Sharif Digital Repository

This paper investigates a new method of dissipating energy in which a rigid tube is driven into the deformable tube under axial compression. Since there is a specific clearance between the rigid and deformable tubes, the deformable tube is expanded during axial compression, and the impact energy is absorbed by plastic expansion of deformable tube and frictional energy between deformable and rigid tubes. Quasi-static axial compression tests with different values of friction coefficient between rigid and deformable tubes are performed. Theoretical formulation with consideration of strain hardening effect is presented to predict the mean crushing load. Theoretical and experimental studies show... 

In this study, an industrial acetylene hydrogenation unit is simulated utilizing three available kinetic models. The results are compared against six-day experimental data and the best model is selected. Effects of feed temperature and the amount of injected hydrogen on ethylene selectivity are also studied. According to the simulation results, the unit is not working under its optimum conditions. Furthermore, by reduction of the hydrogen flow rate to 52 kg/h, process selectivity is increased. In addition, a new approach is proposed to modify the hydrogenation process and reduce undesired by-products. In the simulation of the modified process, hydrogenation reactors temperature, hydrogen... 

Abstract In this study, Molecular Dynamics (MD) and Grand Canonical Monte Carlo (GCMC) simulations were conducted to investigate the diffusivity, solubility, and permeability of CO2, CO, H2, and H2O in a polyurethane membrane at three different temperatures. The characterization of the simulated structures was carried out using XRD, FFV, Tg and density calculation, and cavity size distribution. The obtained results were within the expectations reported data in the literature based on the experimental approach, indicating the authenticity of approached in this work. The results showed that the highest diffusivity and permeability coefficients were observed for... 

The influence of milling and subsequent annealing on nickel-ferrite phase formation was investigated by X-ray diffraction (XRD). Microstructure and magnetic properties of NiFe 2O 4 were determined by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and vibration sample magnetometry (VSM). Single phase nanosized nickel-ferrite was obtained by 30 h mechanical alloying (MA) and subsequent annealing at 600 °C for 1 h. Magnetic properties of the milled powder were extensively affected by the annealing temperature. Considerable growth of the particles and necking by sintering resulted from annealing at 1000 °C  

The Ugi reaction goes fast with high yields in a recyclable and biodegradable low-melting mixture of choline chloride and urea (DES) as a novel and efficient reaction medium. The DES is applicable to a wide range of aldehydes, amines, isocyanides, and acids in good to excellent isolated yields (60-92%) and short reaction times (2-5 h) and can be reused four times without any loss of activity  

A chemoselective synthesis of tetraketone and xanthene derivatives, by means of tandem Knoevenagel condensation and Michael addition in choline chloride-based deep eutectic solvents (DESs), is presented. The reaction of readily available aldehydes and active methylene compounds in malonic acid- and ZnCl2-based DES gives various xanthenes derivatives with good to excellent yields under mild reaction conditions. On the other hand, tetraketones were synthesized in almost quantitative yields by simple condensation of an aldehyde and active methylene compounds in milder deep eutectic solvents of urea and SnCl2. In addition, the reaction of other types of choline chloride-based DES leads to a... 

A novel approach is obtained during the fabrication of NiCoFe-B nanotube arrays via electroless method. Porous anodic aluminum oxide (AAO) templates fabricated by anodization of aluminum foil were sensitized using PdCl 2 solution and immersed into electroless plating baths at room temperature to produce nanotube arrays. Compositional and morphological properties of the nanotube arrays are characterized. Results indicates the formation of end-closed nanotubes with the dimension of 100-130 nm in outside diameter, which is determined by the pore size of the AAO template, and about 15 nm in thickness of tube walls. The possible formation mechanism of end-closed metallic nanotube arrays is... 

Properties of FeCo nanocrystalline intermetallic powders prepared by salt-matrix hydrogen reduction of a milled Fe 2O 3-Co 3O 4 mixture were investigated. The product of 72 ks ball-milling at 350 rpm was CoFe 2O 4 nanopowder. Reduction of this powder for 3.6 ks by hydrogen at 750 °C resulted in the formation of Fe 0.67Co 0.33 stoichiometric compound. Scanning electron microscopy, electron dispersive spectrometry, X-ray diffraction and vibrating sample magnetometry were used to characterize the nanopowder. Using a salt-matrix (NaCl as a dispersion medium) resulted in the decrease of the reduction temperature and improvement of the morphology and magnetic properties of the nanopowder.... 

Most recent findings on structural and magnetic properties of Fe-Ni-Co nano-powders produced by mechanical alloying and subsequent low-temperature hydrogen reduction are presented in this paper. At 300 rpm, with ball to powder weight ratio of 20, single phase nickel-cobalt ferrite is mechanically synthesized for 50 h. The as-milled powder is then subjected to 1 h hydrogen reduction at 700 °C. Hydrogen reduction results in the formation of Fe-16.5%Ni-16.5%Co nano-powders. The phases of the powders are identified by X-ray diffraction (XRD) utilizing Cu Kα radiation. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) are used to study the morphology and the average... 

Simulation optimization is an endeavor to determine the best combination of inputs that result in the best system performance criterion without evaluating all possible combinations. Since simulation optimization applies to many problems, it is extensively studied in the literature with different methods. However, most of these methods ignore the uncertainty of the systems’ parameters, which may lead to a solution that is not robustly optimal in reality. Motivated by this uncertainty, we propose a robust simulation optimization algorithm that follows the well-known Taguchi standpoint but replaces its statistical technique with a minimax method based on the kriging (Gaussian process)... 

Simulation optimization is an endeavor to determine the best combination of inputs that result in the best system performance criterion without evaluating all possible combinations. Since simulation optimization applies to many problems, it is extensively studied in the literature with different methods. However, most of these methods ignore the uncertainty of the systems’ parameters, which may lead to a solution that is not robustly optimal in reality. Motivated by this uncertainty, we propose a robust simulation optimization algorithm that follows the well-known Taguchi standpoint but replaces its statistical technique with a minimax method based on the kriging (Gaussian process)... 

Simulation optimization is an endeavor to determine the best combination of inputs that result in the best system performance criterion without evaluating all possible combinations. Since simulation optimization applies to many problems, it is extensively studied in the literature with different methods. However, most of these methods ignore the uncertainty of the systems’ parameters, which may lead to a solution that is not robustly optimal in reality. Motivated by this uncertainty, we propose a robust simulation optimization algorithm that follows the well-known Taguchi standpoint but replaces its statistical technique with a minimax method based on the kriging (Gaussian process)... 

Lithium perchlorate has been found to be an inexpensive and efficient catalyst for the ring opening of epoxides by indole and N-methylindole, which provides an environmentally friendly method for the synthesis of substituted indoles. A complete regioselectivity in favor of nucleophilic attack at the benzylic carbon atom of aromatic epoxides, such as styrene oxide, is observed. However, aliphatic unsymmetrical alkene oxides undergo selective nucleophilic attack at the sterically less-hindered carbon atom. This catalyst offers several advantages, such as short reaction time, high yields, lower catalytic loading, simple experimental procedure, and easy isolation of the products, under... 

This paper presents an integer linear programming (ILP) framework for the optimal placement of phasor measurement units (PMUs), in the presence of conventional measurements. Furthermore, by the proposed method, the power system remains completely observable during all possible single contingencies for lines and measurement devices. In doing so, the potential of circuit equations associated with both PMUs and conventional measurements as well as the network topology are fully utilized by a system of equations to reach the minimum possible numbers of required PMUs. The limitation of communication channels is also taken into account in the proposed ILP-based framework. The method is implemented... 

Racing catamarans use aerodynamic alleviation concept which in existing extreme ground effect significantly enhances the performance. Beside design measures, controlling strategies may be employed as convenient solutions to improve the performance and address concerns regarding poor stability in these crafts. Being of substantial importance for a racing catamaran to reach the final speed as soon as possible, this study attempts to find the optimal form of changing the drive angle (as control variable) to minimize its acceleration time. In this regard, a mathematical model is developed for forward acceleration phase of these catamarans based on empirical and theoretical methods. Then the... 

Properly adjusting the trim angle during the craft speed up will be extremely important in special cases as in sports competitions or military missions. In such applications, the goal of trim adjustment is to reach final speed in a minimum possible time which is an advantage to just passing the resistance hump. Present study tries to provide insight into how the angles of the drive system and trim tab of a planing craft should be changed during speed up so as to minimise the time to reach the final speed. This is a time-optimal control problem with the drive and trim tab angles as the control variables. Optimal control theory has been used previously for the motion control of marine vessels... 

A single step supercritical method was introduced for synthesis of “magnetite - reduced graphene oxide (M-rGO)” composite in supercritical methanol. Modified surface, smaller size, lesser cytotoxicity, and homogenous dispersion of Fe3O4 nanoparticles on the graphene surface were advantages of this new M-rGO composite in comparison to the materials synthesized by conventional wet chemical method (M-GO). Nanocomposites were injected in tissue equivalent phantoms of agarose gel in 10 mg/g dosage, and were irradiated by a 1600 mW laser beam at wavelength of 800–810 nm. The M-rGO and M-GO were found to be the most and the least efficient samples for increasing the temperature of the phantom. As... 

Power system restoration is the procedure of restoring a power system after a blackout and different strategies have developed for it because of its importance. One of the most practical and economical strategies is a "Build-up strategy" that includes the process of restoring separated islands in the power system and interconnecting them after it. The process of Build-up power system restoration is highly affected by power system telecommunication capabilities. Based on the constraints of wide area measurement system (WAMS) operation, each island must be fully observable. This paper provides an approach for power system restoration and observability of these islands. The New England 39 bus... 

The simulation results on viscoelastic fluid flows i sudden expansion geometry with different expansion ratios are presented. Oldroyd-B, linear Phan-Thien-Tanner (L-PTT) and Finitely Extensible Nonlinear Elastic (FENE-P) based constitutive equations were applied in two-dimensional Cartesian coordinates. The governing equations in transient and fully developed regions were solved using open source software called OpenFOAM. The flow patterns, including velocity profiles, shear stresses and first normal stress differences in some horizontal and vertical sections are illustrated. In addition, effects of the fluid type, flow dynamics and expansion ratio on the flow and vortex patterns in... 

Observability of bulk power transmission network by means of minimum number of phasor measurement units (PMUs), with the aid of the network topology, is a great challenge. This paper presents a novel equivalent integer linear programming method (EILPM) for the exhaustive search-based PMU placement. The state estimation implemented based on such a placement is completely linear, thereby eliminating drawbacks of the conventional SCADA-based state estimation. Additional constraints for observability preservation following single PMU or line outages can easily be implemented in the proposed EILPM. Furthermore, the limitation of communication channels is dealt with by translation of nonlinear...