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    Three-dimensional hybrid of iron–titanium mixed oxide/nitrogen-doped graphene on Ni foam as a superior electrocatalyst for oxygen evolution reaction

    , Article Journal of Colloid and Interface Science ; Volume 563 , 15 March , 2020 , Pages 241-251 Mousavi, D. S ; Asen, P ; Shahrokhian, S ; Irajizad, A ; Sharif University of Technology
    Academic Press Inc  2020
    Abstract
    Growing demands for clean and renewable energy technologies have sparked broad research on the development of highly efficient and stable non-noble metal electrocatalysts for oxygen evolution reaction (OER). In this regard, in the present work a three-dimensional Fe2TiO5/nitrogen-doped graphene (denoted as 3D FTO/NG) hybrid electrocatalyst was synthesized via a facile in-situ process using a hydrothermal method. Structural characterization of the prepared nanocomposite is performed by various techniques e.g. field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM) analysis, Fourier transform infrared spectra (FT-IR), X-ray photoelectron spectroscopy spectra (XPS),... 

    Polyphosphate-reduced graphene oxide on Ni foam as a binder free electrode for fabrication of high performance supercapacitor

    , Article Electrochimica Acta ; Volume 296 , 2019 , Pages 130-141 ; 00134686 (ISSN) Talebi, M ; Asen, P ; Shahrokhian, S ; Ahadian, M. M ; Sharif University of Technology
    Elsevier Ltd  2019
    Abstract
    Polyphosphate reduced graphene oxide on Ni foam (PPO-RGO/NF) is synthesized by varying weight ratios of Na5P3O10 (PO): graphene oxide (GO) with a simple, scalable and low cost method through freeze-drying of the PO-GO/NF followed by thermal treatment of the prepared electrodes. The resulting samples are characterized using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), Brunauer-Emmett-Teller (BET), and raman spectroscopy methods. The results show that the weight ratio of PO:GO, considerably affect the... 

    Cauliflower-Like Ni/MXene-bridged fiber-shaped electrode for flexible microsupercapacitor

    , Article Energy and Fuels ; Volume 36, Issue 4 , 2022 , Pages 2140-2148 ; 08870624 (ISSN) Darmiani, N ; Iraji zad, A ; Esfandiar, A ; Asen, P ; Sharif University of Technology
    American Chemical Society  2022
    Abstract
    Microscale, flexible, and lightweight electrodes are of interest for the generation of light and miniaturized energy storage systems such as microsupercapacitors. Wire or fiber-shaped electrodes can be considered as potential candidates for microsupercapacitor fabrication. Herein, a facile strategy for the preparation of high electrochemical performance fiber-shaped microsupercapacitors based on Ni(OH)2-Ni-Ti3C2 film on a copper wire (CW) electrode is presented. We employed a porous cauliflower-like Ni-Ti3C2 MXene film as the supporting scaffold to bridge a Ni(OH)2 active substance with a Cu wire current collector. This hierarchical structure supplies a high surface area, many electroactive...