around 1060 Fg−1 in 1.0 M H2SO4 electrolyte as measured at a constant current of 2.0 Ag−1, whereas it was 210 Fg−1 for the PANI/TiO2NTs electrode. NiO-ZnO/TiO2NTs electrodes were synthesized by the electrodeposition of... 

Linear structure of polypropylene, which is a direct result of Ziegler-Natta catalysts, led to the melt strength of the polymer is low and it does not show hardness strain. This defect is cause to the use of polypropylene in some processes, such as thermoforming, making foam etc. are limited. A main methods to solve this defect are branching structure of the polymer. There are three general methods for this purpose, which are modified by chemical, electron beam irradiation and polymerization in the presence of metallocene catalyst. The first two methods that past processing, polypropylene branching using linear type is produced, while the third method branching occurs during polymerization.... 

It is a common method to use some proper materials such as honey, herbal fibers, and minerals for covering the wounds as an effective treatment. Nowadays biopolymers and new methods of nanofiber production to build a structure similar to the natural extracellular matrix (ECM) like electrospinning are used to reduce the time of restoration and prevent from the effects of wounds such as bedsores, diabetic ulcers, and severe burns. For effective design of a wound dressing, wound feature, recovery time, physical, mechanical, and biological properties should be considered in order to best as possible heal the bound. In this research, cellulose nanocrystals with average aspect ratio of 11.8 and... 

In cloud computing services, high availability is one of the most quality requirements that it is necessary to maintain customer confidence. This requires various fault tolerance mechanisms for coping with software and hardware failures.In this thesis, after reviewing previous research, eight different scenarios was designed for availability evaluation of redundant openstack private clouds, represented by RBDs and Markov chains, hierarchically assembled.Based on the availability and downtime results obtained from the scenarios and cost consideration of company, best architecture for openstack is implemented.For real world modeling, we tried to collect and analyze the hardware and... 

Bonding gravity with Quantum mechanics has always been a challenging issue. So that, accomplishing a theory of quantum gravity is one of the most important research topics in High-Energy Physics.Information paradox in black holes is among such issues which connect quantum mechanics with gravity. Black holes as a natural solution of Einstein equations have a distinction, with other solutions, since there exists an event horizon that imparts space-time into two causally disconnected regions.According to Hawking’s calculations, black holes would evaporate over time by the thermal radiation. This resulting thermal radiation has less information than the initial collapsed matter in a pure state....